Pure and Applied Chemistry

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• Lichtenberg Crispin, Okuda Jun: Strukturell definierte Allylverbindungen der Hauptgruppenmetalle: Koordination und Reaktivität. Angew. Chem. 2013, 125, 5336. <http://dx.doi.org/10.1002/ange.201208942>
• Incerti-Pradillos Celia A., Kabeshov Mikhail A., Malkov Andrei V.: Highly Stereoselective Synthesis of Z -Homoallylic Alcohols by Kinetic Resolution of Racemic Secondary Allyl Boronates. Angew. Chem. 2013, 125, 5446. <http://dx.doi.org/10.1002/ange.201300709>
• Lichtenberg Crispin, Okuda Jun: Structurally Defined Allyl Compounds of Main Group Metals: Coordination and Reactivity. Angew. Chem. Int. Ed. 2013, 52, 5228. <http://dx.doi.org/10.1002/anie.201208942>
• Incerti-Pradillos Celia A., Kabeshov Mikhail A., Malkov Andrei V.: Highly Stereoselective Synthesis of Z -Homoallylic Alcohols by Kinetic Resolution of Racemic Secondary Allyl Boronates. Angew. Chem. Int. Ed. 2013, 52, 5338. <http://dx.doi.org/10.1002/anie.201300709>
• Kobayashi Shū, Endo Toshimitsu, Yoshino Takumi, Schneider Uwe, Ueno Masaharu: Allylation Reactions of Aldehydes with Allylboronates in Aqueous Media: Unique Reactivity and Selectivity that are Only Observed in the Presence of Water. Chem. Asian J. 2013, 8, 2033. <http://dx.doi.org/10.1002/asia.201300440>
• Chen Jack L.-Y., Scott Helen K., Hesse Matthew J., Willis Christine L., Aggarwal Varinder K.: Highly Diastereo- and Enantioselective Allylboration of Aldehydes using α-Substituted Allyl/Crotyl Pinacol Boronic Esters via in Situ Generated Borinic Esters. J. Am. Chem. Soc. 2013, 135, 5316. <http://dx.doi.org/10.1021/ja401564z>
• Vahabi Roza, Frey Wolfgang, Pietruszka Jörg: Synthesis of Highly-Substituted Enantiomerically Pure Allylboronic Esters and Investigation of Their Stereoselective Addition to Aldehydes. J. Org. Chem. 2013, 78, 11549. <http://dx.doi.org/10.1021/jo402130u>
• Macé Aurélie, Tripoteau Fabien, Zhao Qian, Gayon Eric, Vrancken Emmanuel, Campagne Jean-Marc, Carboni Bertrand: Tandem Reactions Involving 1-Silyl-3-Boryl-2-Alkenes. New Access to (Z)-1-Fluoro-1-Alkenes, Allyl Fluorides, and Diversely α-Substituted Allylboronates. Org. Lett. 2013, 15, 906. <http://dx.doi.org/10.1021/ol4000263>
• Touchet Sabrina, Macé Aurélie, Roisnel Thierry, Carreaux François, Bouillon Alexandre, Carboni Bertrand: [3,3]-Sigmatropic Rearrangement of Boronated Allylcyanates: A New Route to α-Aminoboronate Derivatives and Trisubstituted Tetrahydrofurans. Org. Lett. 2013, 15, 2712. <http://dx.doi.org/10.1021/ol401016x>
• Kliman Laura T., Mlynarski Scott N., Ferris Grace E., Morken James P.: Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation. Angew. Chem. 2012, 124, 536. <http://dx.doi.org/10.1002/ange.201105716>
• Kliman Laura T., Mlynarski Scott N., Ferris Grace E., Morken James P.: Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation. Angew. Chem. Int. Ed. 2012, 51, 521. <http://dx.doi.org/10.1002/anie.201105716>
• Shao Panlin, Shen Litao, Ye Song: Enantioselective Synthesis of Terminal 1,2-Diols from Acyl Chlorides. Chin. J. Chem. 2012, n/a. <http://dx.doi.org/10.1002/cjoc.201200697>
• Ito Hajime, Miya Takanori, Sawamura Masaya: Practical procedure for copper(I)-catalyzed allylic boryl substitution with stoichiometric alkoxide base. Tetrahedron 2012, 68, 3423. <http://dx.doi.org/10.1016/j.tet.2011.08.081>
