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2008, Vol. 80, Issue 5

14th International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-14), Nara, Japan, 2–6 August 2007

This conference is part of the Organometallic Chemistry Directed Toward Organic Synthesis series.
Preface
Koichiro Oshima
p. vi [Details] [Full text - pdf 34 kB]
1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes
Yasunori Yamamoto, Takashi Nishikata and Norio Miyaura
p. 807 [Details + Abstract] [Full text - pdf 400 kB]
OMCOS for functional polymers - double-stranded DNA-like polymers
Tien-Yau Luh, Hui-Chun Yang, Nai-Ti Lin, Shu-Yi Lin, Shern-Long Lee and Chun-hsien Chen
p. 819 [Details + Abstract] [Full text - pdf 467 kB]
Organometallic catalysts in synthetic organic chemistry: From reactions in aqueous media to gold catalysis
Jean-Pierre Genêt, Sylvain Darses and Véronique Michelet
p. 831 [Details + Abstract] [Full text - pdf 405 kB]
Reaction of alcohols and silyl ethers in the presence of an indium/silicon-based catalyst system: Deoxygenation and allyl substitution
Akio Baba, Makoto Yasuda, Yoshihiro Nishimoto, Takahiro Saito and Yoshiyuki Onishi
p. 845 [Details + Abstract] [Full text - pdf 285 kB]
Catalysts through self-assembly for combinatorial homogeneous catalysis
Bernhard Breit
p. 855 [Details + Abstract] [Full text - pdf 194 kB]
Ruthenium catalysts for selective nucleophilic allylic substitution
Christian Bruneau, Jean-Luc Renaud and Bernard Demerseman
p. 861 [Details + Abstract] [Full text - pdf 274 kB]
Evaluation of catalytic activity of copper salts and their removal processes in the three-component coupling reactions
Seung Jun Hwang, Seung Hwan Cho and Sukbok Chang
p. 873 [Details + Abstract] [Full text - pdf 191 kB]
New methods in asymmetric catalysis based on new hemi-labile bidentate ligands
André B. Charette, Alexandre Côté, Jean-Nicolas Desrosiers, Isabelle Bonnaventure, Vincent N. G. Lindsay, Caroline Lauzon, Jad Tannous and Alessandro A. Boezio
p. 881 [Details + Abstract] [Full text - pdf 416 kB]
Catalytic enantioselective Reformatsky reactions
Pier Giorgio Cozzi, Alessandro Mignogna and Luca Zoli
p. 891 [Details + Abstract] [Full text - pdf 299 kB]
Metal carbonyl complexes and chirality
Susan E. Gibson, Karina A. C. Kaufmann, Jennifer A. Loch and Ayako Miyazaki
p. 903 [Details + Abstract] [Full text - pdf 346 kB]
New preparative methods for allylic boronates and their application in stereoselective catalytic allylborations
Dennis G. Hall
p. 913 [Details + Abstract] [Full text - pdf 354 kB]
Nickel-catalyzed coupling reactions of alkenes
Sze-Sze Ng, Chun-Yu Ho, Kristin D. Schleicher and Timothy F. Jamison
p. 929 [Details + Abstract] [Full text - pdf 274 kB]
Carbon-carbon bond-forming reactions using alkyl fluorides
Jun Terao, Hirohisa Todo, Hiroyasu Watabe, Aki Ikumi, Yoshiaki Shinohara and Nobuaki Kambe
p. 941 [Details + Abstract] [Full text - pdf 269 kB]
Asymmetric synthesis: From transition metals to organocatalysis
Pavel Kočovský and Andrei V. Malkov
p. 953 [Details + Abstract] [Full text - pdf 391 kB]
Enantio- and regioselective CpRu-catalyzed Carroll rearrangement
Martina Austeri, Frederic Buron, Samuel Constant, Jerome Lacour, David Linder, Jessica Müller and Simone Tortoioli
p. 967 [Details + Abstract] [Full text - pdf 263 kB]
Palladium-catalyzed selective activation of allyl alcohols as allyl cations, allyl anions, and zwitterionic trimethylenemethanes
Yoshinao Tamaru and Masanari Kimura
p. 979 [Details + Abstract] [Full text - pdf 356 kB]
Transition-metal-catalyzed synthesis of organosulfur compounds
Mieko Arisawa and Masahiko Yamaguchi
p. 993 [Details + Abstract] [Full text - pdf 306 kB]
New synthetic methodologies based on active transition metals
Francisco Alonso and Miguel Yus
p. 1005 [Details + Abstract] [Full text - pdf 252 kB]
Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions
Andrei Bădoiu, Yasmin Brinkmann, Florian Viton and E. Peter Kündig
p. 1013 [Details + Abstract] [Full text - pdf 194 kB]
Application of rhodium-catalyzed cyclohydrocarbonylation to the syntheses of enantiopure homokainoids
