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Pure Appl. Chem., 2010, Vol. 82, No. 8, pp. 1663-1671

http://dx.doi.org/10.1351/PAC-CON-09-11-10

Published online 2010-05-18

Comparison of donor properties of N‑heterocyclic carbenes and N-donors containing the 1H-pyridin-(2E)-ylidene motif

John Slattery, Robert J. Thatcher, Qi Shi and Richard E. Douthwaite*

Department of Chemistry, University of York, Heslington, York YO10 5DD, UK

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  • John Alex, Modak Sudipta, Madasu Mahesh, Katari Madanakrishna, Ghosh Prasenjit: Palladium complexes of the N-fused heterocycle derived abnormal N-heterocyclic carbenes for the much-preferred Cu-free and the amine-free Sonogashira coupling in air. Polyhedron 2013, 64, 20. <http://dx.doi.org/10.1016/j.poly.2013.01.062>
  • Sahin Cigdem, VarliklI Canan, Zafer Ceylan, Shi Qi, Douthwaite Richard E.: A new 1H-pyridin-(2E)-ylidene ruthenium complex as sensitizer for a dye-sensitized solar cell. Journal of Coordination Chemistry 2013, 66, 1384. <http://dx.doi.org/10.1080/00958972.2013.782486>
  • Siemeling Ulrich, Färber Christian, Bruhn Clemens, Fürmeier Sven, Schulz Tim, Kurlemann Michael, Tripp Sandra: Group 10 Metal Complexes of a Ferrocene-Based N-Heterocyclic Carbene: Syntheses, Structures and Catalytic Applications. Euro J Inorg Chem 2012, 2012, 1413. <http://dx.doi.org/10.1002/ejic.201100856>
  • Budagumpi Srinivasa, Haque Rosenani A., Salman Abbas Washeel: Stereochemical and structural characteristics of single- and double-site Pd(II)–N-heterocyclic carbene complexes: Promising catalysts in organic syntheses ranging from CC coupling to olefin polymerizations. Coordination Chemistry Reviews 2012, 256, 1787. <http://dx.doi.org/10.1016/j.ccr.2012.04.003>
  • Färber Christian, Leibold Michael, Bruhn Clemens, Maurer Martin, Siemeling Ulrich: Nitron: a stable N-heterocyclic carbene that has been commercially available for more than a century. Chem Commn 2012, 48, 227. <http://dx.doi.org/10.1039/c1cc16460k>
  • Boyd Peter D. W., Wright L. James, Zafar M. Naveed: Extending the Range of Neutral N-Donor Ligands Available for Metal Catalysts: N-[1-Alkylpyridin-4(1H)-ylidene]amides in Palladium-Catalyzed Cross-Coupling Reactions. Inrog Chem 2011, 50, 10522. <http://dx.doi.org/10.1021/ic201527s>