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Pure Appl. Chem., 2000, Vol. 72, No. 9, pp. 1655-1658

Hypervalent siloxane derivatives. An alternative to Stille and Suzuki couplings

Philip DeShong, Christopher J. Handy and Molly E. Mowery

Department of Chemistry and Biochemistry, University of Maryland at College Park, College Park, MD 20742 USA

Abstract: Siloxane methodology is extended to couplings with iodo- and bromoanilines, hindered arylbromides, and substituted siloxanes as substrates. Additionally, initial studies with 5-bromoindole and other heteroaromatics suggest that the siloxane-mediated cross coupling methodology will also be applicable in these systems.