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Pure Appl. Chem., 2007, Vol. 79, No. 8, pp. 1383-1402

http://dx.doi.org/10.1351/pac200779081383

Structure, magnetism, and thermodynamics of the novel rare earth-based R5T4 intermetallics

V. K. Pecharsky and K. A. Gschneidner

Ames Laboratory of the U.S. Department of Energy and Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011-3020, USA

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  • Singh Niraj K., Mudryk Ya., Pecharsky V. K., Gschneidner K. A.: In situ X-ray powder diffraction study of Ho5Ge4. J. Appl. Phys. 2014, 115, 17E105. <http://dx.doi.org/10.1063/1.4853215>
  • Hadimani R. L., Mudryk Y., Prost T. E., Pecharsky V. K., Gschneidner K. A., Jiles D. C.: Growth and characterization of Pt-protected Gd5Si4 thin films. J. Appl. Phys. 2014, 115, 17C113. <http://dx.doi.org/10.1063/1.4865322>
  • Mudryk Y., Pecharsky V. K., Gschneidner K. A.: Unusual magnetic frustration in Lu-doped Gd5Ge4. J. Appl. Phys. 2013, 113, 17E104. <http://dx.doi.org/10.1063/1.4793600>
  • Wang C. L., Zou J. D., Liu J., Mudryk Y., Gschneidner K. A., Long Y., Smetana V., Miller G. J., Pecharsky V. K.: Crystal structure, magnetic properties, and the magnetocaloric effect of Gd5Rh4 and GdRh. J. Appl. Phys. 2013, 113, 17A904. <http://dx.doi.org/10.1063/1.4793775>
  • Zou J. D., Liu J., Mudryk Y., Pecharsky V. K., Gschneidner K. A.: Ferromagnetic ordering and Griffiths-like phase behavior in Gd5Ge3.9Al0.1. J. Appl. Phys. 2013, 114, 063904. <http://dx.doi.org/10.1063/1.4817956>
  • Cao Q., Chumbley L. S.: Characterization of second-phase plates in a Gd5Ge3 intermetallic compound. Microscopy 2013, 62, 629. <http://dx.doi.org/10.1093/jmicro/dft029>
  • Liu J., Paudyal D., Mudryk Y., Zou J. D., Gschneidner, Jr. K. A., Pecharsky V. K.: Unusual magnetic and structural transformations of DyFe_{4}Ge_{2}. Phys. Rev. B 2013, 88. <http://dx.doi.org/10.1103/PhysRevB.88.014423>
  • Marcano N., Algarabel P. A., Fernández J. Rodríguez, Magén C., Morellón L., Singh Niraj K., Gschneidner K. A., Pecharsky V. K., Ibarra M. R.: Effects of pressure on the magnetic-structural and Griffiths-like transitions in Dy5Si3Ge. Phys. Rev. B 2013, 88. <http://dx.doi.org/10.1103/PhysRevB.88.214429>
  • Yao Jinlei, Zhang Yuemei, Wang Peng, Lutz Laura, Miller Gordon, Mozharivskyj Yurij: Electronically Induced Ferromagnetic Transitions in Sm5Ge4-Type Magnetoresponsive Phases. Phys. Rev. Lett. 2013, 110. <http://dx.doi.org/10.1103/PhysRevLett.110.077204>
  • Belo J.H., Pereira A.M., Ventura J., Oliveira G.N.P., Araújo J.P., Tavares P.B., Fernandes L., Algarabel P.A., Magen C., Morellon L., Ibarra M.R.: Phase control studies in Gd5Si2Ge2 giant magnetocaloric compound. Journal of Alloys and Compounds 2012, 529, 89. <http://dx.doi.org/10.1016/j.jallcom.2012.02.164>
