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Pure Appl. Chem., 2007, Vol. 79, No. 6, pp. 1135-1151

Solvation in pure and mixed solvents: Some recent developments

Omar A. El Seoud

Instituto de Química, Universidade de São Paulo, C.P. 26077, 05513-970, São Paulo, S.P., Brazil

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  • Nawaz Haq, Pires Paulo A. R., Bioni Thaís A., Arêas Elizabeth P. G., El Seoud Omar A.: Mixed solvents for cellulose derivatization under homogeneous conditions: kinetic, spectroscopic, and theoretical studies on the acetylation of the biopolymer in binary mixtures of an ionic liquid and molecular solvents. Cellulose 2014. <>
  • Naderi Fereshteh, Farajtabar Ali, Gharib Farrokh: Solvatochromic and preferential solvation of fluorescein in some water-alcoholic mixed solvents. Journal of Molecular Liquids 2014, 190, 126. <>
  • Gharib Farrokh, Shamel Ali, Jaberi Fatemeh, Farajtabar Ali: Spectral Investigations of Preferential Solvation and Solute–Solvent Interactions of Free Base and Protonated 5,10,15,20-Tetrakis(4-trimethyl-ammonio-phenyl)-porphine Tetratosylate in Aqueous Organic Mixed Solvents. J Solution Chem 2013, 42, 1083. <>
  • Fidale Ludmila C., Heinze Thomas, El Seoud Omar A.: Perichromism: A powerful tool for probing the properties of cellulose and its derivatives. Carbohydrate Polymers 2013, 93, 129. <>
  • Salmar Siim, Kuznetsov Aleksei, Tuulmets Ants, Järv Jaak, Piiskop Sander: Kinetic sonication effects in light of molecular dynamics simulation of the reaction medium. Ultrasonics Sonochemistry 2013, 20, 703. <>
  • Dub Pavel A., Ikariya Takao: Quantum Chemical Calculations with the Inclusion of Nonspecific and Specific Solvation: Asymmetric Transfer Hydrogenation with Bifunctional Ruthenium Catalysts. J. Am. Chem. Soc. 2013, 135, 2604. <>
  • Jones Brynna H., Huber Christopher J., Massari Aaron M.: Solvent-Mediated Vibrational Energy Relaxation from Vaska’s Complex Adducts in Binary Solvent Mixtures. J. Phys. Chem. A 2013, 117, 6150. <>
  • Jones Brynna H., Massari Aaron M.: Origins of Spectral Broadening in Iodated Vaska’s Complex in Binary Solvent Mixtures. J. Phys. Chem. B 2013, 117, 15741. <>
  • Fidale Ludmila C., Lima Paulo M., Hortêncio Lucas M. A., Pires Paulo A. R., Heinze Thomas, El Seoud Omar A.: Employing perichromism for probing the properties of carboxymethyl cellulose films: an expedient, accurate method for the determination of the degree of substitution of the biopolymer derivative. Cellulose 2012, 19, 151. <>
  • Amenta Valeria, Cook Joanne L., Hunter Christopher A., Low Caroline M. R., Vinter Jeremy G.: Influence of Solvent Polarity on Preferential Solvation of Molecular Recognition Probes in Solvent Mixtures. J. Phys. Chem. B 2012, 116, 14433. <>
  • El Seoud Omar A., da Silva Valdinéia C., Possidonio Shirley, Casarano Romeu, Arêas Elizabeth P. G., Gimenes Paula: Microwave-Assisted Derivatization of Cellulose, 2 - The Surprising Effect of the Structure of Ionic Liquids on the Dissolution and Acylation of the Biopolymer. Macromolecular Chem Phys 2011, 212, 2541. <>
