CrossRef enabled

PAC Archives

Archive →

Pure Appl. Chem., 2003, Vol. 75, No. 4, pp. 445-460

http://dx.doi.org/10.1351/pac200375040445

Challenging metal-based transformations. From single-bond activation to catalysis and metallaquinonoids

D. Milstein

Department of Organic Chemistry, The Weizmann Institute of Science, Rehovot, 76100 Israel

CrossRef Cited-by theme picture

CrossRef Cited-by Linking

  • Wang Li, Hunter Seth C., Song Zhimin, Steren Carlos A., Chen Tianniu, Wei Zhenhong, Cai  Hu, Xue Zi-Ling: CH Bond Activation during and after the Reactions of a Metallacyclic Amide with Silanes: Formation of a μ-Alkylidene Hydride Complex, Its H-D Exchange, and β-H Abstraction by a Hydride Ligand. Chem. Eur. J. 2014, n/a. <http://dx.doi.org/10.1002/chem.201303166>
  • Pellegrino Juan, Gaviglio Carina, Milstein David, Doctorovich Fabio: Electron Transfer Behavior of Pincer-Type {RhNO}8 Complexes: Spectroscopic Characterization and Reactivity of Paramagnetic {RhNO}9 Complexes. Organometallics 2013, 32, 6555. <http://dx.doi.org/10.1021/om4008746>
  • Kumar Shanish, Mani Ganesan, Mondal Sukanta, Chattaraj Pratim Kumar: Pyrrole-Based New Diphosphines: Pd and Ni Complexes Bearing the PNP Pincer Ligand. Inorg. Chem. 2012, 51, 12527. <http://dx.doi.org/10.1021/ic301967r>
  • Montag Michael, Efremenko Irena, Diskin-Posner Yael, Ben-David Yehoshoa, Martin Jan M. L., Milstein David: Exclusive C–C Oxidative Addition in a Rhodium Thiophosphoryl Pincer Complex and Computational Evidence for an η3-C–C–H Agostic Intermediate. Organomettalics 2012, 31, 505. <http://dx.doi.org/10.1021/om201205y>
  • Gargir Moti, Ben-David Yehoshua, Leitus Gregory, Diskin-Posner Yael, Shimon Linda J. W., Milstein David: PNS-Type Ruthenium Pincer Complexes. Organometallics 2012, 31, 6207. <http://dx.doi.org/10.1021/om300516j>
  • Ghorai Debasish, Kumar Shanish, Mani Ganesan: Mononuclear, helical binuclear palladium and lithium complexes bearing a new pyrrole-based NNN-pincer ligand: fluxional property. Dalton Trans. 2012, 41, 9503. <http://dx.doi.org/10.1039/c2dt30816a>
  • Schwarz Helmut: Chemie mit Methan: Studieren geht über Probieren!. angew chemie 2011, 123, 10276. <http://dx.doi.org/10.1002/ange.201006424>
  • Schwarz Helmut: Chemistry with Methane: Concepts Rather than Recipes. Angew Chem Int E 2011, 50, 10096. <http://dx.doi.org/10.1002/anie.201006424>
  • Zeng Guixiang, Li Shuhua: Insights into Dehydrogenative Coupling of Alcohols and Amines Catalyzed by a (PNN)–Ru(II) Hydride Complex: Unusual Metal–Ligand Cooperation. Inrog Chem 2011, 50, 10572. <http://dx.doi.org/10.1021/ic200205e>
  • Kundu Sabuj, Brennessel William W., Jones William D.: Synthesis and Reactivity of New Ni, Pd, and Pt 2,6-Bis(di-tert-butylphosphinito)pyridine Pincer Complexes. Inorg. Chem. 2011, 50, 9443. <http://dx.doi.org/10.1021/ic201102v>
  • Albrecht Martin, Lindner Monika M.: Cleavage of unreactive bonds with pincer metal complexes. DALTON T 2011, 40, 8733. <http://dx.doi.org/10.1039/c1dt10339c>
  • Milstein David: Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation. Top Catal 2010, 53, 915. <http://dx.doi.org/10.1007/s11244-010-9523-7>
  • van���der���Vlugt Jarl���Ivar, Reek Joost���N.���H.: Neutrale dreiz��hnige PNP-Liganden und deren Hybrid-Analoga: vielseitige Liganden f��r die kooperative homogene Katalyse. Angew Chem 2009, 121, 8990. <http://dx.doi.org/10.1002/ange.200903193>
  • van���der���Vlugt Jarl���Ivar, Reek Joost���N.���H.: Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis. Angew Chem Int Ed 2009, 48, 8832. <http://dx.doi.org/10.1002/anie.200903193>
  • van der Vlugt Jarl Ivar, Lutz Martin, Pidko Evgeny A., Vogt Dieter, Spek Anthony L.: Cationic and neutral NiII complexes containing a non-innocent PNP ligand: formation of alkyl and thiolate species. Dalton Trans 2009, 1016. <http://dx.doi.org/10.1039/b814806f>
