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Pure Appl. Chem., 2012, Vol. 84, No. 8, pp. 1759-1769

Published online 2012-02-03

Catalytic asymmetric synthesis using chirality‑switchable helical polymer as a chiral ligand

Michinori Suginome1,2*, Takeshi Yamamoto2, Yuuya Nagata2, Tetsuya Yamada2 and Yuto Akai2

1 CREST, JST, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
2 Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Kyoto, Japan

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  • Nagata Yuuya, Yamada Tetsuya, Adachi Takumi, Akai Yuto, Yamamoto Takeshi, Suginome Michinori: Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the “Sergeant” Chiral Units on the Screw-Sense Induction. J. Am. Chem. Soc. 2013, 135, 10104. <>
  • Raynal Matthieu, Portier François, van Leeuwen Piet W. N. M., Bouteiller Laurent: Tunable Asymmetric Catalysis through Ligand Stacking in Chiral Rigid Rods. J. Am. Chem. Soc. 2013, 135, 17687. <>
  • Yamamoto Takeshi, Adachi Takumi, Suginome Michinori: Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (−)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s. ACS Macro Lett. 2013, 2, 790. <>
  • Sohtome Yoshihiro, Yamaguchi Takahisa, Tanaka Shinji, Nagasawa Kazuo: Sequential enantiodivergent organocatalysis: reversibility in enantioswitching controlled by a conformationally flexible guanidine/bisthiourea organocatalyst. Org. Biomol. Chem. 2013, 11, 2780. <>
  • Suginome Michinori, Yamamoto Takeshi, Nagata Yuuya, Yamada Tetsuya, Akai Yuto: ChemInform Abstract: Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand. ChemInform 2012, 43, no. <>