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Pure Appl. Chem., 2010, Vol. 82, No. 7, pp. 1537-1544

http://dx.doi.org/10.1351/PAC-CON-09-10-18

Published online 2010-05-04

Alkynes as “masked” ylides under noble‑metal catalysis

Paul W. Davies

School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK

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  • Zhang Liming: A Non-Diazo Approach to α-Oxo Gold Carbenes via Gold-Catalyzed Alkyne Oxidation. Acc. Chem. Res. 2014, 47, 877. <http://dx.doi.org/10.1021/ar400181x>
  • Li Jiabin, Ji Kegong, Zheng Renhua, Nelson Jonathan, Zhang Liming: Expanding the horizon of intermolecular trapping of in situ generated α-oxo gold carbenes: efficient oxidative union of allylic sulfides and terminal alkynes via C–C bond formation. Chem. Commun. 2014, 50, 4130. <http://dx.doi.org/10.1039/c4cc00739e>
  • Xu Mei, Ren Tian-Tian, Wang Kai-Bing, Li Chuan-Ying: Synthesis of Cyclobutanones via Gold-Catalyzed Oxidative Rearrangement of Homopropargylic Ethers. Adv. Synth. Catal. 2013, n/a. <http://dx.doi.org/10.1002/adsc.201300227>
  • Lu Biao, Li Yuxue, Wang Youliang, Aue Donald H., Luo Yingdong, Zhang Liming: [3,3]-Sigmatropic Rearrangement versus Carbene Formation in Gold-Catalyzed Transformations of Alkynyl Aryl Sulfoxides: Mechanistic Studies and Expanded Reaction Scope. J. Am. Chem. Soc. 2013, 135, 8512. <http://dx.doi.org/10.1021/ja401343p>
  • Kramer Søren, Skrydstrup Troels: Gold-Catalyzed Carbene Transfer to Alkynes: Access to 2,4-Disubstituted Furans. Angew. Chem. 2012, 124, 4759. <http://dx.doi.org/10.1002/ange.201200307>
  • Kramer Søren, Skrydstrup Troels: Gold-Catalyzed Carbene Transfer to Alkynes: Access to 2,4-Disubstituted Furans. Angew. Chem. Int. Ed. 2012, 51, 4681. <http://dx.doi.org/10.1002/anie.201200307>
  • Davies Paul W., Cremonesi Alex, Dumitrescu Lidia: Intermolecular and Selective Synthesis of 2,4,5-Trisubstituted Oxazoles by a Gold-Catalyzed Formal [3+2] Cycloaddition. angew chemie 2011, 123, 9093. <http://dx.doi.org/10.1002/ange.201103563>
  • Davies Paul W., Cremonesi Alex, Dumitrescu Lidia: Intermolecular and Selective Synthesis of 2,4,5-Trisubstituted Oxazoles by a Gold-Catalyzed Formal [3+2] Cycloaddition. Angew Chem Int E 2011, 50, 8931. <http://dx.doi.org/10.1002/anie.201103563>
  • Davies Paul W.: ChemInform Abstract: Alkynes as “Masked” Ylides under Noble-Metal Catalysis. ChemInform 2011, 42, no. <http://dx.doi.org/10.1002/chin.201127209>