  • Yuce Suheyla, Barrio Maria, Emre Baris, Stern-Taulats Enric, Planes Antoni, Tamarit Josep-Lluís, Mudryk Yaroslav, Gschneidner Karl A., Pecharsky Vitalij K., Mañosa Lluís: Barocaloric effect in the magnetocaloric prototype Gd5Si2Ge2. Appl. Phys. Lett. 2012, 101, 071906. <http://dx.doi.org/10.1063/1.4745920>
  • Mudryk Ya., Paudyal D., Pecharsky V., Gschneidner K.: Low-temperature crystal structure and magnetic properties of Gd_{5}Ge_{3}. Physical Review B (Condensed Matter and Materials Physics) 2012, 85, 014116. <http://dx.doi.org/10.1103/PhysRevB.85.014116>
  • Marcano N., Algarabel P., Fernández J. Rodríguez, Magén C., Morellón L., Singh Niraj, Schlagel D., Gschneidner K., Pecharsky V., Ibarra M.: Magnetism and magnetocaloric effect of single-crystal Er_{5}Si_{4} under pressure. Physical Review B (Condensed Matter and Materials Physics) 2012, 85, 024408. <http://dx.doi.org/10.1103/PhysRevB.85.024408>
  • Vélez S., Hernandez J., García-Santiago A., Tejada J., Pecharsky V., Gschneidner K., Schlagel D., Lograsso T., Santos P.: Anisotropic magnetic deflagration in single crystals of Gd_{5}Ge_{4}. Physical Review B (Condensed Matter and Materials Physics) 2012, 85, 054432. <http://dx.doi.org/10.1103/PhysRevB.85.054432>
  • Mudryk Ya., Singh Niraj, Pecharsky V., Schlagel D., Lograsso T., Gschneidner K.: Magnetic and structural properties of single-crystalline Er_{5}Si_{4}. Physical Review B (Condensed Matter and Materials Physics) 2012, 85, 094432. <http://dx.doi.org/10.1103/PhysRevB.85.094432>
  • Belo J. H., Pereira A. M., Araújo J. P., de la Cruz C., dos Santos A. M., Gonçalves J. N., Amaral V. S., Morellon L., Ibarra M. R., Algarabel P. A., Magen C.: Tailoring the magnetism of Tb_{5}Si_{2}Ge_{2} compounds by La substitution. Phys. Rev. B 2012, 86. <http://dx.doi.org/10.1103/PhysRevB.86.014403>
  • Mudryk Yaroslav, Pecharsky Vitalij K., Gschneidner Jr. Karl A.: Extraordinary Responsive Intermetallic Compounds: the R5T4 Family (R = Rare Earth, T = Group 13-15 Element). Z anorg allg Chem 2011, 637, 1948. <http://dx.doi.org/10.1002/zaac.201100327>
  • Wang Hui, Wang Fei, Jones Karah, Miller Gordon J.: Chemical Pressure and Rare-Earth Orbital Contributions in Mixed Rare-Earth Silicides La5–xYxSi4 (0 ≤ x ≤ 5). Inrog Chem 2011, 50, 12714. <http://dx.doi.org/10.1021/ic201840q>
  • Zhong X. C., Zou M., Zhang H., Liu Z. W., Zeng D. C., Gschneidner K. A., Pecharsky V. K.: Crystal structure and magnetic properties of R5Sn4 alloys, where R is Tb, Dy, Ho, and Er. J Appl Phys 2011, 109, 07A917. <http://dx.doi.org/10.1063/1.3549562>
  • Nirmala R., Paudyal Durga, Pecharsky V. K., Gschneidner K. A., Nigam A. K.: First order transition in Dy5Si3Ge: Transport and thermal properties, and first principles calculations. J Appl Phys 2011, 109, 07A923. <http://dx.doi.org/10.1063/1.3554255>
