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Pure Appl. Chem., 2009, Vol. 81, No. 7, pp. 1279-1296

Published online 2009-06-29

Vanadium-salen and -salan complexes: Characterization and application in oxygen-transfer reactions

Pedro Adão1, Mannar R. Maurya2, Umesh Kumar2, Fernando Avecilla3, Rui T. Henriques1, Maxim L. Kusnetsov1, João Costa Pessoa1* and Isabel Correia1*

1 Centro Química Estrutural, Instituto Superior Técnico, TU Lisbon, Av. Rovísco Pais, 1049-001 Lisbon, Portugal
2 Department of Chemistry, Indian Institute of Technology, Roorkee 247667, India
3 Departamento de Química Fundamental, Universidade da Coruña, Campus da A Zapateira, 15071, A Coruña, Spain

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  • Huber Stefan, Cokoja Mirza, Kühn Fritz E.: Historical landmarks of the application of molecular transition metal catalysts for olefin epoxidation. Journal of Organometallic Chemistry 2014, 751, 25. <>
  • Adão Pedro, Barroso Sónia, Avecilla Fernando, Oliveira M. Conceição, Pessoa João Costa: CuII–salan compounds: Synthesis, characterization and evaluation of their potential as oxidation catalysts. Journal of Organometallic Chemistry 2014, 760, 212. <>
  • Naskar Sumita, Naskar Subhendu, Butcher Ray J., Corbella Montserrat, Espinosa Ferao Arturo, Chattopadhyay Shyamal Kumar: Synthesis, X-ray Crystal Structures, and Spectroscopic, Electrochemical, and Theoretical Studies of MnIII Complexes of Pyridoxal Schiff Bases with Two Diamines. Eur. J. Inorg. Chem. 2013, 2013, 3249. <>
  • Barman Sanmitra, Patil Smita, Desper John, Aikens Christine M., Levy Christopher J.: Helical Oxidovanadium(IV) Salen-Type Complexes: Synthesis, Characterisation and Catalytic Behaviour. Eur. J. Inorg. Chem. 2013, 2013, 5708. <>
  • Matos Cristina P., Valente Andreia, Marques Fernanda, Adão Pedro, Paula Robalo M., de Almeida Rodrigo F.M., Pessoa João Costa, Santos Isabel, Helena Garcia M., Tomaz Ana Isabel: New polydentate Ru(III)-Salan complexes: Synthesis, characterization, anti-tumour activity and interaction with human serum proteins. Inorganica Chimica Acta 2013, 394, 616. <>
  • Mandal Soumik, Mandal Santanu, Seth Dipravath K., Mukhopadhyay Balaram, Gupta Parna: Ruthenium and osmium complexes of novel carbohydrate derived salen ligands: Synthesis, characterization and in situ ligand reduction. Inorganica Chimica Acta 2013, 398, 83. <>
  • Mandal Senjuti, Modak Ritwik, Goswami Sanchita: Synthesis and characterization of a copper(II) complex of a ONN donor Schiff base ligand derived from pyridoxal and 2-(pyrid-2-yl)ethylamine – A novel pyridoxal based fluorescent probe. Journal of Molecular Structure 2013, 1037, 352. <>
  • Maurya Mannar R., Haldar Chanchal, Kumar Amit, Kuznetsov Maxim L., Avecilla Fernando, Costa Pessoa João: Vanadium complexes having [VO]2+, [VO]3+ and [VO2]+ cores with hydrazones of 2,6-diformyl-4-methylphenol: synthesis, characterization, reactivity, and catalytic potential. Dalton Trans. 2013, 42, 11941. <>
  • Erçağ Ayşe, Şahin Musa, Koca Atif, Bozkurt Esat: Synthesis, characterization, EPR, electrochemical, and in situ spectroelectrochemical studies of salen-type oxovanadium(IV) and copper(II) complexes derived from 3,4-diaminobenzophenone. Journal of Coordination Chemistry 2013, 66, 1635. <>
  • Coletti A., Galloni P., Sartorel A., Conte V., Floris B.: Salophen and salen oxo vanadium complexes as catalysts of sulfides oxidation with H2O2: Mechanistic insights. Catalysis Today 2012, 192, 44. <>
  • Casas José S., Couce Mª Delfina, Sordo José: Coordination chemistry of vitamin B6 and derivatives: A structural overview. Coordination Chemistry Reviews 2012, 256, 3036. <>
  • Adão Pedro, Kuznetsov Maxim L., Barroso Sónia, Martins Ana M., Avecilla F., Pessoa João Costa: Amino Alcohol-Derived Reduced Schiff Base VIVO and VV Compounds as Catalysts for Asymmetric Sulfoxidation of Thioanisole with Hydrogen Peroxide. Inorg. Chem. 2012, 51, 11430. <>
  • Mukherjee Tirtha, Pessoa João Costa, Kumar Amit, Sarkar Asit R.: Synthesis, spectroscopic characterization, insulin-enhancment, and competitive DNA binding activity of a new Zn(ii) complex with a vitamin B6 derivative—a new fluorescence probe for Zn(ii). DALTON T 2012, 41, 5260. <>
  • Maurya Mannar R., Saini Priyanka, Kumar Amit, Costa Pessoa João: Oxidovanadium(IV) Complexes of Tetradentate Ligands Encapsulated in Zeolite-Y as Catalysts for the Oxidation of Styrene, Cyclohexene and Methyl Phenyl Sulfide. Euro J Inorg Chem 2011, 2011, 4846. <>
  • Conte Valeria, Coletti Alessia, Floris Barbara, Licini Giulia, Zonta Cristiano: Mechanistic aspects of vanadium catalysed oxidations with peroxides. Coord Chem Rev 2011, 255, 2165. <>
  • Maurya Mannar R., Pessoa João Costa: Polymer-bound metal complexes as catalysts: Synthesis, characterization, reactivity and catalytic activity in E–H bond activation. J Organomet Chem 2011, 696, 244. <>
  • Kirillova Marina V., Kuznetsov Maxim L., Kozlov Yuriy N., Shul’pina Lidia S., Kitaygorodskiy Alex, Pombeiro Armando J. L., Shul’pin Georgiy B.: Participation of Oligovanadates in Alkane Oxidation with H2O2 Catalyzed by Vanadate Anion in Acidified Acetonitrile: Kinetic and DFT Studies. ACS Catal 2011, 1, 1511. <>
  • Mukherjee Tirtha, Costa Pessoa Joa̅o, Kumar Amit, Sarkar Asit R.: Oxidovanadium(IV) Schiff Base Complex Derived from Vitamin B6: Synthesis, Characterization, and Insulin Enhancing Properties. Inorg Chem 2011, 50, 4349. <>
  • Conte Valeria, Floris Barbara: Vanadium and molybdenum peroxides: synthesis and catalytic activity in oxidation reactions. Dalton Trans 2011, 40, 1419. <>
  • Adão Pedro, Avecilla Fernando, Bonchio Marcella, Carraro Mauro, Costa Pessoa João, Correia Isabel: Titanium(IV)-Salan Catalysts for Asymmetric Sulfoxidation with Hydrogen Peroxide. Eur J Inorg Chem 2010, 2010, 5568. <>
  • Pereira Clara, Leite Andreia, Nunes Ana, Rebelo Susana L. H., Rangel Maria, Freire Cristina: Oxidovanadium(IV) Complexes of 3-Hydroxy-4-pyrone and 3-Hydroxy-4-pyridinone Ligands: A New Generation of Homogeneous Catalysts for the Epoxidation of Geraniol. Catal Lett 2010, 135, 98. <>