Pure and Applied Chemistry

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• Niepötter Benedikt, Herbst-Irmer Regine, Kratzert Daniel, Samuel Prinson P., Mondal Kartik Chandra, Roesky Herbert W., Jerabek Paul, Frenking Gernot, Stalke Dietmar: Experimentelle Elektronendichteuntersuchung eines Silylons. Angew. Chem. 2014, 126, 2806. <http://dx.doi.org/10.1002/ange.201308609>
• Niepötter Benedikt, Herbst-Irmer Regine, Kratzert Daniel, Samuel Prinson P., Mondal Kartik Chandra, Roesky Herbert W., Jerabek Paul, Frenking Gernot, Stalke Dietmar: Experimental Charge Density Study of a Silylone. Angew. Chem. Int. Ed. 2014, 53, 2766. <http://dx.doi.org/10.1002/anie.201308609>
• Petz Wolfgang, Neumüller Bernhard: On the Alkylation of Ph3 PCHP(O)Ph2 : Formation and Crystal Structures of Neutral and Cationic Addition Compounds. Eur. J. Inorg. Chem. 2014, 2014, 1218. <http://dx.doi.org/10.1002/ejic.201301427>
• Kuzu Istemi, Kneusels Nis-Julian H., Bauer Mona, Neumüller Bernhard, Tonner Ralf: Synthesis and Characterization of the Silylated Hexaphenyl Carbodiphosphorane [Me3 SiC(PPh3 )2 ][CF3 SO3 ]. Z. anorg. allg. Chem. 2014, 640, 417. <http://dx.doi.org/10.1002/zaac.201300545>
• Li Yan, Mondal Kartik Chandra, Lübben Jens, Zhu Hongping, Dittrich Birger, Purushothaman Indu, Parameswaran Pattiyil, Roesky Herbert W.: A functionalized Ge3-compound with a dual character of the central germanium atom. Chem. Commun. 2014, 50, 2986. <http://dx.doi.org/10.1039/c3cc49635j>
• Soriano Elena, Fernández Israel: Allenes and computational chemistry: from bonding situations to reaction mechanisms. Chem. Soc. Rev. 2014, 43, 3041. <http://dx.doi.org/10.1039/c3cs60457h>
• Mondal Kartik Chandra, Roesky Herbert W., Schwarzer Martin C., Frenking Gernot, Niepötter Benedikt, Wolf Hilke, Herbst-Irmer Regine, Stalke Dietmar: Ein stabiles biradikaloides Singulett-Siladicarben: (L:) 2 Si. Angew. Chem. 2013, 125, 3036. <http://dx.doi.org/10.1002/ange.201208307>
• Xiong Yun, Yao Shenglai, Inoue Shigeyoshi, Epping Jan Dirk, Driess Matthias: Ein cyclisches Silylon (“Siladicarben”) mit einem elektronenreichen Silicium(0)-Atom. Angew. Chem. 2013, 125, 7287. <http://dx.doi.org/10.1002/ange.201302537>
• Mondal Kartik Chandra, Roesky Herbert W., Schwarzer Martin C., Frenking Gernot, Niepötter Benedikt, Wolf Hilke, Herbst-Irmer Regine, Stalke Dietmar: A Stable Singlet Biradicaloid Siladicarbene: (L:) 2 Si. Angew. Chem. Int. Ed. 2013, 52, 2963. <http://dx.doi.org/10.1002/anie.201208307>
• Xiong Yun, Yao Shenglai, Inoue Shigeyoshi, Epping Jan Dirk, Driess Matthias: A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom. Angew. Chem. Int. Ed. 2013, 52, 7147. <http://dx.doi.org/10.1002/anie.201302537>
• Ruiz David A., Melaimi Mohand, Bertrand Guy: Carbodicarbenes, Carbon(0) Derivatives, Can Dimerize. Chem. Asian J. 2013, 8, 2940. <http://dx.doi.org/10.1002/asia.201300887>
• Flock Johanna, Suljanovic Amra, Torvisco Ana, Schoefberger Wolfgang, Gerke Birgit, Pöttgen Rainer, Fischer Roland C., Flock Michaela: The Role of 2,6-Diaminopyridine Ligands in the Isolation of an Unprecedented, Low-Valent Tin Complex. Chem. Eur. J. 2013, 19, 15504. <http://dx.doi.org/10.1002/chem.201301340>
