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2006, Vol. 78, Issue 2
Special Topic Issue on the Theme of Organometallics in Organic Synthesis

13th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-13), Geneva, Switzerland, 17–21 July 2005

This conference is part of the Organometallic Chemistry Directed Toward Organic Synthesis series.
James R. Bull
p. v [Details] [Full text - pdf 33 kB]
Alexandre Alexakis
p. vi [Details] [Full text - pdf 31 kB]
Transition-metal-catalyzed reactions of allenes
Shengming Ma
p. 197 [Details + Abstract] [Full text - pdf 327 kB]
Air-stable phosphine oxides as preligands for catalytic activation reactions of C-Cl, C-F, and C-H bonds
Lutz Ackermann, Robert Born, Julia H. Spatz, Andreas Althammer and Christian J. Gschrei
p. 209 [Details + Abstract] [Full text - pdf 192 kB]
Toward an understanding of the factors responsible for the 1,2-migration of alkyl groups in borate complexes
Varinder K. Aggarwal, Guang Yu Fang, Xavier Ginesta, Dean M. Howells and Mirko Zaja
p. 215 [Details + Abstract] [Full text - pdf 308 kB]
Palladium-mediated cascade or multicomponent reactions: A new route to carbo- and heterocyclic compounds
Geneviève Balme, Didier Bouyssi and Nuno Monteiro
p. 231 [Details + Abstract] [Full text - pdf 249 kB]
Photochemical release of various functional groups
Christian G. Bochet
p. 241 [Details + Abstract] [Full text - pdf 227 kB]
Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base pair model
Bernhard Breit and Wolfgang Seiche
p. 249 [Details + Abstract] [Full text - pdf 375 kB]
Sulfenylphosphinoferrocenes: Novel planar chiral ligands in enantioselective catalysis
Silvia Cabrera, Olga García Mancheño, Ramón Gómez Arrayás, Inés Alonso, Pablo Mauleón and Juan C. Carretero
p. 257 [Details + Abstract] [Full text - pdf 511 kB]
Catalytic asymmetric addition reactions leading to carbon-carbon bond formation: Phenyl and alkenyl transfer to aldehydes and alkynylation of α-imino esters
Jian-Xin Ji, Jing Wu, Lijin Xu, Chiu-Wing Yip, Kim Hung Lam and Albert S. C. Chan
p. 267 [Details + Abstract] [Full text - pdf 198 kB]
GaCl3-catalyzed reactions utilizing isocyanides as a C1 source
Mamoru Tobisu, Masayuki Oshita, Sachiko Yoshioka, Aki Kitajima and Naoto Chatani
p. 275 [Details + Abstract] [Full text - pdf 200 kB]
Hydrostannation of activated alkynes mediated by Stryker's reagent
Lai To Leung and Pauline Chiu
p. 281 [Details + Abstract] [Full text - pdf 172 kB]
First enantioselective one-pot, three-component imino Reformatsky reaction
Pier Giorgio Cozzi and Eleonora Rivalta
p. 287 [Details + Abstract] [Full text - pdf 185 kB]
Development of homogeneous and heterogeneous asymmetric catalysts for practical enantioselective reactions
Kuiling Ding
p. 293 [Details + Abstract] [Full text - pdf 338 kB]
Rhodium-catalyzed asymmetric reactions with a dynamic library of chiral tropos phosphorus ligands
Cesare Gennari, Chiara Monti and Umberto Piarulli
p. 303 [Details + Abstract] [Full text - pdf 236 kB]
New chiral tridentate ligands for asymmetric catalysis
Kevin Murtagh, Brian A. Sweetman and Patrick J. Guiry
p. 311 [Details + Abstract] [Full text - pdf 266 kB]
3-Aminopyrrolidine lithium amides as chiral ligands for alkyllithium derivatives: Synthesis, NMR analysis, and computational study of their mixed aggregates
Anne Harrison-Marchand, Jean-Yves Valnot, Aline Corruble, Nicolas Duguet, Hassan Oulyadi, Stéphanie Desjardins, Catherine Fressigné and Jacques Maddaluno
p. 321 [Details + Abstract] [Full text - pdf 300 kB]
Syntheses and reactions of optically active α-aminoallenylstannanes and α-aminopropargylboranes
Louis S. Hegedus, Peter Ranslow, Michal Achmatowicz, Cristobal de los Rios, Christopher Hyland, Eva M. Garcia-Frutos and Sarri Salman
p. 333 [Details + Abstract] [Full text - pdf 249 kB]
Development of palladium catalysts for asymmetric hydroamination reactions
King Kuok Hii
p. 341 [Details + Abstract] [Full text - pdf 248 kB]
Palladium-catalyzed ring-forming reactions: Methods and applications
Mark Lautens, Dino Alberico, Cyril Bressy, Yuan-Qing Fang, Brian Mariampillai and Thorsten Wilhelm
