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Pure Appl. Chem., 2010, Vol. 82, No. 7, pp. 1471-1483

http://dx.doi.org/10.1351/PAC-CON-09-09-11

Published online 2010-05-04

Aerobic oxidation with bifunctional molecular catalysts

Takao Ikariya*, Shigeki Kuwata and Yoshihito Kayaki

Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama 2-12-1-E4-1, Meguro-ku, Tokyo 152‑8552, Japan

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  • Mizoguchi Hirotaka, Uchida Tatsuya, Katsuki Tsutomu: Ruthenium-Catalyzed Oxidative Kinetic Resolution of Unactivated and Activated Secondary Alcohols with Air as the Hydrogen Acceptor at Room Temperature. Angew. Chem. 2014, 126, 3242. <http://dx.doi.org/10.1002/ange.201310426>
  • Mizoguchi Hirotaka, Uchida Tatsuya, Katsuki Tsutomu: Ruthenium-Catalyzed Oxidative Kinetic Resolution of Unactivated and Activated Secondary Alcohols with Air as the Hydrogen Acceptor at Room Temperature. Angew. Chem. Int. Ed. 2014, 53, 3178. <http://dx.doi.org/10.1002/anie.201310426>
  • Kamitani Masahiro, Nishiguchi Yoshinori, Tada Ryosuke, Itazaki Masumi, Nakazawa Hiroshi: Synthesis of Fe–H/Si–H and Fe–H/Ge–H Bifunctional Complexes and Their Catalytic Hydrogenation Reactions toward Nonpolar Unsaturated Organic Molecules. Organometallics 2014, 33, 1532. <http://dx.doi.org/10.1021/om5000562>
  • Bartoszewicz Agnieszka, Ahlsten Nanna, Martín-Matute Belén: Enantioselective Synthesis of Alcohols and Amines by Iridium-Catalyzed Hydrogenation, Transfer Hydrogenation, and Related Processes. Chem. Eur. J. 2013, 19, 7274. <http://dx.doi.org/10.1002/chem.201202836>
  • Suzuki Chiharu, Hirano Koji, Satoh Tetsuya, Miura Masahiro: Ruthenium-Catalyzed Regioselective C–H Alkenylation Directed by a Free Amino Group. Org. Lett. 2013, 15, 3990. <http://dx.doi.org/10.1021/ol401779h>
  • Bartoszewicz Agnieszka, Marcos Rocío, Sahoo Suman, Inge A. Ken, Zou Xiaodong, Martín-Matute Belén: A Highly Active Bifunctional Iridium Complex with an Alcohol/Alkoxide-Tethered N-Heterocyclic Carbene for Alkylation of Amines with Alcohols. Chem. Eur. J. 2012, 18, 14510. <http://dx.doi.org/10.1002/chem.201201845>
  • Kashiwame Yohei, Kuwata Shigeki, Ikariya Takao: Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation. Organometallics 2012, 31, 8444. <http://dx.doi.org/10.1021/om301063n>
  • Pellissier Hélène: Catalytic Non-Enzymatic Kinetic Resolution. Synth Catal 2011, 353, 1613. <http://dx.doi.org/10.1002/adsc.201100111>
  • Kuwata Shigeki, Ikariya Takao: β-Protic Pyrazole and N-Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis. Chem Eur J 2011, 17, 3542. <http://dx.doi.org/10.1002/chem.201003296>
  • Aiki Shota, Taketoshi Ayako, Kuwabara Junpei, Koizumi Take-aki, Kanbara Takaki: The catalytic activity of a cyclometalated ruthenium(III) complex for aerobic oxidative dehydrogenation of benzylamines. J Organomet Chem 2011, 696, 1301. <http://dx.doi.org/10.1016/j.jorganchem.2010.10.063>
  • Taketoshi Ayako, Koizumi Take-aki, Kanbara Takaki: Aerobic oxidative dehydrogenation of benzylamines catalyzed by a cyclometalated ruthenium complex. Tetrahetron Lett 2010, 51, 6457. <http://dx.doi.org/10.1016/j.tetlet.2010.10.004>