  • Nath Mahato Rabindra, Sethupathi K., Sankaranarayanan V., Nirmala R., Nigam A. K., Malik S. K.: Giant magnetoresistance and table-like magnetocaloric effect in double perovskite oxide PrSrMnCoO6. J Appl Phys 2011, 109, 07E319. <http://dx.doi.org/10.1063/1.3556716>
  • Disseler S., Svensson J., Peter S., Byers C., Baines C., Amato A., Giblin S., Carretta P., Graf M.: Competing interactions and magnetic frustration in Yb_{4}LiGe_{4}. Physical Review B (Condensed Matter and Materials Physics) 2011, 84, 174429. <http://dx.doi.org/10.1103/PhysRevB.84.174429>
  • Paudyal Durga, Mudryk Y., Pecharsky V. K., Misra S., Miller G. J., Gschneidner K. A.: Influence of Y substitutions on the magnetism of Gd[sub 5]Ge[sub 4] . J Appl Phys 2010, 107, 09A908. <http://dx.doi.org/10.1063/1.3349231>
  • Nirmala R., Morozkin A. V., Lamsal Jagat, Yelon W. B., Malik S. K.: Magnetic transition in the rare earth intermetallic compound Ce[sub 5]Ge[sub 4]: Heat capacity and neutron diffraction studies. J Appl Phys 2010, 107, 09E308. <http://dx.doi.org/10.1063/1.3360185>
  • Singh Niraj K., Paudyal Durga, Pecharsky V. K., Gschneidner K. A.: Magnetic and magnetothermodynamic properties of Ho[sub 5]Si[sub 4]. J Appl Phys 2010, 107, 09A921. <http://dx.doi.org/10.1063/1.3365515>
  • Hansen B. R., Bahl C. R. H., Kuhn L. Theil, Smith A., Gschneidner K. A., Pecharsky V. K.: Consequences of the magnetocaloric effect on magnetometry measurements. J Appl Phys 2010, 108, 043923. <http://dx.doi.org/10.1063/1.3466977>
  • Singh Niraj K., Paudyal D., Mudryk Ya., Pecharsky V. K., Gschneidner K. A.: Magnetostructural properties of Ho_{5}(Si_{0.8}Ge_{0.2})_{4}. Phys. Rev. B 2010, 81. <http://dx.doi.org/10.1103/PhysRevB.81.184414>
  • Paudyal Durga, Mudryk Ya., Pecharsky V., Gschneidner K.: Competing crystal and magnetic structures in Gd_{5}Ge_{4}. Phys Rev B 2010, 82, 144413. <http://dx.doi.org/10.1103/PhysRevB.82.144413>
  • Mudryk Y., Paudyal D., Pecharsky V., Gschneidner K., Misra S., Miller G.: Controlling Magnetism of a Complex Metallic System Using Atomic Individualism. Phys Rev Letters 2010, 105, 066401. <http://dx.doi.org/10.1103/PhysRevLett.105.066401>
  • Misra Sumohan, Poweleit Eric T., Miller Gordon J.: On the Crystal Structure, Metal Atom Site Preferences and Magnetic Properties of Nd5-xErxTt4 (Tt = Si or Ge). Z anorg allg Chem 2009, 635, 889. <http://dx.doi.org/10.1002/zaac.200801353>
  • Gschneidner K.A.: The magnetocaloric effect, magnetic refrigeration and ductile intermetallic compounds. Acta Mater 2009, 57, 18. <http://dx.doi.org/10.1016/j.actamat.2008.08.048>
  • Gschneidner K.A., Mudryk Ya., Becker A.T., Larson J.L.: The crystal structures of some RM and RM2 compounds (where R=rare earth metal and M=non - rare earth metal). Calphad J 2009, 33, 8. <http://dx.doi.org/10.1016/j.calphad.2008.07.008>
  • Zou M., Pecharsky V.K., Gschneidner K.A., Schlagel D.L., Lograsso T.A.: Spontaneous generation of voltage in the magnetocaloric compound Tb5Si2.2Ge1.8 and elemental Gd. J Alloys Comp 2009, 488, 550. <http://dx.doi.org/10.1016/j.jallcom.2008.09.032>
