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Pure Appl. Chem., 2006, Vol. 78, No. 2, pp. 519-523

Asymmetric protonation of silyl enolates catalyzed by chiral phosphine-silver(I) complexes

Akira Yanagisawa, Taichiro Touge and Takayoshi Arai

Department of Chemistry, Faculty of Science, Chiba University, Yayoi-cho 1-33, Inage, Chiba 263-8522, Japan

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  • Yamashita Yasuhiro, Imaizumi Takaki, Guo Xun-Xiang, Kobayashi Shū: Chiral Silver Amides as Effective Catalysts for Enantioselective [3+2] Cycloaddition Reactions. Chem —Asian J 2011, 6, 2550. <>
  • Claraz Aurélie, Leroy Jérôme, Oudeyer Sylvain, Levacher Vincent: Catalytic Enantioselective Protonation of Enol Trifluoroacetates by Means of Hydrogenocarbonates and Cinchona Alkaloids. J Org Chern 2011, 76, 6457. <>
  • Martin Juliette, Plaquevent Jean-Christophe, Maddaluno Jacques, Rouden Jacques, Lasne Marie-Claire: Efficient Deracemization of Pipecolic Acid Amides through Enantioselective Protonation of Their Lithium Enolates: Insights into the Origin of the Transferred Proton. Eur J Org Chem 2009, 2009, 5414. <>
  • Mohr Justin T., Hong Allen Y., Stoltz Brian M.: Enantioselective protonation. Nature Chem 2009, 1, 359. <>
  • Yanagisawa Akira, Arai Takayoshi: Recent advances in chiral phosphine–silver(i) complex-catalyzed asymmetric reactions. Chem Commun 2008, 1165. <>