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Pure Appl. Chem., 2001, Vol. 73, No. 2, pp. 239-242

http://dx.doi.org/10.1351/pac200173020239

Some newer aspects of organozirconium chemistry of relevance to organic synthesis. Zr-Catalyzed enantioselective carbometallation

Ei-ichi Negishi

Herbert C. Brown Laboratories of Chemistry, Purdue University, West Lafayette, Indiana 47907-1393, USA

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  • Yan Xiaoyu, Zhou Yiqing, Xi Chanjuan: Reactivity of Alkynylzirconate toward α,β-Unsaturated Carbonyl Compounds. Organometallics 2013, 32, 869. <http://dx.doi.org/10.1021/om301176e>
  • Negishi Ei-ichi: Die magische Kraft der Übergangsmetalle: Vergangenheit, Gegenwart und Zukunft (Nobel-Aufsatz). angew chemie 2011, 123, 6870. <http://dx.doi.org/10.1002/ange.201101380>
  • Negishi Ei-ichi: Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture). Angew Chem Int E 2011, 50, 6738. <http://dx.doi.org/10.1002/anie.201101380>
  • Camara James M., Petros Robby A., Norton Jack R.: Zirconium-Catalyzed Carboalumination of α-Olefins and Chain Growth of Aluminum Alkyls: Kinetics and Mechanism. J Am Chem Soc 2011, 133, 5263. <http://dx.doi.org/10.1021/ja104032w>
  • Negishi Ei-Ichi: ChemInform Abstract: Some Newer Aspects of Organozirconium Chemistry of Relevance to Organic Synthesis: Zr-Catalyzed Enantioselective Carbometalation. ChemInform 2010, 32, no. <http://dx.doi.org/10.1002/chin.200142282>
  • Parfenova Lyudmila V., Berestova Tatyana V., Tyumkina Tatyana V., Kovyazin Pavel V., Khalilov Leonard M., Whitby Richard J., Dzhemilev Usein M.: Enantioselectivity of chiral zirconocenes as catalysts in alkene hydro-, carbo- and cycloalumination reactions. Tet Asymm 2010, 21, 299. <http://dx.doi.org/10.1016/j.tetasy.2010.01.001>
  • den Hartog Tim, Jan van Dijken Derk, Minnaard Adriaan J., Feringa Ben L.: An enantioselective catalytic approach to syn deoxypropionate units combining asymmetric Cu-catalyzed 1,6- and 1,4-conjugate addition. Tet Asymm 2010, 21, 1574. <http://dx.doi.org/10.1016/j.tetasy.2010.04.057>
  • ter Horst Bjorn, Feringa Ben L., Minnaard Adriaan J.: Iterative strategies for the synthesis of deoxypropionates. Chem Commun 2010, 46, 2535. <http://dx.doi.org/10.1039/b926265b>
  • Xi Chanjuan, Yan Xiaoyu, You Wei, Takahashi Tamotsu: Coupling Reactions of Zirconate Complexes Induced by Carbonyl Compounds. Angew Chem 2009, 121, 8264. <http://dx.doi.org/10.1002/ange.200904255>
  • Xi Chanjuan, Yan Xiaoyu, You Wei, Takahashi Tamotsu: Coupling Reactions of Zirconate Complexes Induced by Carbonyl Compounds. Angew Chem Int Ed 2009, 48, 8120. <http://dx.doi.org/10.1002/anie.200904255>
  • Seki Kazutaka, Yu Rongmin, Yamazaki Yumi, Yamashita Yasuhiro, Kobayashi Shū: Asymmetric meso-aziridine ring-opening reactions using a chiral zirconium catalyst. Chem Commun 2009, 5722. <http://dx.doi.org/10.1039/b914271c>
  • Nakamura Shinji, Yonehara Mitsuhiro, Uchiyama Masanobu: Silylmetalation of Alkenes. Chem Eur J 2008, 14, 1068. <http://dx.doi.org/10.1002/chem.200701118>
  • Fañanás Francisco J., Rodríguez Félix: Cross-Coupling–Elimination Reactions Mediated or Catalyzed by Zirconium Complexes: A Valuable Tool in Organic Synthesis. Eur J Org Chem 2008, 2008, 1315. <http://dx.doi.org/10.1002/ejoc.200700939>
  • Xi Chanjuan, Liu Yuanyuan, Yan Xiaoyu, Chen Chao: Zirconocene-promoted coupling reaction of terminal acetylenes to geminal enediynes in the presence of p-chloranil. J Organomet Chem 2007, 692, 4612. <http://dx.doi.org/10.1016/j.jorganchem.2007.04.028>
  • Seki Kazutaka, Ueno Masaharu, Kobayashi Sh?: Storable, powdered chiral zirconium complex for asymmetric aldol and hetero Diels?Alder reactions. Org Biomol Chem 2007, 5, 1347. <http://dx.doi.org/10.1039/b701466j>
  • Wipf Peter, Nunes Ruth L.: Selective carbon–carbon bond formations with alkenylzirconocenes. Tetrahedron 2004, 60, 1269. <http://dx.doi.org/10.1016/j.tet.2003.12.018>