p. 351 [Details + Abstract] [Full text - pdf 334 kB]
Catalytic activation of nitrogen derivatives with transition-metal complexes
Hélène Lebel, Olivier Leogane, Kim Huard and Sylvain Lectard
p. 363 [Details + Abstract] [Full text - pdf 274 kB]
New technologies in catalysis using base metals
Bruce H. Lipshutz, Tom Butler, Bryan A. Frieman, Vladimir Kogan, Ching-Tien Lee, Asher Lower, Danielle M. Nihan, Benjamin R. Taft and Anthony E. Tomaso
p. 377 [Details + Abstract] [Full text - pdf 372 kB]
Synthesis of spiroketals by iridium-catalyzed double hydroalkoxylation
Barbara A. Messerle and Khuong Q. Vuong
p. 385 [Details + Abstract] [Full text - pdf 167 kB]
Chiral Ru/PNNP complexes in catalytic and stoichiometric electrophilic O- and F-atom transfer to 1,3-dicarbonyl compounds
Cristina Bonaccorsi, Martin Althaus, Claus Becker, Antonio Togni and Antonio Mezzetti
p. 391 [Details + Abstract] [Full text - pdf 234 kB]
Alkoxy- and hydroxycyclization of enynes catalyzed by Pd(II) and Pt(II) catalysts
Véronique Michelet, Lise Charruault, Serafino Gladiali and Jean-Pierre Genêt
p. 397 [Details + Abstract] [Full text - pdf 277 kB]
Dual Lewis acid - Lewis base activation in enantioselective additions to aldehydes
Erica Wingstrand, Stina Lundgren, Maël Penhoat and Christina Moberg
p. 409 [Details + Abstract] [Full text - pdf 141 kB]
Torque control by metal-orbital interactions
Masahiro Murakami, Yasufumi Miyamoto, Munehiro Hasegawa, Ippei Usui and Takanori Matsuda
p. 415 [Details + Abstract] [Full text - pdf 276 kB]
Indium-catalyzed addition of carbon units to acetylenes: Development of a new C-C bond formation toward exploitation of chemical resources
Masaharu Nakamura
p. 425 [Details + Abstract] [Full text - pdf 282 kB]
Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: Tetraorganosilanes for the practical cross-coupling reaction
Yoshiaki Nakao, Akhila K. Sahoo, Hidekazu Imanaka, Akira Yada and Tamejiro Hiyama
p. 435 [Details + Abstract] [Full text - pdf 208 kB]
New synthetic reactions catalyzed by cobalt complexes
Hideki Yorimitsu and Koichiro Oshima
p. 441 [Details + Abstract] [Full text - pdf 298 kB]
Synthesis and reactivity of new strained cyclic allene and alkyne precursors
Diego Peña, Beatriz Iglesias, Iago Quintana, Dolores Pérez, Enrique Guitián and Luis Castedo
p. 451 [Details + Abstract] [Full text - pdf 167 kB]
Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction
Jean-Baptiste Sortais, Laurent Barloy, Claude Sirlin, André H. M. de Vries, Johannes G. de Vries and Michel Pfeffer
p. 457 [Details + Abstract] [Full text - pdf 225 kB]
Catalytic asymmetric ring-opening of cyclopentadiene - heterodienophile cycloadducts with organometallic reagents
Mauro Pineschi, Federica Del Moro, Paolo Crotti and Franco Macchia
p. 463 [Details + Abstract] [Full text - pdf 165 kB]
Connecting catalytic cycles by organometallic transformations in situ: Novel perspectives in the olefin metathesis field
Bernd Schmidt
p. 469 [Details + Abstract] [Full text - pdf 204 kB]
Acid-base catalysis using chiral palladium complexes
Mikiko Sodeoka and Yoshitaka Hamashima
p. 477 [Details + Abstract] [Full text - pdf 511 kB]
Helicity control in the synthesis of helicenes and related compounds
Ivo Starý, Irena G. Stará, Zuzana Alexandrová, Petr Sehnal, Filip Teplý, David Šaman and Lubomír Rulíšek
p. 495 [Details + Abstract] [Full text - pdf 198 kB]
Rhodium-catalyzed asymmetric hydrogenation using self-assembled chiral bidentate ligands
James M. Takacs, Kittichai Chaiseeda, Shin A. Moteki, D. Sahadeva Reddy, Di Wu and Kusumlata Chandra
p. 501 [Details + Abstract] [Full text - pdf 336 kB]
Dabbling with air-stable organoaluminum species
Kallolmay Biswas, Alex Chapron, Thea Cooper, Paul K. Fraser, Andrew Novak, Oscar Prieto and Simon Woodward
p. 511 [Details + Abstract] [Full text - pdf 251 kB]
Asymmetric protonation of silyl enolates catalyzed by chiral phosphine-silver(I) complexes
Akira Yanagisawa, Taichiro Touge and Takayoshi Arai
p. 519 [Details + Abstract] [Full text - pdf 205 kB]