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Pure Appl. Chem., 2010, Vol. 82, No. 7, pp. 1415-1428

http://dx.doi.org/10.1351/PAC-CON-09-10-37

Published online 2010-05-06

Catalytic activation of hydrogen, silicon, and fluorine by transition-metal complexes

Waqar Rauf, Amaruka Hazari, Véronique Gouverneur and John M. Brown*

Chemistry Research Laboratory, 12 Mansfield Rd., Oxford OX1 3TA

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  • Okuda Yasuhiro, Ishiguro Yuya, Mori Seiji, Nakajima Kiyohiko, Nishihara Yasushi: Experimental and Theoretical Studies on the Platinum-Mediated Selective C(sp)–Si Bond Cleavage of Alkynylsilanes. Organometallics 2014, 33, 1878. <http://dx.doi.org/10.1021/om5002588>
  • Zhang He, Lin Jin-Hong, Xiao Ji-Chang, Gu Yu-Cheng: Rh-catalyzed allylic C–F bond activation: the stereoselective synthesis of trisubstituted monofluoroalkenes and a mechanism study. Org. Biomol. Chem. 2014, 12, 581. <http://dx.doi.org/10.1039/c3ob42038h>
  • Kuganathan Navaratnarajah, Veal Edward, Green Malcolm L. H., Green Jennifer C., Pascu Sofia I.: Exploring Pathways for Activation of Carbon Monoxide by Palladium Iminophosphines. ChemPlusChem 2013, 78, 1413. <http://dx.doi.org/10.1002/cplu.201300214>
  • Liang Yun, Geng Weizhi, Wei Junnian, Xi Zhenfeng: Palladium-Catalyzed Intermolecular Coupling of 2-Silylaryl Bromides with Alkynes: Synthesis of Benzosiloles and Heteroarene-Fused Siloles by Catalytic Cleavage of the C(sp3)Si Bond. angew chemie 2012, 124, 1970. <http://dx.doi.org/10.1002/ange.201108154>
  • Liang Yun, Geng Weizhi, Wei Junnian, Xi Zhenfeng: Palladium-Catalyzed Intermolecular Coupling of 2-Silylaryl Bromides with Alkynes: Synthesis of Benzosiloles and Heteroarene-Fused Siloles by Catalytic Cleavage of the C(sp3)Si Bond. Angew Chem Int E 2012, 51, 1934. <http://dx.doi.org/10.1002/anie.201108154>
  • Ishida Naoki, Ikemoto Wataru, Murakami Masahiro: Intramolecular σ-Bond Metathesis Between Carbon–Carbon and Silicon–Silicon Bonds. Org. Lett. 2012, 14, 3230. <http://dx.doi.org/10.1021/ol301280u>
  • Hollingworth Charlotte, Hazari Amaruka, Hopkinson Matthew N., Tredwell Matthew, Benedetto Elena, Huiban Mickael, Gee Antony D., Brown John M., Gouverneur Véronique: Palladium-Catalyzed Allylic Fluorination. Angew Chem 2011, 123, 2661. <http://dx.doi.org/10.1002/ange.201007307>
  • Hollingworth Charlotte, Hazari Amaruka, Hopkinson Matthew N., Tredwell Matthew, Benedetto Elena, Huiban Mickael, Gee Antony D., Brown John M., Gouverneur Véronique: Palladium-Catalyzed Allylic Fluorination. Angew Chem Int Ed 2011, 50, 2613. <http://dx.doi.org/10.1002/anie.201007307>
  • Liang Yun, Zhang Shaoguang, Xi Zhenfeng: Palladium-Catalyzed Synthesis of Benzosilolo[2,3-b]indoles via Cleavage of a C(sp3)–Si Bond and Consequent Intramolecular C(sp2)–Si Coupling. J Am Chem Soc 2011, 133, 9204. <http://dx.doi.org/10.1021/ja2024959>
  • Luo Qian, Wang Chao, Li Yuexing, Ouyang Kunbing, Gu Li, Uchiyama Masanobu, Xi Zhenfeng: Opening the silole ring: Efficient and specific cleavage of the endo-C(sp2)-Si bond with AcOH/ROH system. Chem Sci 2011, 2, 2271. <http://dx.doi.org/10.1039/c1sc00356a>