• Barua Shiblee R., Allen Wesley D., Kraka Elfi, Jerabek Paul, Sure Rebecca, Frenking Gernot: Nearly Degenerate Isomers of C(BH)2 : Cumulene, Carbene, or Carbone?. Chem. Eur. J. 2013, 19, 15941. <http://dx.doi.org/10.1002/chem.201302181>
• Celik Mehmet Ali, Frenking Gernot, Neumüller Bernhard, Petz Wolfgang: Exploiting the Twofold Donor Ability of Carbodiphosphoranes: Theoretical Studies of [(PPh 3 ) 2 C→EH 2 ] q (E q =Be, B + , C 2+ , N 3+ , O 4+ ) and Synthesis of the Dication [(Ph 3 P) 2 CCH 2 ] 2+. ChemPlusChem 2013, 78, 1024. <http://dx.doi.org/10.1002/cplu.201300169>
• Bhatia Sonam, Malkhede Yogesh J., Bharatam Prasad V.: Existence of dynamic tautomerism and divalent N(I) character in N -(pyridin-2-yl)thiazol-2-amine. J. Comput. Chem. 2013, 34, 1577. <http://dx.doi.org/10.1002/jcc.23293>
• Guha Ankur Kanti, Gogoi Ujjal, Phukan Ashwini K.: Revisiting the reactivity of different carbon bases: A theoretical study. Int. J. Quantum Chem. 2013, n/a. <http://dx.doi.org/10.1002/qua.24485>
• Petz Wolfgang, Neumüller Bernhard: Contribution to the Chemistry of (ClC{PPh3 }2 )Cl, a Precursor of the Carbodiphosphorane C(PPh3 )2. Z. anorg. allg. Chem. 2013, 639, 2331. <http://dx.doi.org/10.1002/zaac.201300175>
• Gámez José A., Hermann Markus, Frenking Gernot: Structures and Bonding Situation of the Allyl Systems and Cyclic Isomers [H2 E -E (H)-E H2 ]-,·,+ (E = C, Si, Ge, Sn). Z. anorg. allg. Chem. 2013, 639, 2493. <http://dx.doi.org/10.1002/zaac.201300473>
• Giziroglu Emrah, Donnadieu Bruno, Bertrand Guy: Synthesis and characterization of a pyrazolium bearing N-heterocyclic carbene–palladium(II) complex. Journal of Organometallic Chemistry 2013, 724, 251. <http://dx.doi.org/10.1016/j.jorganchem.2012.11.021>
• Kleinpeter Erich, Werner Peter, Koch Andreas: Push–pull allenes-conjugation, (anti)aromaticity and quantification of the push–pull character. Tetrahedron 2013, 69, 2436. <http://dx.doi.org/10.1016/j.tet.2013.01.027>
• Xiong Yun, Yao Shenglai, Tan Gengwen, Inoue Shigeyoshi, Driess Matthias: A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene. J. Am. Chem. Soc. 2013, 135, 5004. <http://dx.doi.org/10.1021/ja402477w>
• Li Yan, Mondal Kartik Chandra, Roesky Herbert W., Zhu Hongping, Stollberg Peter, Herbst-Irmer Regine, Stalke Dietmar, Andrada Diego M.: Acyclic Germylones: Congeners of Allenes with a Central Germanium Atom. J. Am. Chem. Soc. 2013, 135, 12422. <http://dx.doi.org/10.1021/ja406112u>
• De Susmita, Parameswaran Pattiyil: Neutral tricoordinated beryllium(0) compounds – isostructural to BH3 but isoelectronic to NH3. Dalton Trans. 2013, 42, 4650. <http://dx.doi.org/10.1039/c3dt32749c>
• Esterhuysen Catharine, Frenking Gernot: Complexation behavior of two-coordinated carbon compounds containing fluorenyl ligands. Dalton Trans. 2013, 42, 13349. <http://dx.doi.org/10.1039/c3dt32872d>
• Couchman Shannon A., Holzmann Nicole, Frenking Gernot, Wilson David J. D., Dutton Jason L.: Beryllium chemistry the safe way: a theoretical evaluation of low oxidation state beryllium compounds. Dalton Trans. 2013, 42, 11375. <http://dx.doi.org/10.1039/c3dt50563d>
• Nguyen Thi Ai Nhung, Frenking Gernot: Structure and bonding of tetrylone complexes [(CO)4W{E(PPh3)2}] (E = C–Pb). Molecular Physics 2013, 111, 2640. <http://dx.doi.org/10.1080/00268976.2013.813593>
