Pure Appl. Chem., 2013, Vol. 85, No. 10, pp. 1967-1978
http://dx.doi.org/10.1351/PAC-CON-12-11-09
Published online 2013-06-01
Recent progress in research on stimuli-responsive circularly polarized luminescence based on π-conjugated molecules
Abstract:
This short review article summarizes recent progress in research on various stimuli-responsive circularly polarized luminescence (CPL) properties derived from π-conjugated molecules and related materials. As representative examples, assembled structures of chiral π-conjugated polymers and molecules showed tunable CPL resulting from the enhancement of chirality induction by aggregation. Fascinating CPL-active species, pyrrole-based anion-responsive π-conjugated molecules exhibiting CPL induced by anion binding and ion pairing, are also discussed.
Keywords
chirality; fluorescence; helical structures; molecular recognition; self-assembly; supramolecular chemistry.