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2012, Vol. 84, Issue 3
Chlorine-free Synthesis for Green Chemistry

Pietro Tundo
p. vi [Details] [Full text - pdf 77 kB]

Chlorine-free Synthesis for Green Chemistry

Chlorine-free synthesis: An overview
Pietro Tundo
p. 411 [Details + Abstract] [Full text - pdf 451 kB]
Replacing benzyl chloride with benzyl alcohol in heterogeneous catalytic benzylation of aromatic compounds
Natalia Candu, Stefan Wuttke, Erhard Kemnitz, Simona M. Coman and Vasile I. Pârvulescu
p. 427 [Details + Abstract] [Full text - pdf 211 kB]
Novel general halogen-free methodology for the synthesis of organophosphorus compounds
Nina K. Gusarova, Svetlana N. Arbuzova and Boris A. Trofimov
p. 439 [Details + Abstract] [Full text - pdf 692 kB]
Environmentally benign and effective syntheses of N-substituted carbamates via alcoholysis of disubstituted ureas over TiO2/SiO2 catalyst
Liguo Wang, Jianpeng Shang, Shimin Liu, Lequan Liu, Shiguo Zhang and Youquan Deng
p. 461 [Details + Abstract] [Full text - pdf 474 kB]
Phosgene-free synthesis of 1,3-diphenylurea via catalyzed reductive carbonylation of nitrobenzene
Andrea Vavasori and Lucio Ronchin
p. 473 [Details + Abstract] [Full text - pdf 377 kB]
Green approaches to the production of iopamidol
Pier Lucio Anelli, Marino Brocchetta, Luciano Lattuada and Fulvio Uggeri
p. 485 [Details + Abstract] [Full text - pdf 260 kB]
Laser electrodispersion as a new chlorine-free method for the production of highly effective metal-containing supported catalysts
Ekaterina S. Lokteva, Anton A. Peristyy, Natalia E. Kavalerskaya, Elena V. Golubina, Lada V. Yashina, Tatiana N. Rostovshchikova, Sergey A. Gurevich, Vladimir M. Kozhevin, Denis A. Yavsin and Valery V. Lunin
p. 495 [Details + Abstract] [Full text - pdf 666 kB]
Molecular sieve catalysts as substitutes for metal chlorides in the chemical industry: Some selected examples
Michel Guisnet, Ludovic Pinard, Matteo Guidotti and Federica Zaccheria
p. 509 [Details + Abstract] [Full text - pdf 159 kB]
Simple halogen-free synthesis of aryl cinnamates using Mo-Keggin heteropoly acids as catalyst
Valeria Palermo, Diego M. Ruiz, Juan C. Autino, Patricia G. Vázquez and Gustavo P. Romanelli
p. 529 [Details + Abstract] [Full text - pdf 636 kB]
Polyoxometalate and copolymer-functionalized ionic liquid catalyst for esterification
Huan Li, Jizhong Chen, Li Hua, Yunxiang Qiao, Yinyin Yu, Zhenyan Pan, Hanming Yang and Zhenshan Hou
p. 541 [Details + Abstract] [Full text - pdf 439 kB]
Chlorine-free copper-catalyzed oxidative synthesis of 1,3,4-oxadiazoles with molecular oxygen as the sole oxidant
Huanfeng Jiang, Xianwei Li, Xiaoyan Pan and Peng Zhou
p. 553 [Details + Abstract] [Full text - pdf 133 kB]
Selective epoxidation of propylene to propylene oxide with H2 and O2 over Au/Ti-MWW catalysts
Yingjie Ren, Le Xu, Liyan Zhang, Jianggan Wang, Yueming Liu, Mingyuan He and Peng Wu
p. 561 [Details + Abstract] [Full text - pdf 1789 kB]
Organic synthesis using carbon dioxide as phosgene-free carbonyl reagent
An-Hua Liu, Yu-Nong Li and Liang-Nian He
p. 581 [Details + Abstract] [Full text - pdf 695 kB]
Recent progress in phosgene-free methods for synthesis of dimethyl carbonate
Weicai Peng, Ning Zhao, Fukui Xiao, Wei Wei and Yuhan Sun
p. 603 [Details + Abstract] [Full text - pdf 479 kB]
