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Pure Appl. Chem., 2008, Vol. 80, No. 5, pp. 1155-1160

New hydrosilylation reaction of arylacetylene accompanied by C-H bond activation catalyzed by a xantsil ruthenium complex

Hiromi Tobita1, Nobukazu Yamahira1, Keisuke Ohta1, Takashi Komuro1 and Masaaki Okazaki2

1 Department of Chemistry, Graduate School of Science, Tohoku University,Sendai 980-8578, Japan
2 International Research Center for Elements Science, Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan

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  • Komuro Takashi, Furuyama Keisuke, Kitano Takeo, Tobita Hiromi: Synthesis of a 14-electron iridium(III) complex with a xanthene-based bis(silyl) chelate ligand (xantsil): A distorted seesaw-shaped four-coordinate geometry and reactions leading to 16-electron complexes. Journal of Organometallic Chemistry 2014, 751, 686. <>
  • Montiel-Palma Virginia, Muñoz-Hernández Miguel A., Cuevas-Chávez Cynthia A., Vendier Laure, Grellier Mary, Sabo-Etienne Sylviane: Phosphinodi(benzylsilane) PhP{(o-C6H4CH2)SiMe2H}2: A Versatile “PSi2Hx” Pincer-Type Ligand at Ruthenium. Inorg. Chem. 2013, 52, 9798. <>
  • Li Yong-Hua, Ding Xue-Hua, Zhang Yuan, He Wen-Rui, Huang Wei: Synthesis, characterization, and catalytic behavior of a PSiP pincer-type ruthenium(II) complex. J Inorg Chem Commun 2012, 15, 194. <>
  • Kameo Hajime, Ishii Sho, Nakazawa Hiroshi: Synthesis and Reactivity of Rhodium Complexes Bearing [E(o-C6H4PPh2)3]-Type Tetradentate Ligands (E = Si, Ge, and Sn). Organomettalics 2012, 31, 2212. <>
  • Kameo Hajime, Ishii Sho, Nakazawa Hiroshi: Synthesis of iridium complexes bearing {o-(Ph2P)C6H4}3E type (E = Si, Ge, and Sn) ligand and evaluation of electron donating ability of group 14 elements E. Dalton Trans. 2012, 41, 8290. <>
  • Kameo Hajime, Ishii Sho, Nakazawa Hiroshi: Facile synthesis of rhodium and iridium complexes bearing a [PEP]-type ligand (E = Ge or Sn) via E–C bond cleavage. Dalton Trans. 2012, 41, 11386. <>
  • Fang Hongyun, Choe Yoong-Kee, Li Yonghua, Shimada Shigeru: Synthesis, Structure, and Reactivity of Hydridoiridium Complexes Bearing a Pincer-Type PSiP Ligand. Chem —Asian J 2011, 6, 2512. <>
  • Li Yong-Hua, Zhang Yuan, Ding Xue-Hua: Synthesis, structure, and catalytic behavior of a PSiP pincer-type iridium(III) complex. J Inorg Chem Commun 2011, 14, 1306. <>
  • Komuro Takashi, Begum Rockshana, Ono Rikima, Tobita Hiromi: Synthesis and characterisation of hydrido molybdenum and tungsten complexes having a hemilabile tridentate Si,Si,O-ligand: observation of stepwise hydrosilylation of a nitrile to form an N-silylimine on the metal centre. Dalton Trans 2011, 40, 2348. <>