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Pure Appl. Chem., 2008, Vol. 80, No. 3, pp. 459-474

En route to diplatinum polyynediyl complexes trans,trans-(Ar)(R3P)2Pt(C≡C)nPt(PR3)2(Ar): Untold tales, including end-group strategies

Jürgen Stahl1, James C. Bohling2, Thomas B. Peters2, Laura de Quadras1 and John A. Gladysz1,3

1 Institute for Organic Chemistry and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany
2 Department of Chemistry, University of Utah, Salt Lake City, UT 84112, USA
3 Department of Chemistry, Texas AM University, P.O. Box 30012, College Station, TX 77842-3012, USA

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  • Vincent Kevin B., Zeng Qiang, Parthey Matthias, Yufit Dmitry S., Howard Judith A.K., Hartl František, Kaupp Martin, Low Paul J.: Syntheses, Spectroelectrochemical Studies, and Molecular and Electronic Structures of Ferrocenyl Ene-diynes. Organometallics 2013, 32, 6022. <>
  • Tanaka Yuya, Ishisaka Takuya, Inagaki Akiko, Koike Takashi, Lapinte Claude, Akita Munetaka: Photochromic Organometallics with a Dithienylethene (DTE) Bridge, [YCCDTECCY] (Y={MCp*(dppe)}): Photoswitchable Molecular Wire (M=Fe) versus Dual Photo- and Electrochromism (M=Ru). Chemistry A European Journal 2010, 16, 4762. <>
  • Owen Gareth R., Gauthier Sébastien, Weisbach Nancy, Hampel Frank, Bhuvanesh Nattamai, Gladysz John A.: Towards multistranded molecular wires: Syntheses, structures, and reactivities of tetraplatinum bis(polyynediyl) complexes with Pt-Cx-Pt-(P(CH2)3P)2-Pt-Cx-Pt-(P(CH2)3P)2 cores (x = 4, 6, 8). Dalton Trans 2010, 39, 5260. <>
  • Matsuura Yumi, Tanaka Yuya, Akita Munetaka: p-Diethynylbenzene-based molecular wires, Fe–CC-p-C6H2X2–CC–Fe [Fe=Fe(η5-C5Me5)(dppe)]: Synthesis, substituent effects and unexpected formation of benzodifuran complex. J Organomet Chem 2009, 694, 1840. <>