Chlorine-free catalysts for green synthesis of cyclic carbonates from carbon dioxide
Rui Li, Xin Tong, Xiaofang Li and Changwen Hu
p. 621 [Details + Abstract] [Full text - pdf 460 kB]
Cyclic carbonates as monomers for phosgene- and isocyanate-free polyurethanes and polycarbonates
Sang-Hyun Pyo, Per Persson, M. Amin Mollaahmad, Kent Sörensen, Stefan Lundmark and Rajni Hatti-Kaul
p. 637 [Details + Abstract] [Full text - pdf 942 kB]
Direct synthesis of dimethyl carbonate from methanol and carbon dioxide over organotin‑functionalized mesoporous benzene‑silica
Binbin Fan, Hongyu Li, Weibin Fan, Zhangfen Qin and Ruifeng Li
p. 663 [Details + Abstract] [Full text - pdf 537 kB]
Synthesis of unsymmetrical organic carbonates catalyzed by a sulfonic acid-functionalized zirconium phosphonate
Jinliang Song, Binbin Zhang, Suxiang Wu, Qian Wang, Honglei Fan, Zhaofu Zhang and Buxing Han
p. 675 [Details + Abstract] [Full text - pdf 317 kB]
Activity of ceria and ceria-supported gold nanoparticles for the carbamoylation of aliphatic amines by dimethyl carbonate
Raquel Juárez, Avelino Corma and Hermenegildo García
p. 685 [Details + Abstract] [Full text - pdf 256 kB]
Phosgene-free carbamoylation of aniline via dimethyl carbonate
Sandra Grego, Fabio Aricò and Pietro Tundo
p. 695 [Details + Abstract] [Full text - pdf 345 kB]
Cyclization reaction of amines with dialkyl carbonates to yield 1,3-oxazinan-2-ones
C. Robert McElroy, Fabio Aricò, Franco Benetollo and Pietro Tundo
p. 707 [Details + Abstract] [Full text - pdf 429 kB]
A greener, halide‑free approach to ionic liquid synthesis
Jamie L. Ferguson, John D. Holbrey, Shieling Ng, Natalia V. Plechkova, Kenneth R. Seddon, Alina A. Tomaszowska and David F. Wassell
p. 723 [Details + Abstract] [Full text - pdf 264 kB]
Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing
Gabriela Gurau, Hui Wang, Yun Qiao, Xingmei Lu, Suojiang Zhang and Robin D. Rogers
p. 745 [Details + Abstract] [Full text - pdf 781 kB]
Synthesis of glycerol carbonate from glycerol and dimethyl carbonate in basic ionic liquids
Cinzia Chiappe and Sunita Rajamani
p. 755 [Details + Abstract] [Full text - pdf 312 kB]
Aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran on supported vanadium oxide catalysts: Structural effect and reaction mechanism
Junfang Nie and Haichao Liu
p. 765 [Details + Abstract] [Full text - pdf 779 kB]
Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source
Shuguang Liang, Huizhen Liu, Jinli Liu, Weitao Wang, Tao Jiang, Zhaofu Zhang and Buxing Han
p. 779 [Details + Abstract] [Full text - pdf 452 kB]
Effective catalysis of poly(ethylene terephthalate) (PET) degradation by metallic acetate ionic liquids
Xueyuan Zhou, Xingmei Lu, Qian Wang, Minli Zhu and Zengxi Li
p. 789 [Details + Abstract] [Full text - pdf 544 kB]
Environmentally friendly approaches to the synthesis of new antibiotics from sugars
Nuno M. Xavier and Amélia P. Rauter
p. 803 [Details + Abstract] [Full text - pdf 760 kB]
Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
Laura I. Rossi and Manuel I. Velasco
p. 819 [Details + Abstract] [Full text - pdf 171 kB]
A green metrics assessment of phosgene and phosgene-free syntheses of industrially important commodity chemicals
John Andraos
p. 827 [Details + Abstract] [Full text - pdf 2354 kB]