  • Ribeiro Eduardo Alberton, Sidooski Thiago, Nandi Leandro Guarezi, Machado Vanderlei Gageiro: Interaction of protonated merocyanine dyes with amines in organic solvents. Spectochim Acta A 2011, 81, 745. <>
  • Farajtabar Ali, Jaberi Fatemeh, Gharib Farrokh: Preferential solvation and solvation shell composition of free base and protonated 5, 10, 15, 20-tetrakis(4-sulfonatophenyl)porphyrin in aqueous organic mixed solvents. Spectochim Acta A 2011, 83, 213. <>
  • Leal José M., Navarro Ana M., García Begoña, Hoyuelos Francisco J., Peñacoba Indalecio A.: Preferential Solvation in Alkan-1-ol/Alkylbenzoate Binary Mixtures by Solvatochromic Probes. Chem B 2011, 115, 10259. <>
  • Bhattacharyya S. P., Mandal Abhijit, Misra Ramprasad: Spectral Response of 4-Methyl-2,6-dicarbomethoxyphenol, an Excited-State Intramolecular Proton-Transfer Probe in Cyclohexane–Ethanol Mixtures: Signatures of Medium Microheterogeneity. Chem B 2011, 115, 11840. <>
  • Amenta Valeria, Cook Joanne L., Hunter Christopher A., Low Caroline M. R., Vinter Jeremy G.: Molecular recognition probes of solvation thermodynamics in solvent mixtures. Biomol Chem 2011, 9, 7571. <>
  • El-Mallah N. M., Senior S. A., Nabil G. M., Ramadan M. Sh., Hamed E. A.: Effect of acetonitrile-water mixtures on the reaction of dinitrochlorobenzene and dinitrochlorobenzotrifluoride with hydroxide ion. Int J Chem Kinet 2010, 42, 453. <>
  • Samiey Babak, Toosi Ali Raoof: Kinetics of malachite green fading in alcohol-water binary mixtures. Int J Chem Kinet 2010, 42, 508. <>
  • Fidale Ludmila C., Ißbrücker Constance, Silva Priscilla L., Lucheti Camila M., Heinze Thomas, El Seoud Omar A.: Probing the dependence of the properties of cellulose acetates and their films on the degree of biopolymer substitution: use of solvatochromic indicators and thermal analysis. Cellulose 2010, 17, 937. <>
  • Sato Bruno M., de Oliveira Carolina G., Martins Clarissa T., El Seoud Omar A.: Thermo-solvatochromism in binary mixtures of water and ionic liquids: on the relative importance of solvophobic interactions. Phys Chem Chem Phys 2010, 12, 1764. <>
  • Cabot Rafel, Hunter Christopher A.: A thermodynamic study of selective solvation in solvent mixtures. Org Biomol Chem 2010, 8, 1943. <>
  • Fidale Ludmila C., Possidonio Shirley, El Seoud Omar A.: Application of 1-Allyl-3-(1-butyl)imidazolium Chloride in the Synthesis of Cellulose Esters: Properties of the Ionic Liquid, and Comparison with Other Solvents. Macromol Biosci 2009, 9, 813. <>
  • Martins Clarissa T., Lima Michelle S., Bastos Erick L., El Seoud Omar A.: Thermo-Solvatochromism of Merocyanine Polarity Probes – What Are the Consequences of Increasing Probe Lipophilicity through Annelation?. Eur J Org Chem 2008, 2008, 1165. <>
  • Fidale Ludmila C., Ruiz Naiara, Heinze Thomas, Seoud Omar A. El: Cellulose Swelling by Aprotic and Protic Solvents: What are the Similarities and Differences?. Macromol Chem Phys 2008, 209, 1240. <>
  • Fracaroli Alejandro M., Silva O. Fernando, Granados Alejandro M., de Rossi Rita H.: 3H-1,2-Dithiole-3-thione derivatives as novel solvatochromic dyes. J Phys Org Chem 2008, 21, 1007. <>
  • El Seoud Omar A.: Solvation in Pure and Mixed Solvents: Some Recent Developments. ChemInform 2007, 38. <>