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Pure Appl. Chem., 2009, Vol. 81, No. 7, pp. 1251-1264

http://dx.doi.org/10.1351/PAC-CON-08-09-01

Published online 2009-06-29

On the reactivity of bromoperoxidase I (Ascophyllum nodosum) in buffered organic media: Formation of carbon bromine bonds

Jens Hartung1*, Yvonne Dumont1, Marco Greb2, Diana Hach1, Franz Köhler2, Heiko Schulz1, Marian Časný3, Dieter Rehder3 and Hans Vilter4

1 Fachbereich Chemie, Organische Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Straße, 67663 Kaiserslautern, Germany
2 Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany
3 Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg, Germany
4 Zurmaiener Straße 16, D-54292 Trier, Germany

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  • Dönges Maike, Amberg Matthias, Stapf Georg, Kelm Harald, Bergsträßer Uwe, Hartung Jens: cis-2,6-Bis-(methanolate)-piperidine oxovanadium(V) complexes as catalysts for oxidative alkenol cyclization by tert-butyl hydroperoxide. Inorganica Chimica Acta 2014. <http://dx.doi.org/10.1016/j.ica.2014.02.007>
  • Moriuchi Toshiyuki, Ikeuchi Kousuke, Hirao Toshikazu: Synthesis of vanadium(v) hydrazido complexes with tris(2-hydroxyphenyl)amine ligands. Dalton Trans. 2013, 42, 11824. <http://dx.doi.org/10.1039/c3dt50533b>
  • Patra Swarup, Chatterjee Suparna, Si Tapan Kr., Mukherjea Kalyan K.: Synthesis, structural characterization, VHPO mimicking peroxidative bromination and DNA nuclease activity of oxovanadium(v) complexes. Dalton Trans. 2013, 42, 13425. <http://dx.doi.org/10.1039/c3dt51291f>
  • Wischang Diana, Radlow Madlen, Hartung Jens: Vanadate-dependent bromoperoxidases from Ascophyllum nodosum in the synthesis of brominated phenols and pyrroles. Dalton Trans. 2013, 42, 11926. <http://dx.doi.org/10.1039/c3dt51582f>
  • Wischang Diana, Radlow Madlen, Schulz Heiko, Vilter Hans, Viehweger Lutz, Altmeyer Matthias O., Kegler Carsten, Herrmann Jennifer, Müller Rolf, Gaillard Fanny, Delage Ludovic, Leblanc Catherine, Hartung Jens: Molecular cloning, structure, and reactivity of the second bromoperoxidase from Ascophyllum nodosum. Bioorganic Chemistry 2012, 44, 25. <http://dx.doi.org/10.1016/j.bioorg.2012.05.003>
  • Wischang Diana, Hartung Jens: Bromination of phenols in bromoperoxidase-catalyzed oxidations. Tetrahedron 2012, 68, 9456. <http://dx.doi.org/10.1016/j.tet.2012.08.081>
  • Si Tapan K., Paul Shiv S., Drew Michael G. B., Mukherjea Kalyan K.: Synthesis, structural characterization and catalytic activity of a multifunctional enzyme mimetic oxoperoxovanadium(v) complex. DALTON T 2012, 41, 5805. <http://dx.doi.org/10.1039/c2dt12505f>
  • Wischang Diana, Brücher Oliver, Hartung Jens: Bromoperoxidases and functional enzyme mimics as catalysts for oxidative bromination—A sustainable synthetic approach. Coord Chem Rev 2011, 255, 2204. <http://dx.doi.org/10.1016/j.ccr.2011.04.003>
  • Wischang Diana, Hartung Jens: Parameters for bromination of pyrroles in bromoperoxidase-catalyzed oxidations. Tetrahedron 2011, 67, 4048. <http://dx.doi.org/10.1016/j.tet.2011.04.010>
  • Brücher Oliver, Hartung Jens: Vanadium(V)-Catalyzed Oxidative Bromination of Acid Labile Alkenols and Alkenes in Alkyl Carbonates. ACS Catal 2011, 1, 1448. <http://dx.doi.org/10.1021/cs200349c>
  • Wischang Diana, Hartung Jens, Hahn Thomas, Ulber Roland, Stumpf Tobias, Fecher-Trost Claudia: Vanadate(v)-dependent bromoperoxidase immobilized on magnetic beads as reusable catalyst for oxidative bromination. Green Chem 2011, 13, 102. <http://dx.doi.org/10.1039/c0gc00499e>
  • Johnson Todd L., Palenik Brian, Brahamsha Bianca: CHARACTERIZATION OF A FUNCTIONAL VANADIUM-DEPENDENT BROMOPEROXIDASE IN THE MARINE CYANOBACTERIUM SYNECHOCOCCUS SP. CC93111 : CYANOBACTERIAL BROMOPEROXIDASE. J Phycol 2011, 47, 792. <http://dx.doi.org/10.1111/j.1529-8817.2011.01007.x>