• Robinson Anna, Aggarwal Varinder K.: Stereocontrolled asymmetric synthesis of syn-E-1,4-diol-2-enes using allyl boronates and its application in the total synthesis of solandelactone F. Biomol Chem 2012, 10, 1795. <http://dx.doi.org/10.1039/c2ob06975j>
• Hall Dennis G., Lee Jack C. H., Ding Jinyue: Catalytic enantioselective transformations of borylated substrates: Preparation and synthetic applications of chiral alkylboronates. Pure Appl. Chem. 2012, 1. <http://dx.doi.org/10.1351/PAC-CON-12-02-04>
• Kobayashi Shū, Endo Toshimitsu, Ueno Masaharu: Chiral Zinc-Catalyzed Asymmetric α-Alkylallylation and α-Chloroallylation of Aldehydes. angew chemie 2011, 123, 12470. <http://dx.doi.org/10.1002/ange.201106433>
• Kobayashi Shū, Endo Toshimitsu, Ueno Masaharu: Chiral Zinc-Catalyzed Asymmetric α-Alkylallylation and α-Chloroallylation of Aldehydes. Angew Chem Int E 2011, 50, 12262. <http://dx.doi.org/10.1002/anie.201106433>
• Dao Hai Thanh, Schneider Uwe, Kobayashi Shū: “Design” of Boron-Based Compounds as Pro-Nucleophiles and Co-Catalysts for Indium(I)-Catalyzed Allyl Transfer to Various Csp3-Type Electrophiles. Chem —Asian J 2011, 6, 2522. <http://dx.doi.org/10.1002/asia.201100096>
• Schneider Uwe, Kobayashi Shū, Dao Hai Thanh: Indium(i)-catalyzed alkyl–allyl coupling between ethers and an allylborane. Chem Commun 2011, 47, 692. <http://dx.doi.org/10.1039/c0cc03673k>
• Sánchez Carolina, Ariza Xavier, Cornellà Josep, Farràs Jaume, Garcia Jordi, Ortiz Jordi: Stereodivergent Addition of 4-Silyloxy-1,2-Allenes to Aldehydes by Hydroboration. Chem Eur J 2010, 16, 11535. <http://dx.doi.org/10.1002/chem.201001563>
• Titan-Kohlenhydrat-Komplexe. Nachr Chem Tech Lab 2010, 38, 1244. <http://dx.doi.org/10.1002/nadc.19900381010>
• Cmrecki Vesna, Eichenauer Nils C., Frey Wolfgang, Pietruszka Jörg: Microwave assisted synthesis of enantiomerically pure allylboronates. Tetrahedron 2010, 66, 6550. <http://dx.doi.org/10.1016/j.tet.2010.04.100>
• Althaus Martin, Mahmood Adeem, Suárez José Ramón, Thomas Stephen P., Aggarwal Varinder K.: Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry. J Am Chem Soc 2010, 132, 4025. <http://dx.doi.org/10.1021/ja910593w>
• Ariza Xavier, Cornellà Josep, Font-Bardia Mercè, Garcia Jordi, Ortiz Jordi, Sánchez Carolina, Solans Xavier: Stereocontrolled Synthesis of Highly Functionalized Quaternary Carbon Centers: A Route to α-Substituted Serines. Angew Chem 2009, 121, 4266. <http://dx.doi.org/10.1002/ange.200900609>
• Cornellà Josep, Font-Bardia Mercè, Garcia Jordi, Ortiz Jordi, Sánchez Carolina, Solans Xavier, Ariza Xavier: Stereocontrolled Synthesis of Highly Functionalized Quaternary Carbon Centers: A Route to α-Substituted Serines. Angew Chem Int Ed 2009, 48, 4202. <http://dx.doi.org/10.1002/anie.200900609>
• Malkov Andrei V., Kabeshov Mikhail A., Barłog Maciej, Kočovský Pavel: Enantioselective and Catalytic Method for α-Crotylation of Aldehydes with a Kinetic Self-Refinement of Stereochemistry. Chem Eur J 2009, 15, 1570. <http://dx.doi.org/10.1002/chem.200802224>
• Berrée Fabienne, Gernigon Nicolas, Hercouet Alain, Lin Chia Hui, Carboni Bertrand: S_N2′ Boron-Mediated Mitsunobu Reactions - A New One-Pot Three-Component Synthesis of Substituted Enamides and Enol Benzoates. Eur J Org Chem 2009, 2009, 329. <http://dx.doi.org/10.1002/ejoc.200800965>