• Takagi Nozomi, Tonner Ralf, Frenking Gernot: Carbodiphosphorane Analogues E(PPh3)2 with E=C-Pb: A Theoretical Study with Implications for Ligand Design. Chemistry A European Journal 2012, 18, 1772. <http://dx.doi.org/10.1002/chem.201100494>
• Guha Ankur Kanti, Phukan Ashwini K.: Do Carbenes Have a “Hidden” Carbon(0) Character? Revisiting the Electronic Structure of 2,2′-Bipyridyl Carbene. Chemistry A European Journal 2012, 18, 4419. <http://dx.doi.org/10.1002/chem.201103250>
• Celik Mehmet Ali, Sure Rebecca, Klein Susanne, Kinjo Rei, Bertrand Guy, Frenking Gernot: Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2. Chemistry A European Journal 2012, 18, 5676. <http://dx.doi.org/10.1002/chem.201103965>
• Nguyen Thi Ai Nhung, Frenking Gernot: Transition-Metal Complexes of Tetrylones [(CO)5 W-E(PPh3 )2 ] and Tetrylenes [(CO)5 W-NHE] (E=C-Pb): A Theoretical Study. Chem. Eur. J. 2012, 18, 12733. <http://dx.doi.org/10.1002/chem.201200741>
• Schröter Peter, Gessner Viktoria H.: Tetrahedral versus Planar Four-Coordinate Carbon: A Sulfonyl-Substituted Methandiide. Chem. Eur. J. 2012, 18, 11223. <http://dx.doi.org/10.1002/chem.201201369>
• Petz Wolfgang, Neumüller Bernhard: Reaction of (PPh3)2C→CO2 with Halogenated Hydrocarbons; Formation and Crystal Structure of a Cationic Ester with 1, 2-Dichloroethane. Z. anorg. allg. Chem. 2012, 638, 987. <http://dx.doi.org/10.1002/zaac.201200122>
• Rogachev Andrey Yu., Jerabek Paul, Klein Susanne, Frenking Gernot, Hoffmann Roald: Hunting dimers. Theor Chem Accounts 2012, 131, 1149. <http://dx.doi.org/10.1007/s00214-012-1149-3>
• Bhatia Sonam, Bagul Chandrakant, Kasetti Yoganjaneyulu, Patel Dhilon S., Bharatam Prasad V.: Divalent N(I) Character in 2-(Thiazol-2-yl)guanidine: An Electronic Structure Analysis. J. Phys. Chem. A 2012, 116, 9071. <http://dx.doi.org/10.1021/jp304789u>
• Esterhuysen Catharine, Frenking Gernot: Distinguishing Carbones from Allenes by Complexation to AuCl. Chemistry A European Journal 2011, 17, 9944. <http://dx.doi.org/10.1002/chem.201101213>
• Petz Wolfgang, Neumüller Bernhard: Reaction of C(PPh3)2 with MI2 Compounds (M = Zn, Cd) - Formation and Crystal Structures of [I2Zn{C(PPh3)2}], [(I2Cd{C(PPh3)2})2] and the Salt-Like Compounds (HC{PPh3}2)[MI3(THF)] and (HC{PPh3}2)2[ZnI4]. Euro J Inorg Chem 2011, 2011, 4889. <http://dx.doi.org/10.1002/ejic.201100646>
• Frenking Gernot, Tonner Ralf: Carbodicarbenes-divalent carbon(0) compounds exhibiting carbon-carbon donor-acceptor bonds. WIREs Comput Mol Sci 2011, 1, 869. <http://dx.doi.org/10.1002/wcms.53>
• Petz Wolfgang, Dehnicke Kurt, Neumüller Bernhard: About the Reaction of BeCl2 with the Carbodiphosphorane Addition Compound O2C←C(PPh3)2 and its Hydrolysis Product Ph3PCHP(O)Ph2. Z anorg allg Chem 2011, 637, 1761. <http://dx.doi.org/10.1002/zaac.201100293>
• Petz Wolfgang, Dehnicke Kurt, Holzmann Nicole, Frenking Gernot, Neumüller Bernhard: The Reaction of BeCl2 with Carbodiphosphorane C(PPh3)2; Experimental and Theoretical Studies. Z anorg allg Chem 2011, 637, 1702. <http://dx.doi.org/10.1002/zaac.201100328>
• Takagi Nozomi, Frenking Gernot: Divalent Pb(0) compounds. Theor Chem Acc 2011, 129, 615. <http://dx.doi.org/10.1007/s00214-011-0909-9>