  • Schwartsburd Leonid, Cohen Revital, Konstantinovski Leonid, Milstein David: A Pincer-Type Anionic Platinum(0) Complex. Angew Chem 2008, 120, 3659. <http://dx.doi.org/10.1002/ange.200705927>
  • Schwartsburd Leonid, Cohen Revital, Konstantinovski Leonid, Milstein David: A Pincer-Type Anionic Platinum(0) Complex. Angew Chem Int Ed 2008, 47, 3603. <http://dx.doi.org/10.1002/anie.200705927>
  • Boro Brian J., Duesler Eileen N., Goldberg Karen I., Kemp Richard A.: An unprecedented bonding mode for potassium within a PCP-pincer palladium hydride–K-Selectride® complex. J Inorg Chem Commun 2008, 11, 1426. <http://dx.doi.org/10.1016/j.inoche.2008.09.021>
  • Klerman Yulie, Ben-Ari Eyal, Diskin-Posner Yael, Leitus Gregory, Shimon Linda J. W., Ben-David Yehoshoa, Milstein David: Pyridine-based SNS-iridium and -rhodium sulfide complexes, including d8–d8 metal–metal interactions in the solid state. Dalton Trans 2008, 3226. <http://dx.doi.org/10.1039/b802223b>
  • Gauvin Régis M., Rozenberg Haim, Shimon Linda J. W., Ben-David Yehoshoa, Milstein David: Osmium-Mediated CH and CC Bond Cleavage of a Phenolic Substrate:p-Quinone Methide and Methylene Arenium Pincer Complexes. Chem Eur J 2007, 13, 1382. <http://dx.doi.org/10.1002/chem.200601385>
  • Vuzman Dana, Poverenov Elena, Diskin-Posner Yael, Leitus Gregory, Shimon Linda J. W., Milstein David: Reactivity and stability of platinum(ii) formyl complexes based on PCP-type ligands. The significance of sterics. Dalton Trans 2007, 5692. <http://dx.doi.org/10.1039/b711444c>
  • Frech Christian M., Shimon Linda J. W., Milstein David: Ligand-Controlled Formation of a Low-Valent Pincer Rhodium(I)–Dioxygen Adduct Bearing a Very Short OO Bond. HCA 2006, 89, 1730. <http://dx.doi.org/10.1002/hlca.200690170>
  • Gagliardo Marcella, Havenith Remco W.A., van Klink Gerard, van Koten Gerard: (P-Bis(pentafluorophenyl) substituted) PCP-pincer Ru(II) complexes: A theoretical study of the molecular structure and electronic properties. J Organomet Chem 2006, 691, 4411. <http://dx.doi.org/10.1016/j.jorganchem.2006.01.035>
  • Böhme Diethard K., Schwarz Helmut: Gasphasenkatalyse mit atomaren und Cluster-Metall-Ionen: ultimative “Single-Site”-Katalysatoren. Angew Chem 2005, 117, 2388. <http://dx.doi.org/10.1002/ange.200461698>
  • Frech Christian M., Shimon Linda J. W., Milstein David: Redox-Induced Collapse and Regeneration of a Pincer-Type Complex Framework: A Nonplanar Coordination Mode of Palladium(II). Angew Chem 2005, 117, 1737. <http://dx.doi.org/10.1002/ange.200462386>
  • Böhme Diethard K., Schwarz Helmut: Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts. Angew Chem Int Ed 2005, 44, 2336. <http://dx.doi.org/10.1002/anie.200461698>
  • Frech Christian M., Shimon Linda J. W., Milstein David: Redox-Induced Collapse and Regeneration of a Pincer-Type Complex Framework: A Nonplanar Coordination Mode of Palladium(II). Angew Chem Int Ed 2005, 44, 1709. <http://dx.doi.org/10.1002/anie.200462386>
  • Kossoy Elizaveta, Iron Mark A., Rybtchinski Boris, Ben-David Yehoshoa, Shimon Linda J. W., Konstantinovski Leonid, Martin Jan M. L., Milstein David: π-Accepting-Pincer Rhodium Complexes: An Unusual Coordination Mode of PCP-Type Systems. Chem Eur J 2005, 11, 2319. <http://dx.doi.org/10.1002/chem.200401116>
  • van der Boom Milko E., Liou Shyh-Yeon, Shimon Linda J.W., Ben-David Yehoshoa, Milstein David: Nickel promoted C–H, C–C and C–O bond activation in solution. Inorganica Chimica Acta 2004, 357, 4015. <http://dx.doi.org/10.1016/j.ica.2004.06.002>
  • Milstein David: Challenging Metal-Based Transformations. From Single-Bond Activation to Catalysis and Metallaquinonoids. ChemInform 2003, 34. <http://dx.doi.org/10.1002/chin.200346270>