• Burks Heather E., Kliman Laura T., Morken James P.: Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration. J Am Chem Soc 2009, 131, 9134. <http://dx.doi.org/10.1021/ja809610h>
• Carosi Lisa, Hall Dennis G.: Chiral α-substituted allylboronates in a one-pot three-component asymmetric allylic alkylation/carbonyl allylation reaction sequence — Applications to the syntheses of (+)-(3R,5R)-3-hydroxy-5-decanolide and (–)-massoialactone. Can J Chem 2009, 87, 650. <http://dx.doi.org/10.1139/V09-036>
• Pietruszka Jörg, Schöne Niklas, Frey Wolfgang, Grundl Li: Diastereo- and Enantiomerically Pure Allylboronates: Their Synthesis and Scope. Chem Eur J 2008, 14, 5178. <http://dx.doi.org/10.1002/chem.200800034>
• Chataigner Isabelle, Zammattio Françoise, Lebreton Jacques, Villiéras Jean: Enantioselective addition of β-functionalized allylboronates to aldehydes and aldimines. Stereocontrolled synthesis of α-methylene-γ-lactones and lactams. Tetrahedron 2008, 64, 2441. <http://dx.doi.org/10.1016/j.tet.2007.12.046>
• Miyaura Norio: Metal-Catalyzed Reactions of Organoboronic Acids and Esters. Bull Chem Soc Jpn 2008, 81, 1535. <http://dx.doi.org/10.1246/bcsj.81.1535>
• Carosi Lisa, Hall Dennis G.: Catalytic Enantioselective Preparation of α-Substituted Allylboronates: One-Pot Addition to Functionalized Aldehydes and a Route to Chiral Allylic Trifluoroborate Reagents. Angew Chem 2007, 119, 6017. <http://dx.doi.org/10.1002/ange.200700975>
• Carosi Lisa, Hall Dennis G.: Catalytic Enantioselective Preparation of α-Substituted Allylboronates: One-Pot Addition to Functionalized Aldehydes and a Route to Chiral Allylic Trifluoroborate Reagents. Angew Chem Int Ed 2007, 46, 5913. <http://dx.doi.org/10.1002/anie.200700975>
• Peng Feng, Hall Dennis G.: Preparation of α-substituted allylboronates by chemoselective iridium-catalyzed asymmetric allylic alkylation of 1-propenylboronates. Tetrahetron Lett 2007, 48, 3305. <http://dx.doi.org/10.1016/j.tetlet.2007.02.124>
• Gao Xuri, Hall Dennis G., Deligny Michael, Favre Annaick, Carreaux François, Carboni Bertrand: Catalytic Enantioselective Three-Component Hetero-[4+2] Cycloaddition/Allylboration Approach to α-Hydroxyalkyl Pyrans: Scope, Limitations, and Mechanistic Proposal. Chem Eur J 2006, 12, 3132. <http://dx.doi.org/10.1002/chem.200501197>
• Dragutan Valerian, Dragutan Ileana: A resourceful new strategy in organic synthesis: Tandem and stepwise metathesis/non-metathesis catalytic processes. J Organomet Chem 2006, 691, 5129. <http://dx.doi.org/10.1016/j.jorganchem.2006.08.012>
• Christoffers Jens, Baro Angelika: Stereoselective Construction of Quaternary Stereocenters. Adv Synth Catal 2005, 347, 1473. <http://dx.doi.org/10.1002/adsc.200505165>
• Carosi Lisa, Lachance Hugo, Hall Dennis G.: Additions of functionalized α-substituted allylboronates to aldehydes under the novel Lewis and Brønsted acid catalyzed manifolds. Tetrahetron Lett 2005, 46, 8981. <http://dx.doi.org/10.1016/j.tetlet.2005.10.115>
• Ramachandran P. Veeraraghavan, Pratihar Debarshi, Biswas Debanjan: Synthesis of 4-substituted homoallylic alcohols via a one-pot tandem Lewis-acid catalyzed crotylboration-[3,3]-sigmatropic rearrangement. Chem Commun 2005, 1988. <http://dx.doi.org/10.1039/b418996e>
