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Pure Appl. Chem., 2011, Vol. 83, No. 7, pp. 1343-1349

Published online 2011-04-30

Solvent-free reactions of alkynes in ball mills: It is definitely more than mixing

Achim Stolle* and Bernd Ondruschka

Institute for Technical Chemistry and Environmental Chemistry, Friedrich-Schiller University Jena, Lessingstraße 12, D-07743 Jena, Germany

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  • Chen Longrui, Lemma Betsegaw E., Rich Jenna S., Mack James: Freedom: a copper-free, oxidant-free and solvent-free palladium catalysed homocoupling reaction. Green Chem. 2014, 16, 1101. <>
  • Cheng Guolin, Zhang Hong, Cui Xiuling: Copper(i)-catalyzed homo-coupling of terminal alkynes at room temperature under solvent and base free conditions using O2 as an oxidant. RSC Adv. 2014, 4, 1849. <>
  • Brahmachari Goutam, Das Suvankar: l-Proline catalyzed multicomponent one-pot synthesis of gem-diheteroarylmethane derivatives using facile grinding operation under solvent-free conditions at room temperature. RSC Adv. 2014, 4, 7380. <>
  • Rossi Renzo, Bellina Fabio, Lessi Marco, Manzini Chiara: Development and applications of highly selective palladium-catalyzed monocoupling reactions of (cyclo)alkenes and 1,3-alkadienes bearing two or three electrophilic sites and bis(enol triflates) with terminal alkynes. Tetrahedron 2013, 69, 7869. <>
  • Allen Scott E., Walvoord Ryan R., Padilla-Salinas Rosaura, Kozlowski Marisa C.: Aerobic Copper-Catalyzed Organic Reactions. Chem. Rev. 2013, 113, 6234. <>
  • Wang Guan-Wu: Mechanochemical organic synthesis. Chem. Soc. Rev. 2013, 42, 7668. <>
  • Chartoire Anthony, Boreux Arnaud, Martin Anthony R., Nolan Steven P.: Solvent-free aryl amination catalysed by [Pd(NHC)] complexes. RSC Adv. 2013, 3, 3840. <>
  • Štrukil Vjekoslav, Igrc Marina D., Fábián László, Eckert-Maksić Mirjana, Childs Scott L., Reid David G., Duer Melinda J., Halasz Ivan, Mottillo Cristina, Friščić Tomislav: A model for a solvent-free synthetic organic research laboratory: click-mechanosynthesis and structural characterization of thioureas without bulk solvents. Green Chem. 2012, 14, 2462. <>