Wen-Hua Chiou, Angèle Schoenfelder, André Mann and Iwao Ojima
p. 1019 [Details + Abstract] [Full text - pdf 263 kB]
Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
Koen Geurts, Stephen P. Fletcher, Anthoni W. van Zijl, Adriaan J. Minnaard and Ben L. Feringa
p. 1025 [Details + Abstract] [Full text - pdf 354 kB]
Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis
Hajime Ito, Shinichiro Ito, Yusuke Sasaki, Kou Matsuura and Masaya Sawamura
p. 1039 [Details + Abstract] [Full text - pdf 224 kB]
Hydrogenation of polar functionalities with Cp*Ru(PN) catalysts
Masato Ito
p. 1047 [Details + Abstract] [Full text - pdf 254 kB]
Cu(I)-catalyzed asymmetric allylation of ketones and ketimines
Motomu Kanai, Reiko Wada, Tomoyuki Shibuguchi and Masakatsu Shibasaki
p. 1055 [Details + Abstract] [Full text - pdf 312 kB]
Golden opportunities in catalysis
Norbert Krause, Volker Belting, Carl Deutsch, Jörg Erdsack, Hong-Tao Fan, Birgit Gockel, Anja Hoffmann-Röder, Nobuyoshi Morita and Frank Volz
p. 1063 [Details + Abstract] [Full text - pdf 213 kB]
Asymmetric epoxidation of olefins catalyzed by Ti(salan) complexes using aqueous hydrogen peroxide as the oxidant
Kazuhiro Matsumoto, Yuji Sawada and Tsutomu Katsuki
p. 1071 [Details + Abstract] [Full text - pdf 228 kB]
Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes
Tsumoru Morimoto, Masahiko Fujioka, Koji Fuji, Ken Tsutsumi and Kiyomi Kakiuchi
p. 1079 [Details + Abstract] [Full text - pdf 276 kB]
First palladium- and nickel-catalyzed oxidative diamination of alkenes: Cyclic urea, sulfamide, and guanidine building blocks
Kilian Muñiz, Claas H. Hövelmann, Jan Streuff and Esther Campos-Gómez
p. 1089 [Details + Abstract] [Full text - pdf 242 kB]
Nickel-catalyzed carbocyanation of alkynes
Yoshiaki Nakao and Tamejiro Hiyama
p. 1097 [Details + Abstract] [Full text - pdf 326 kB]
Asymmetric synthesis of planar-chiral ferrocenes by Mo- or Ru-catalyzed enantioselective metathesis
Masamichi Ogasawara, Susumu Watanabe, Kiyohiko Nakajima and Tamotsu Takahashi
p. 1109 [Details + Abstract] [Full text - pdf 211 kB]
Nickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imine
Sensuke Ogoshi, Haruo Ikeda and Hideo Kurosawa
p. 1115 [Details + Abstract] [Full text - pdf 317 kB]
Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes
Tetsuya Satoh, Kenji Ueura and Masahiro Miura
p. 1127 [Details + Abstract] [Full text - pdf 265 kB]
γ-Methylidene-δ-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones
Ryo Shintani, Masataka Murakami and Tamio Hayashi
p. 1135 [Details + Abstract] [Full text - pdf 260 kB]
Toward the total synthesis of ritterazine N
Douglass F. Taber, Jean-Michel Joerger and Karen V. Taluskie
p. 1141 [Details + Abstract] [Full text - pdf 239 kB]
Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation
Yoichiro Kuninobu, Yuta Nishina, Atsushi Kawata, Makoto Shouho and Kazuhiko Takai
p. 1149 [Details + Abstract] [Full text - pdf 250 kB]
New hydrosilylation reaction of arylacetylene accompanied by C-H bond activation catalyzed by a xantsil ruthenium complex
Hiromi Tobita, Nobukazu Yamahira, Keisuke Ohta, Takashi Komuro and Masaaki Okazaki
p. 1155 [Details + Abstract] [Full text - pdf 194 kB]
Palladium-catalyzed cross-addition of triisopropylsilylacetylene to unactivated alkynes
Naofumi Tsukada, Satoshi Ninomiya, Yoshimi Aoyama and Yoshio Inoue
p. 1161 [Details + Abstract] [Full text - pdf 168 kB]
New cyclizations via catalytic ruthenium vinylidenes
Jesús A. Varela, Carlos González-Rodríguez, Silvia G. Rubín, Luis Castedo and Carlos Saá
p. 1167 [Details + Abstract] [Full text - pdf 304 kB]
Cationic palladium-catalyzed hydrosilylative cross-coupling of alkynes with alkenes forming 4-silylated-1-butene frameworks
Takamitsu Shimamoto, Motoharu Chimori, Hiroaki Sogawa, Yuki Harada, Masaharu Aoki and Keiji Yamamoto
p. 1179 [Details + Abstract] [Full text - pdf 213 kB]
Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes
Makoto Yamashita and Kyoko Nozaki
p. 1187 [Details + Abstract] [Full text - pdf 273 kB]