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Pure Appl. Chem., 2012, Vol. 84, No. 3, pp. 439-459

http://dx.doi.org/10.1351/PAC-CON-11-07-11

Published online 2012-01-17

Novel general halogen-free methodology for the synthesis of organophosphorus compounds*

Nina K. Gusarova, Svetlana N. Arbuzova and Boris A. Trofimov*

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation

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  • Artem’ev Alexander V., Gusarova Nina K., Korocheva Anastasiya O., Malysheva Svetlana F., Gatilov Yurii V., Trofimov Boris A.: A shortcut to tris[2-(4-hydroxyphenyl)ethyl]phosphine oxide and 2-(4-hydroxyphenyl)ethylphosphinic acid via reaction of elemental phosphorus with 4-tert-butoxystyrene. Mendeleev Communications 2014, 24, 29. <http://dx.doi.org/10.1016/j.mencom.2013.12.009>
  • Montchamp Jean-Luc: Phosphinate Chemistry in the 21st Century: A Viable Alternative to the Use of Phosphorus Trichloride in Organophosphorus Synthesis. Acc. Chem. Res. 2014, 47, 77. <http://dx.doi.org/10.1021/ar400071v>
  • Kuimov Vladimir A., Malysheva Svetlana F., Gusarova Nina K., Korocheva Anastasiya O., Trofimov Boris A.: One-pot microwave synthesis of tertiary phosphine sulfides directly from aromatic alkenes, elemental phosphorus and sulfur in KOH–DMSO system. Journal of Sulfur Chemistry 2014, 35, 137. <http://dx.doi.org/10.1080/17415993.2013.809454>
  • Fisher Henry C., Prost Lucie, Montchamp Jean-Luc: Organophosphorus Chemistry without PCl3 : A Bridge from Hypophosphorous Acid to H-Phosphonate Diesters. Eur. J. Org. Chem. 2013, 2013, 7973. <http://dx.doi.org/10.1002/ejoc.201301412>
  • Gusarova N. K., Chernysheva N. A., Yas’ko S. V., Trofimov B. A.: Highly efficient atom economical “green chemistry” synthesis of vinyl sulfides from thiols and acetylene in water. Russ Chem Bull 2013, 62, 438. <http://dx.doi.org/10.1007/s11172-013-0059-4>
  • Protasiewicz John D.: Nitrogen, phosphorus, arsenic, antimony, and bismuth. Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 2013, 109, 66. <http://dx.doi.org/10.1039/c3ic90011h>
  • Montchamp Jean-Luc: Organophosphorus Synthesis Without Phosphorus Trichloride: The Case for the Hypophosphorous Pathway. Phosphorus, Sulfur, and Silicon and the Related Elements 2013, 188, 66. <http://dx.doi.org/10.1080/10426507.2012.727925>
  • Artem'ev Alexander V., Malysheva Svetlana F., Belogorlova Nataliya A., Gusarova Nina K.: Three-component reaction between elemental sulfur, primary phosphines, and amines: straightforward synthesis of organylammonium trithiophosphonates. Journal of Sulfur Chemistry 2013, 34, 227. <http://dx.doi.org/10.1080/17415993.2012.735235>
  • Gusarova N. K., Verkhoturova S. I., Kazantseva T. I., Arbuzova S. N., Albanov A. I., Tatarinova A. A., Trofimov B. A.: Radical addition of secondary phosphine chalcogenides to allylamine: Atom-economic synthesis of aminopropylphosphine chalcogenides. Russ J Gen Chem 2013, 83, 1895. <http://dx.doi.org/10.1134/S1070363213100162>
  • Gusarova N. K., Malysheva S. F., Kuimov V. A., Belogorlova N. A., Vashchenko A. V., Trofimov B. A.: Cycloaddition of primary phosphines to divinyl sulfide. Russ J Org Chem 2013, 49, 12. <http://dx.doi.org/10.1134/S107042801301003X>
  • Artem’ev A. V., Malysheva S. F., Korocheva A. O., Fedorov S. V.: Direct phosphorylation of β-alkylstyrenes with elemental phosphorus under Trofimov-Gusarova reaction conditions. Russ J Org Chem 2013, 49, 1839. <http://dx.doi.org/10.1134/S1070428013120233>
  • Gusarova Nina K., Arbuzova Svetlana N., Trofimov Boris A.: ChemInform Abstract: Novel General Halogen-Free Methodology for the Synthesis of Organophosphorus Compounds. ChemInform 2012, 43, no. <http://dx.doi.org/10.1002/chin.201244240>
  • Artem'ev Alexander V., Malysheva Svetlana F., Korocheva Anastasiya O., Bagryanskaya Irina Yu.: One-Pot Halogen-Free Synthesis of 2,3-Dihydro-1H-inden-2-yl-phosphinic Acid from 1H-indene and Elemental Phosphorus via the Trofimov-Gusarova Reaction. Heteroatom Chem 2012, 23, 568. <http://dx.doi.org/10.1002/hc.21051>
  • Yakhvarov D. G., Gorbachuk E. V., Kagirov R. M., Sinyashin O. G.: Electrochemical reactions of white phosphorus. Russ Chem Bull 2012, 61, 1300. <http://dx.doi.org/10.1007/s11172-012-0176-5>
  • Malysheva S. F., Artem’ev A. V., Belogorlova N. A., Korocheva A. O., Gusarova N. K., Trofimov B. A.: First example of the $$ C_{sp^2 } $$ -P bond formation in the reaction of red phosphorus with hetaryl halides. Russ J Gen Chem 2012, 82, 1307. <http://dx.doi.org/10.1134/S1070363212070213>