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Pure Appl. Chem., 2009, Vol. 81, No. 2, pp. 205-215

http://dx.doi.org/10.1351/PAC-CON-08-09-14

A strategy for constructing C-sialosides based on Ireland-Claisen rearrangement and its application for synthesis of CF2-linked ganglioside GM4 analog

Mikiko Sodeoka1, Go Hirai1, Toru Watanabe1 and Taeko Miyagi2

1 Synthetic Organic Chemistry Laboratory, RIKEN, Hirosawa, Wako, Saitama 351 0198, Japan
2 Division of Biochemistry, Miyagi Cancer Center Research Institute, Natori 981-1293, Japan, and CREST,JST Kawaguchi 332-1102, Japan

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