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Pure Appl. Chem., 2010, Vol. 82, No. 11, pp. 2005-2016

http://dx.doi.org/10.1351/PAC-CON-09-12-06

Published online 2010-08-01

Formal Lewis acidic character of gold nanocluster catalyst

Hidehiro Sakurai1,2,3*, Ikuyo Kamiya2 and Hiroaki Kitahara3

1 PRESTO, Japan Science and Technology Agency, Tokyo 102-0075, Japan
2 Research Center for Molecular Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan
3 School of Physical Science, The Graduate University for Advanced Studies, Myodaiji, Okazaki 444-8787, Japan

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  • Haesuwannakij Setsiri, Karuehanon Weeranuch, Mishra Vijay Laksami, Kitahara Hiroaki, Sakurai Hidehiro, Kanaoka Shokyoku, Aoshima Sadahito: Size-controlled preparation of gold nanoclusters stabilized by high-viscosity hydrophilic polymers using a microflow reactor. Monatsh Chem 2014, 145, 23. <http://dx.doi.org/10.1007/s00706-013-1001-z>
  • Lee Li-Chen, Zhao Yan: Room Temperature Hydroamination of Alkynes Catalyzed by Gold Clusters in Interfacially Cross-Linked Reverse Micelles. ACS Catal. 2014, 4, 688. <http://dx.doi.org/10.1021/cs401213c>
  • Oliver-Meseguer Judit, Leyva-Pérez Antonio, Corma Avelino: Very Small (3-6 Atoms) Gold Cluster Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond-Forming Reactions in Solution. ChemCatChem 2013, 5, 3509. <http://dx.doi.org/10.1002/cctc.201300695>
  • Mitsudome Takato, Yamamoto Yuya, Noujima Akifumi, Mizugaki Tomoo, Jitsukawa Koichiro, Kaneda Kiyotomi: Highly Efficient Etherification of Silanes by Using a Gold Nanoparticle Catalyst: Remarkable Effect of O2. Chem. Eur. J. 2013, 19, 14398. <http://dx.doi.org/10.1002/chem.201302807>
  • Li Lei, Huang Genping, Chen Zhou, Liu Wei, Wang Xiufang, Chen Yanmei, Yang Lijuan, Li Wu, Li Yahong: Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT. Eur. J. Org. Chem. 2012, 2012, 5564. <http://dx.doi.org/10.1002/ejoc.201200829>
  • Zhang Yan, Cui Xinjiang, Shi Feng, Deng Youquan: Nano-Gold Catalysis in Fine Chemical Synthesis. Chemistry Review 2012, 112, 2467. <http://dx.doi.org/10.1021/cr200260m>
  • Stratakis Manolis, Garcia Hermenegildo: Catalysis by Supported Gold Nanoparticles: Beyond Aerobic Oxidative Processes. Chem. Rev. 2012, 112, 4469. <http://dx.doi.org/10.1021/cr3000785>
  • Dhital Raghu Nath, Kamonsatikul Choavarit, Somsook Ekasith, Bobuatong Karan, Ehara Masahiro, Karanjit Sangita, Sakurai Hidehiro: Low-Temperature Carbon–Chlorine Bond Activation by Bimetallic Gold/Palladium Alloy Nanoclusters: An Application to Ullmann Coupling. J. Am. Chem. Soc. 2012, 134, 20250. <http://dx.doi.org/10.1021/ja309606k>
  • Oliver-Meseguer J., Cabrero-Antonino J. R., Dominguez I., Leyva-Perez A., Corma A.: Small Gold Clusters Formed in Solution Give Reaction Turnover Numbers of 107 at Room Temperature. Science 2012, 338, 1452. <http://dx.doi.org/10.1126/science.1227813>
  • Tsukuda Tatsuya, Tsunoyama Hironori, Sakurai Hidehiro: Aerobic Oxidations Catalyzed by Colloidal Nanogold. Chem Asian J 2011, 6, 736. <http://dx.doi.org/10.1002/asia.201000611>
  • Sakurai Hidehiro, Kamiya Ikuyo, Kitahara Hiroaki: ChemInform Abstract: Formal Lewis Acidic Character of Gold Nanocluster Catalyst. ChemInform 2011, 42, no. <http://dx.doi.org/10.1002/chin.201136235>