• DeHope Alan, Donnadieu Bruno, Bertrand Guy: Grubbs and Hoveyda-type ruthenium complexes bearing a cyclic bent-allene. J Organomet Chem 2011, 696, 2899. <http://dx.doi.org/10.1016/j.jorganchem.2011.03.010>
• Patel Dhilon S., Bharatam Prasad V.: To Bend or Not to Bend! The Dilemma of Allenes. J Org Chem 2011, 76, 2558. <http://dx.doi.org/10.1021/jo102432a>
• Patel Dhilon S., Bharatam Prasad V.: Divalent N(I) Compounds with Two Lone Pairs on Nitrogen. J Phys Chem A 2011, 115, 7645. <http://dx.doi.org/10.1021/jp111017u>
• Martin David, Melaimi Mohand, Soleilhavoup Michele, Bertrand Guy: A Brief Survey of Our Contribution to Stable Carbene Chemistry. Organomettalics 2011, 30, 5304. <http://dx.doi.org/10.1021/om200650x>
• Martin David, Soleilhavoup Michele, Bertrand Guy: Stable singlet carbenes as mimics for transition metal centers. Chem Sci 2011, 2, 389. <http://dx.doi.org/10.1039/c0sc00388c>
• Melaimi Mohand, Soleilhavoup Michèle, Bertrand Guy: Stabile cyclische Carbene und verwandte Spezies jenseits der Diaminocarbene. Angew Chem 2010, 122, 8992. <http://dx.doi.org/10.1002/ange.201000165>
• Guisado-Barrios Gregorio, Bouffard Jean, Donnadieu Bruno, Bertrand Guy: Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs). Angew Chem 2010, 122, 4869. <http://dx.doi.org/10.1002/ange.201001864>
• Klein Susanne, Frenking Gernot: Carbodiylide C(ECp*)2 (E=B-Tl): eine weitere Klasse theoretisch vorhergesagter Kohlenstoff(0)-Verbindungen. Angew Chem 2010, 122, 7260. <http://dx.doi.org/10.1002/ange.201002773>
• Kinjo Rei, Donnadieu Bruno, Bertrand Guy: Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN+.). Angew Chem 2010, 122, 6066. <http://dx.doi.org/10.1002/ange.201002889>
• Melaimi Mohand, Soleilhavoup Michèle, Bertrand Guy: Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes. Angew Chem Int Ed 2010, 49, 8810. <http://dx.doi.org/10.1002/anie.201000165>
• Guisado-Barrios Gregorio, Bouffard Jean, Donnadieu Bruno, Bertrand Guy: Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs). Angew Chem Int E 2010, 49, 4759. <http://dx.doi.org/10.1002/anie.201001864>
• Klein Susanne, Frenking Gernot: Carbodiylides C(ECp*)2 (E=B-Tl): Another Class of Theoretically Predicted Divalent Carbon(0) Compounds. Angew Chem Int Ed 2010, 49, 7106. <http://dx.doi.org/10.1002/anie.201002773>
• Kinjo Rei, Donnadieu Bruno, Bertrand Guy: Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN+. ). Angewandte Chemie International Edition 2010, 49, 5930. <http://dx.doi.org/10.1002/anie.201002889>
• Klein Susanne, Tonner Ralf, Frenking Gernot: Carbodicarbenes and Related Divalent Carbon(0) Compounds. Chem. Eur. J. 2010, 16, 10160. <http://dx.doi.org/10.1002/chem.201000174>
• Takagi Nozomi, Shimizu Takayasu, Frenking Gernot: Divalent E(0) Compounds (E=Si-Sn). Chem Eur J 2009, 15, 8593. <http://dx.doi.org/10.1002/chem.200901401>
• Petz Wolfgang, Öxler Florian, Neumüller Bernhard, Tonner Ralf, Frenking Gernot: Carbodiphosphorane C(PPh₃)₂ as a Single and Twofold Lewis Base with Boranes: Synthesis, Crystal Structures and Theoretical Studies on [H₃B{C(PPh₃)₂}] and [{(μ-H)H₄B₂}{C(PPh₃)₂}]⁺ . Eur J Inorg Chem 2009, 2009, 4507. <http://dx.doi.org/10.1002/ejic.200900691>
• Dyker C. Adam, Bertrand Guy: Chemical bonding: Rethinking carbon. Nature Chem 2009, 1, 265. <http://dx.doi.org/10.1038/nchem.265>