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Pure Appl. Chem., 2007, Vol. 79, No. 6, pp. 1111-1123

Microemulsions as microreactors in physical organic chemistry

Luis García-Río1, J. Ramon Leis1, Juan Carlos Mejuto2 and Moisés Pérez-Lorenzo1

1 Departamento de Química Física, Facultad de Química, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain
2 Departamento de Química Física, Facultad de Ciencias, Universidad de Vigo, Ourense, Spain

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  • Saha Rumpa, Ghosh Aniruddha, Saha Bidyut: Combination of best promoter and micellar catalyst for chromic acid oxidation of 1-butanol to 1-butanal in aqueous media at room temperature. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2014, 124, 130. <>
  • Schrader Philipp, Culaguin-Chicaroux Andres, Enders Sabine: Phase behavior of the water+nonionic surfactant (C12E8)+1-dodecene ternary system across a wide temperature range. Chemical Engineering Science 2013, 93, 131. <>
  • Schrader Philipp, Paasche Christian, Enders Sabine: Phase behavior of systems containing Genapol X080®+technical 1-dodecene+water compared with the phase behavior of pure C12E8+pure 1-dodecene+water. Chemical Engineering Science 2013. <>
  • Romsted Laurence S., Bravo-Díaz Carlos: Modeling chemical reactivity in emulsions. Current Opinion in Colloid & Interface Science 2013, 18, 3. <>
  • Hayes Douglas G., Alkhatib Mayson H., Gomez del Rio Javier, Urban Volker S.: Physicochemical characterization of water-in-oil microemulsions formed by a binary 1,3-dioxolane alkyl ethoxylate/Aerosol-OT surfactant system. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2013, 417, 99. <>
  • Moldes Óscar A., Astray Gonzalo, Cid Antonio, Iglesias-Otero Manuel Á., Morales Jorge, Mejuto Juan C.: Percolation Threshold of AOT Microemulsions with n-Alkyl Acids as Additives Prediction by Means of Artificial Neural Networks. TSD 2013, 50, 360. <>
  • Cid A., Mejuto J.C., Orellana P.G., López-Fernández O., Rial-Otero R., Simal-Gandara J.: Effects of ascorbic acid on the microstructure and properties of SDS micellar aggregates for potential food applications. Food Research International 2012. <>
  • Morales Jorge, Manso José A., Cid Antonio, Lodeiro Carlos, Mejuto Juan Carlos: Degradation of carbofuran derivatives in restricted water environments: Basic hydrolysis in AOT-based microemulsions. Journal of Colloids and Interface Science 2012, 372, 113. <>
  • Shrivastava Alpa, Singh Ajaya Kumar, Sachdev Neerja, Shrivastava Dilip Raj, Katre Yokraj, Singh Surya P., Singh Man, Mejuto J.C.: Micelle catalyzed oxidative degradation of norfloxacin by chloramine-T. Journal of Molecular Catalysis A: Chemical 2012, 361-362, 1. <>
  • Dvores Michelle P., Marom Gad, Magdassi Shlomo: Formation of Organic Nanoparticles by Electrospinning of Volatile Microemulsions. Langmir 2012, 28, 6978. <>
  • Rico-Lattes Isabelle, Perez Emile, Franceschi-Messant Sophie, Lattes Armand: Organized molecular systems as reaction media. Chim 2011, 14, 700. <>
  • Lloyd Nathan W., Kardaras Eleni, Ebeler Susan E., Dungan Stephanie R.: Measuring Local Equilibrium Flavor Distributions in SDS Solution Using Headspace Solid-Phase Microextraction. Chem B 2011, 115, 14484. <>
  • Astray G., Cid A., Manso J.A., Moldes O., Morales J., Quintás J.: Dyes and biomimetic systems: detergency and food industry Colorantes y sistemas biomiméticos: detergencia e industria alimentaria. CyTA - Journal of Food 2011, 9, 252. <>
  • Cid A., Gómez-Díaz D., Mejuto J. C., Navaza J. M.: Viscosity and Percolative Phenomena in AOT based Microemulsions. TSD 2011, 48, 165. <>
  • Shrikhande Janhavi J., Hassan P.A., Jayaram R.V.: Condensation reaction of benzaldehyde and acetone in o/w microemulsions: Effect of microemulsion compositions. Colloid Surf A Phys Eng Aspects 2010, 370, 64. <>
  • Fernández-Alonso Alejandra, Pastoriza Gallego Ma José, Bravo-Díaz Carlos: Butanolysis of 4-methylbenzenediazonium ions in binary n-BuOH/H2O mixtures and in n-BuOH/SDS/H2O reverse micelles. Effects of solvent composition, acidity and temperature on the switch between heterolytic and homolytic dediazoniation mechanisms. Org Biomol Chem 2010, 8, 5304. <>
  • Pastoriza-Gallego M. José, Bravo-Díaz Carlos: Butanolysis of 2-methylbenzenediazonium ions: product distribution, rate constants of product formation, and activation parameters. J Phys Org Chem 2009, 22, 390. <>
  • Arias-Estevez M., Astray G., Cid A., Fernández-Gándara D., García-Río L., Mejuto J. C.: Influence of colloid suspensions of humic acids upon the alkaline fading of carbocations. J Phys Org Chem 2008, 21, 555. <>
  • Pan Xiaoming, Bhatia Surita R.: Effect of counterion substitution on the viscosity anomaly in AOT microemulsions. Journal of Colloid and Interface Science 2008, 327, 152. <>
  • Chechik Victor: Reactivity in organised assemblies. Annu Rep Prog Chem Sect B 2008, 104, 331. <>
  • Garcia-Rio Luis, Leis J. Ramon, Mejuto Juan Carlos, Perez-Lorenzo Moises: Microemulsions as Microreactors in Physical Organic Chemistry. ChemInform 2007, 38. <>