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Pure Appl. Chem., 2008, Vol. 80, No. 3, pp. 447-457

http://dx.doi.org/10.1351/pac200880030447

Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry

Akira Sekiguchi

Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan

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  • Asay Matthew, Sekiguchi Akira: Recent Developments in the Reactivity of Stable Disilynes. Bull. Chem. Soc. Jpn. 2012, 85, 1245. <http://dx.doi.org/10.1246/bcsj.20120212>
  • Takeuchi Katsuhiko, Ikoshi Masao, Ichinohe Masaaki, Sekiguchi Akira: Silicon version of enamines: Amino-substituted disilenes by the reactions of the disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) with amines. J Organomet Chem 2011, 696, 1156. <http://dx.doi.org/10.1016/j.jorganchem.2010.07.008>
  • Jones Cameron, Bonyhady Simon J., Holzmann Nicole, Frenking Gernot, Stasch Andreas: Preparation, Characterization, and Theoretical Analysis of Group 14 Element(I) Dimers: A Case Study of Magnesium(I) Compounds as Reducing Agents in Inorganic Synthesis. Inrog Chem 2011, 50, 12315. <http://dx.doi.org/10.1021/ic200682p>
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  • Yamaguchi Torahiko, Sekiguchi Akira: Unusual Reactivity of a Disilyne with 4-Dimethylaminopyridine: Formation of an Intramolecularly N-Coordinated Silylene and Its Isomerization to a Zwitterionic Silyl Anion. J Am Chem Soc 2011, 133, 7352. <http://dx.doi.org/10.1021/ja202605x>
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  • Woodul William D., Carter Emma, Müller Robert, Richards Anne F., Stasch Andreas, Kaupp Martin, Murphy Damien M., Driess Matthias, Jones Cameron: A Neutral, Monomeric Germanium(I) Radical. J Am Chem Soc 2011, 133, 10074. <http://dx.doi.org/10.1021/ja204344e>
  • Takeuchi Katsuhiko, Ichinohe Masaaki, Sekiguchi Akira: Access to a Stable Si2N2 Four-Membered Ring with Non-Kekulé Singlet Biradical Character from a Disilyne. J Am Chcm Soc 2011, 133, 12478. <http://dx.doi.org/10.1021/ja2059846>
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  • Takeuchi Katsuhiko, Ichinohe Masaaki, Sekiguchi Akira: Hydroboration of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2), Giving Boryl-Substituted Disilenes. Organomet 2011, 30, 2044. <http://dx.doi.org/10.1021/om200106h>
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  • Matsuo Tsukasa, Suzuki Katsunori, Fukawa Tomohide, Li Baolin, Ito Mikinao, Shoji Yoshiaki, Otani Takashi, Li Liangchun, Kobayashi Megumi, Hachiya Makoto: Synthesis and Structures of a Series of Bulky “Rind-Br” Based on a Rigid Fused-Ring s-Hydrindacene Skeleton. J Chem Soc Japan 2011, 84, 1178. <http://dx.doi.org/10.1246/bcsj.20110090>
  • Bonyhady Simon J., Jones Cameron, Nembenna Sharanappa, Stasch Andreas, Edwards Alison J., McIntyre Garry J.: β-Diketiminate-Stabilized Magnesium(I) Dimers and Magnesium(II) Hydride Complexes: Synthesis, Characterization, Adduct Formation, and Reactivity Studies. Chemistry - A European Journal 2010, 16, 938. <http://dx.doi.org/10.1002/chem.200902425>
  • Yamaguchi Torahiko, Sekiguchi Akira, Driess Matthias: An N-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2. J Am Chem Soc 2010, 132, 14061. <http://dx.doi.org/10.1021/ja107160g>
  • Murata Yoshitaka, Ichinohe Masaaki, Sekiguchi Akira: Unsymmetrically Substituted Disilyne Dsi2iPrSi—Si≡Si—SiNpDsi2 (Np = CH2tBu): Synthesis and Characterization. J Am Chem Soc 2010, 132, 16768. <http://dx.doi.org/10.1021/ja1091744>
  • Takeuchi Katsuhiko, Ikoshi Masao, Ichinohe Masaaki, Sekiguchi Akira: Addition of Amines and Hydroborane to the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) Giving Amino- and Boryl-Substituted Disilenes. J Am Chem Soc 2010, 132, 930. <http://dx.doi.org/10.1021/ja910157h>
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  • Yamaguchi Torahiko, Ichinohe Masaaki, Sekiguchi Akira: Addition of methyllithium to disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]), giving a disilenyllithium, and its unexpected isomerization to a disilacyclopropylsilyllithium. New J Chem 2010, 34, 1544. <http://dx.doi.org/10.1039/c0nj00027b>
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  • Takeuchi Katsuhiko, Ichinohe Masaaki, Sekiguchi Akira, Guo Jing-Dong, Nagase Shigeru: Reactivity of the disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) toward bis(silylcyanide) forming a 1,4-diaza-2,3-disilabenzene analog. J Phys Org Chem 2009, n/a. <http://dx.doi.org/10.1002/poc.1617>
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  • Sekiguchi Akira: ChemInform Abstract: Disilyne with a Silicon-Silicon Triple Bond: A New Entry to Multiple Bond Chemistry. ChemInform 2008, 39. <http://dx.doi.org/10.1002/chin.200830258>
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