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Pure Appl. Chem., 2007, Vol. 79, No. 4, pp. 701-713

Enantioselective constructions of quaternary carbons and their application to the asymmetric total syntheses of fredericamycin A and discorhabdin A

Yasuyuki Kita and Hiromichi Fujioka

Faculty of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565, Japan

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  • Zheng ZiSheng, Zhang-Negrerie Daisy, Du YunFei, Zhao Kang: The applications of hypervalent iodine(III) reagents in the constructions of heterocyclic compounds through oxidative coupling reactions. Sci. China Chem. 2014, 57, 189. <>
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  • Shintani Ryo, Isobe Shingo, Takeda Momotaro, Hayashi Tamio: Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes. Angew Chem 2010, 122, 3883. <>
  • Shintani Ryo, Isobe Shingo, Takeda Momotaro, Hayashi Tamio: Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes. Angew Chem Int Ed 2010, 49, 3795. <>
  • García Ruano José Luis, Martín-Castro Ana M., Tato Francisco, Torrente Esther, Poveda Ana M.: Stereodivergent Quaternization of 2-Alkyl-2-p-tolylsulfinylacetonitriles: NMR Spectroscopic Evidence of Planar and Pyramidal Benzylic Carbanions. Chem Eur J 2010, 16, 6317. <>
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  • Liang Huan, Ciufolini Marco A.: Synthetic aspects of the oxidative amidation of phenols. Tetrahedron 2010, 66, 5884. <>
  • Geraskin Ivan M., Pavlova Olga, Neu Heather M., Yusubov Mekhman S., Nemykin Victor N., Zhdankin Viktor V.: Comparative Reactivity of Hypervalent Iodine Oxidants in Metalloporphyrin-Catalyzed Oxygenation of Hydrocarbons: Iodosylbenzene Sulfate and 2-Iodylbenzoic Acid Ester as Safe and Convenient Alternatives to Iodosylbenzene. Adv Synth Catal 2009, 351, 733. <>
  • Neu Heather M., Yusubov Mekhman S., Zhdankin Viktor V., Nemykin Victor N.: Binuclear Iron(III) Phthalocyanine(μ-Oxodimer)-Catalyzed Oxygenation of Aromatic Hydrocarbons with Iodosylbenzene Sulfate and Iodosylbenzene as the Oxidants. Adv Synth Catal 2009, 351, 3168. <>
  • Yusubov Mekhman S., Zagulyaeva Aleksandra A., Zhdankin Viktor V.: Iodine(V)/Ruthenium(III)-Cocatalyzed Oxidations: A Highly Efficient Tandem Catalytic System for the Oxidation of Alcohols and Hydrocarbons with Oxone. Chem Eur J 2009, 15, 11091. <>
  • Zhong Wei, Little R. Daniel: Exploration and determination of the redox properties of the pseudopterosin class of marine natural products. Tetrahedron 2009, 65, 10784. <>
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  • Zhdankin Viktor V., Nemykin Victor N., Karimov Rashad R., Kazhkenov Zeinul-Gabiden: Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline oxides: first entry into the heterocyclic system of benziodoxazole. Chem Commun 2008, 6131. <>
  • Kita Yasuyuki, Fujioka Hiromichi: Enantioselective Constructions of Quaternary Carbons and Their Application to the Asymmetric Total Syntheses of Fredericamycin A and Discorhabdin A. ChemInform 2007, 38. <>