• Ramachandran P. Veeraraghavan, Chandra J. Subash, Prabhudas Bodhuri, Pratihar Debarshi, Reddy M.Venkat Ram: Studies towards the synthesis of epothilone A via organoboranes. Org Biomol Chem 2005, 3, 3812. <http://dx.doi.org/10.1039/b508001k>
• Pietruszka Jörg, Schöne Niklas: New 1,3-Disubstituted Enantiomerically Pure Allylboronic Esters by Johnson Rearrangement of Boron-Substituted Allyl Alcohols. Eur J Org Chem 2004, 2004, 5011. <http://dx.doi.org/10.1002/ejoc.200400572>
• Prabhudas Bodhuri, Ramachandran P.Veeraraghavan, Chandra J.Subash, Reddy M.Venkat Ram, Brown Herbert C.: Preparative-scale synthesis of both antipodes of B-γ,γ-dimethylallyldiisopinocampheylborane: application for the synthesis of C1–C6 subunit of epothilone. Tetrahetron Lett 2004, 45, 1011. <http://dx.doi.org/10.1016/j.tetlet.2003.11.087>
• Ramachandran P. Veeraraghavan, Pratihar Debarshi, Biswas Debanjan, Srivastava Amit, Ram Reddy M. Venkat: Novel Functionalized Trisubstituted Allylboronates via Hosomi−Miyaura Borylation of Functionalized Allyl Acetates. Org Lett 2004, 6, 481. <http://dx.doi.org/10.1021/ol035952z>
• Ramachandran P. Veeraraghavan, Liu Haipeng, Ram Reddy M. Venkat, Brown Herbert C.: Synthesis of Homoallylic Chiral Tertiary Alcohols via Chelation-Controlled Diastereoselective Nucleophilic Addition on α-Alkoxyketones:  Application for the Synthesis of the C₁−C₁₁ Subunit of 8-epi-Fostriecin. Org Lett 2003, 5, 3755. <http://dx.doi.org/10.1021/ol035516c>
• Goldberg Steven D., Grubbs Robert H.: A One-Pot Cross-Metathesis/Allylboration Reaction: A Three-Component Coupling for the Synthesis of Functionalized Homoallylic Alcohols. Angew Chem 2002, 114, 835. <http://dx.doi.org/10.1002/1521-3757(20020301)114:5<835::AID-ANGE835>3.0.CO;2-7>
• Hupe Eike, Marek Ilan, Knochel Paul: Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers in Cyclic and Acyclic Molecules. Org Lett 2002, 4, 2861. <http://dx.doi.org/10.1021/ol0262486>
• Schlapbach Achim, Hoffmann Reinhard W.: (E)-α-Sulfonamidocrotylboronates as Reagents for the Stereoselective Homoaldol Synthesis. Eur J Org Chem 2001, 2001, 323. <http://dx.doi.org/10.1002/1099-0690(200101)2001:2<323::AID-EJOC323>3.0.CO;2-A>
• Hunter Thomas J., O'Doherty George A.: An Enantioselective Synthesis of Benzylidene-Protected syn-3,5-Dihydroxy Carboxylate Esters via Osmium, Palladium, and Base Catalysis. Org Lett 2001, 3, 1049. <http://dx.doi.org/10.1021/ol0156188>
• Vorontsova N. V., Rozenberg V. I., Vorontsov E. V., Tok O. L., Bubnov Yu. N.: Stereoselective synthesis of homoallylic alcohols of the [2.2]paracyclophane series and their use as auxiliaries in asymmetric allylboration of aldehydes. Russ Chem Bull 2000, 49, 912. <http://dx.doi.org/10.1007/BF02494718>
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• Hafner Andreas, Duthaler Rudolf O., Marti Roger, Rihs Grety, Rothe-Streit Petra, Schwarzenbach Franz: Enantioselective syntheses with titanium carbohydrate complexes. Part 7. Enantioselective allyltitanation of aldehydes with cyclopentadienyldialkoxyallyltitanium complexes. S J Am Chem Soc 1992, 114, 2321. <http://dx.doi.org/10.1021/ja00033a005>
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