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Pure Appl. Chem., 2010, Vol. 82, No. 7, pp. 1461-1469

http://dx.doi.org/10.1351/PAC-CON-09-09-10

Published online 2010-05-04

Highly enantioselective isomerization of primary allylic alcohols catalyzed by (P,N)-iridium complexes

Luca Mantilli, David Gérard, Sonya Torche, Céline Besnard and Clément Mazet*

Department of Organic Chemistry, University of Geneva, quai Ernest Ansermet 30, CH-1211 Geneva 4, Switzerland

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  • Bernasconi Maurizio, Ramella Vincenzo, Tosatti Paolo, Pfaltz Andreas: Iridium-Catalyzed Asymmetric Hydrogenation of 3,3-Disubstituted Allylic Alcohols in Ethereal Solvents. Chem. Eur. J. 2014, 20, 2440. <http://dx.doi.org/10.1002/chem.201303915>
  • Ren Kai, Hu Bei, Zhao Mengmeng, Tu Yahui, Xie Xiaomin, Zhang Zhaoguo: Ruthenium-Catalyzed Oxidation of Allyl Alcohols with Intermolecular Hydrogen Transfer: Synthesis of α,β-Unsaturated Carbonyl Compounds. J. Org. Chem. 2014, 79, 2170. <http://dx.doi.org/10.1021/jo500042h>
  • Menéndez-Rodríguez Lucía, Crochet Pascale, Cadierno Victorio: Catalytic isomerization of allylic alcohols promoted by complexes [RuCl2(η6-arene)(PTA-Me)] under homogeneous conditions and supported on Montmorillonite K-10. Journal of Molecular Catalysis A: Chemical 2013, 366, 390. <http://dx.doi.org/10.1016/j.molcata.2012.10.025>
  • Mantilli Luca, Gérard David, Besnard Céline, Mazet Clément: Structure-Activity Relationship in the Iridium-Catalyzed Isomerization of Primary Allylic Alcohols. Eur. J. Inorg. Chem. 2012, 2012, 3320. <http://dx.doi.org/10.1002/ejic.201200369>
  • Lorenzo-Luis Pablo, Romerosa Antonio, Serrano-Ruiz Manuel: Catalytic Isomerization of Allylic Alcohols in Water. ACS Catal. 2012, 1079. <http://dx.doi.org/10.1021/cs300092d>
  • Quintard Adrien, Alexakis Alexandre, Mazet Clément: Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis. Angew. Chem. 2011, 123, 2402. <http://dx.doi.org/10.1002/ange.201007001>
  • Quintard Adrien, Alexakis Alexandre, Mazet Clément: Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis. Angew. Chem. Int. Ed. 2011, 50, 2354. <http://dx.doi.org/10.1002/anie.201007001>
  • Varela-Álvarez Adrián, Sordo José A., Piedra Estefanía, Nebra Noel, Cadierno Victorio, Gimeno José: Ruthenium(IV)-Catalyzed Isomerization of the CC Bond of O-Allylic Substrates: A Theoretical and Experimental Study. Chemistry A European Journal 2011, 17, 10583. <http://dx.doi.org/10.1002/chem.201101131>
  • Fernández-Zúmel Mariano A., Lastra-Barreira Beatriz, Scheele Marcus, Díez Josefina, Crochet Pascale, Gimeno José: Chiral phosphonite, phosphite and phosphoramidite η6-arene-ruthenium(ii) complexes: application to the kinetic resolution of allylic alcohols. Dalton Trans 2010, 39, 7780. <http://dx.doi.org/10.1039/c0dt00140f>