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Pure Appl. Chem., 2010, Vol. 82, No. 9, pp. 1797-1812

Published online 2010-06-28

Intramolecular annulations of donor–acceptor cyclopropanes

Terry P. Lebold and Michael A. Kerr*

Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7, Canada

Abstract: The intramolecular reaction of donor–acceptor cyclopropanes with various dipoles and dipolar equivalents allows access to a variety of bicyclic adducts with good stereocontrol. The linkers can often be cleaved to provide stereodefined products.