  • Singh Niraj K., Paudyal Durga, Mudryk Ya., Pecharsky V. K., Gschneidner K. A.: Magnetostructural transition in Ho_{5}Ge_{4} . Phys Rev B 2009, 79, 094115. <http://dx.doi.org/10.1103/PhysRevB.79.094115>
  • Arnold Z., Magen C., Morellon L., Algarabel P., Kamarad J., Ibarra M., Pecharsky V., Gschneidner K.: Magnetocaloric effect of Er5Si4 under hydrostatic pressure. Phys Rev B 2009, 79, 144430. <http://dx.doi.org/10.1103/PhysRevB.79.144430>
  • Zou M., Sampaio J. A., Pecharsky V. K., Gschneidner K. A.: Spontaneous generation of voltage in the magnetocaloric compound La(Fe_{0.88}Si_{0.12})_{13} and comparison to SmMn_{2}Ge_{2} . Phys Rev B 2009, 80, 172403. <http://dx.doi.org/10.1103/PhysRevB.80.172403>
  • Chernyshov A. S., Mudryk Ya., Paudyal D., Pecharsky V. K., Gschneidner K. A., Schlagel D. L., Lograsso T. A.: Magnetostructural transition in Gd_{5}Sb_{0.5}Ge_{3.5} . Phys Rev B 2009, 80, 184416. <http://dx.doi.org/10.1103/PhysRevB.80.184416>
  • Roy S.B., Chaddah P., Pecharsky V.K., Gschneidner K.A.: Overview No. 145 Metamagnetic transitions, phase coexistence and metastability in functional magnetic materials. Acta Mater 2008, 56, 5895. <http://dx.doi.org/10.1016/j.actamat.2008.08.040>
  • Paudyal Durga, Pecharsky V K, Gschneidner Jr K A: Origins of ferromagnetism and antiferromagnetism in Gd5Ge4. J Phys Condens Matter 2008, 20, 235235. <http://dx.doi.org/10.1088/0953-8984/20/23/235235>
  • Moore J D, Perkins G K, Morrison K, Ghivelder L, Chattopadhyay M K, Roy S B, Chaddah P, Gschneidner Jr K A, Pecharsky V K, Cohen L F: Local probing of arrested kinetics in Gd5Ge4. J Phys Condens Matter 2008, 20, 465212. <http://dx.doi.org/10.1088/0953-8984/20/46/465212>
  • Singh Niraj K.: Unusual magnetic properties of (Er_{1−x}Gd_{x})_{5}Si_{4} compounds. Phys Rev B 2008, 77, 054414. <http://dx.doi.org/10.1103/PhysRevB.77.054414>
  • Ouyang Z., Nojiri H., Yoshii S., Rao G., Wang Y., Pecharsky V., Gschneidner K.: Field-induced magnetostructural transition in Gd5Ge4 studied by pulsed magnetic fields. Phys Rev B 2008, 77, 184426. <http://dx.doi.org/10.1103/PhysRevB.77.184426>
  • Paudyal Durga, Mudryk Ya., Lee Y., Pecharsky V., Gschneidner K., Harmon B.: Understanding the extraordinary magnetoelastic behavior in GdNi. Phys Rev B 2008, 78, 184436. <http://dx.doi.org/10.1103/PhysRevB.78.184436>
  • Tseng Y., Haskel D., Souza-Neto N., Mudryk Ya., Pecharsky V., Gschneidner K.: Pressure-induced removal of magnetostructural inhomogeneity in Ge-rich Gd5(SixGe1−x)4 giant magnetocaloric alloys. Phys Rev B 2008, 78, 214433. <http://dx.doi.org/10.1103/PhysRevB.78.214433>
  • Pecharsky V. K., Gschneidner K. A. Jr.: Structure, Magnetism, and Thermodynamics of the Novel Rare Earth-Based Ln5T4 Intermetallics. ChemInform 2007, 38. <http://dx.doi.org/10.1002/chin.200752230>