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Pure Appl. Chem., 2008, Vol. 80, No. 6, pp. 1239-1252

http://dx.doi.org/10.1351/pac200880061239

What can be learnt from dielectric relaxation spectroscopy about ion solvation and association?

Richard Buchner

Institute for Physical and Theoretical Chemistry, University of Regensburg, D-93040 Regensburg, Germany

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  • Mazur Kamila, Buchner Richard, Bonn Mischa, Hunger Johannes: Hydration of Sodium Alginate in Aqueous Solution. Macromolecules 2014, 47, 771. <http://dx.doi.org/10.1021/ma4023873>
  • Abbas Zareen, Ulfsbo Adam, Turner David R.: Monte Carlo simulation of the dissociation constants of CO2 in 0 to 1molal sodium chloride between 0 and 25°C. Marine Chemistry 2013, 150, 1. <http://dx.doi.org/10.1016/j.marchem.2013.01.002>
  • Bugris V., Haspel H., Kukovecz Á., Kónya Z., Sipiczki M., Sipos P., Pálinkó I.: Rehydration of dehydrated CaFe-L(ayered)D(ouble)H(ydroxide) followed by thermogravimetry, X-ray diffractometry and dielectric relaxation spectroscopy. Journal of Molecular Structure 2013, 1044, 26. <http://dx.doi.org/10.1016/j.molstruc.2012.10.040>
  • Sun Zheng, Zhang Wenkai, Ji Minbiao, Hartsock Robert, Gaffney Kelly J.: Contact Ion Pair Formation between Hard Acids and Soft Bases in Aqueous Solutions Observed with 2DIR Spectroscopy. J. Phys. Chem. B 2013, 117, 15306. <http://dx.doi.org/10.1021/jp4033854>
  • Navarro Ana M., García Begoña, Ibeas Saturnino, Hoyuelos Francisco J., Peñacoba Indalecio A., Leal José M.: Microwave Dielectric Relaxation Spectroscopy Study of Alkan-1-ol/Alkylbenzoate Binary Solvents. J. Phys. Chem. B 2013, 117, 11765. <http://dx.doi.org/10.1021/jp406609r>
  • Sun Zheng, Zhang Wenkai, Ji Minbiao, Hartsock Robert, Gaffney Kelly J.: Aqueous Mg2+ and Ca2+ Ligand Exchange Mechanisms Identified with 2DIR Spectroscopy. J. Phys. Chem. B 2013, 130930123715009. <http://dx.doi.org/10.1021/jp407960x>
  • Fedotova Marina V., Kruchinin Sergey E.: 1D-RISM study of glycine zwitterion hydration and ion-molecular complex formation in aqueous NaCl solutions. Journal of Molecular Liquids 2012, 169, 1. <http://dx.doi.org/10.1016/j.molliq.2012.03.008>
  • Eiberweiser Andreas, Buchner Richard: Ion-pair or ion-cloud relaxation? On the origin of small-amplitude low-frequency relaxations of weakly associating aqueous electrolytes. Journal of Molecular Liquids 2012, 176, 52. <http://dx.doi.org/10.1016/j.molliq.2012.03.025>
  • Rahman Hafiz M.A., Buchner Richard: Hydration and sodium-ion binding of trifluoroacetate in aqueous solution. Journal of Molecular Liquids 2012, 176, 93. <http://dx.doi.org/10.1016/j.molliq.2012.05.017>
  • Rahman Hafiz M. A., Hefter Glenn, Buchner Richard: Hydration of Formate and Acetate Ions by Dielectric Relaxation Spectroscopy. Chem B 2012, 116, 314. <http://dx.doi.org/10.1021/jp207504d>
  • Hunger Johannes, Tielrooij Klaas-Jan, Buchner Richard, Bonn Mischa, Bakker Huib J.: Complex Formation in Aqueous Trimethylamine-N-oxide (TMAO) Solutions. Chem B 2012, 116, 4783. <http://dx.doi.org/10.1021/jp212542q>
  • Stoppa Alexander, Hunger Johannes, Hefter Glenn, Buchner Richard: Structure and Dynamics of 1-N-Alkyl-3-N-Methylimidazolium Tetrafluoroborate + Acetonitrile Mixtures. J. Phys. Chem. B 2012, 116, 7509. <http://dx.doi.org/10.1021/jp3020673>
  • Palombo Francesca, Meech Stephen R.: Dynamics of Formamide Ionic Solutions Investigated by Ultrafast Optical Kerr Effect. J. Phys. Chem. B 2012, 116, 13481. <http://dx.doi.org/10.1021/jp3087418>
  • Gaffney Kelly J., Ji Minbiao, Odelius Michael, Park Sungnam, Sun Zheng: H-bond switching and ligand exchange dynamics in aqueous ionic solution. Chemical Physics Letters 2011, 504, 1. <http://dx.doi.org/10.1016/j.cplett.2011.01.063>
  • Hu Xingbang, Lin Qiuxing, Gao Junyang, Wu Youting, Zhang Zhibing: Anion–cation and ion–solvent interaction of some typical ionic liquids in solvents with different dielectric constant. chem phys letts 2011, 516, 35. <http://dx.doi.org/10.1016/j.cplett.2011.09.051>
  • Bešter-Rogač Marija, Stoppa Alexander, Hunger Johannes, Hefter Glenn, Buchner Richard: Association of ionic liquids in solution: a combined dielectric and conductivity study of [bmim][Cl] in water and in acetonitrile. PCCP 2011, 13, 17588. <http://dx.doi.org/10.1039/c1cp21371g>
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  • Zech Oliver, Hunger Johannes, Sangoro Joshua R., Iacob Ciprian, Kremer Friedrich, Kunz Werner, Buchner Richard: Correlation between polarity parameters and dielectric properties of [Na][TOTO]—a sodium ionic liquid. Phys Chem Chem Phys 2010, 12, 14341. <http://dx.doi.org/10.1039/c0cp00840k>
  • Kaatze Udo: Techniques for measuring the microwave dielectric properties of materials. Metrologica 2010, 47, S91. <http://dx.doi.org/10.1088/0026-1394/47/2/S10>
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  • Lukšič Miha, Hribar-Lee Barbara, Buchner Richard, Vlachy Vojko: Modelling fast mode dielectric relaxation of counterions in aqueous solutions of ionene bromides and fluorides. Phys Chem Chem Phys 2009, 11, 10053. <http://dx.doi.org/10.1039/b914938b>
  • Spickermann C., Thar J., Lehmann S. B. C., Zahn S., Hunger J., Buchner R., Hunt P. A., Welton T., Kirchner B.: Why are ionic liquid ions mainly associated in water? A Car–Parrinello study of 1-ethyl-3-methyl-imidazolium chloride water mixture. J Chem Phys 2008, 129, 104505. <http://dx.doi.org/10.1063/1.2974098>
  • Schröder C., Hunger J., Stoppa A., Buchner R., Steinhauser O.: On the collective network of ionic liquid/water mixtures. II. Decomposition and interpretation of dielectric spectra. J Chem Phys 2008, 129, 184501. <http://dx.doi.org/10.1063/1.3002563>