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Pure Appl. Chem., 2007, Vol. 79, No. 12, pp. 2155-2177

Chemistry of porous coordination polymers

Tapas Kumar Maji1 and Susumu Kitagawa2

1 Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560 064, India
2 Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura campus, Kyoto, 615-8510, Japan

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  • Shankar Ravi, Singh Rohit, Kociok-Köhn Gabriele, Molloy Kieran C.: Studies on the Coordination Behavior of Methanesulfonate in Zinc(II) Based Two and Three Dimensional Supramolecular Assemblies. Proc. Natl. Acad. Sci., India, Sect. A Phys. Sci. 2014. <>
  • Motakef-Kazemi Negar, Shojaosadati Seyed Abbas, Morsali Ali: In situ synthesis of a drug-loaded MOF at room temperature. Microporous and Mesoporous Materials 2014, 186, 73. <>
  • Iyer Abishek K., Peter Sebastian C.: Two-Dimensional Bicapped Supramolecular Hybrid Semiconductor Material Constructed from the Insulators α-Keggin Polyoxomolybdate and 4,4′-Bipyridine. Inorg. Chem. 2014, 53, 653. <>
  • Boldog Ishtvan, Domasevitch Konstantin, Maclaren Jana K., Heering Christian, Makhloufi Gamall, Janiak Christoph: A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs. CrystEngComm 2014, 16, 148. <>
  • Khutia Anupam, Janiak Christoph: Programming MIL-101Cr for selective and enhanced CO2 adsorption at low pressure by postsynthetic amine functionalization. Dalton Trans. 2014, 43, 1338. <>
  • Sen Susan, Neogi Subhadip, Aijaz Arshad, Xu Qiang, Bharadwaj Parimal K.: Structural variation in Zn(ii) coordination polymers built with a semi-rigid tetracarboxylate and different pyridine linkers: synthesis and selective CO2 adsorption studies. Dalton Trans. 2014, 43, 6100. <>
  • Zhang Zhong Jie, Xie Dong Hua, Cui Peng, Chen Xiang Ying: Conversion of a zinc salicylate complex into porous carbons through a template carbonization process as a superior electrode material for supercapacitors. RSC Adv. 2014, 4, 6664. <>
  • Suresh Venkata M., George Subi J., Maji Tapas Kumar: MOF Nano-Vesicles and Toroids: Self-Assembled Porous Soft-Hybrids for Light Harvesting. Adv. Funct. Mater. 2013, 23, 5585. <>
  • Morisaki Yasuhiro, Gon Masayuki, Chujo Yoshiki: Conjugated microporous polymers consisting of tetrasubstituted [2.2]Paracyclophane junctions. J. Polym. Sci. A Polym. Chem. 2013, 51, 2311. <>
  • Brassinne Jérémy, Fustin Charles-André, Gohy Jean-François: Polymer Gels Constructed Through Metal–Ligand Coordination. J Inorg Organomet Polym 2013, 23, 24. <>
  • Darling Kari, Ouellette Wayne, Prosvirin Andrey, Walter Shannon, Dunbar Kim R., Zubieta Jon: Hydrothermal synthesis and structures of materials of the M(II)/tetrazole/sulfate family (M(II)=Co, Ni; tetrazole=3- and 4-pyridyltetrazole and pyrazinetetrazole). Polyhedron 2013, 58, 18. <>
  • Jayaramulu Kolleboyina, Haldar Ritesh, Maji Tapas Kumar: Self-assembly of tetrabromoterephthalic acid with different metal system: Diversity in dimensionalities, structures and gas adsorption. Polyhedron 2013, 52, 553. <>
  • Saha Rajat, Dey Sanjoy Kumar, Biswas Susobhan, Jana Atish Dipankar, Kumar Sanjay: Transformation of a Mother Crystal to a Daughter Crystal through Amorphous Phase: De-assembly of Coordination Helices upon Heating and Re-assembly through Aquation. Crystal Growth & Design 2013, 13, 2135. <>
  • Khutia Anupam, Rammelberg Holger Urs, Schmidt Thomas, Henninger Stefan, Janiak Christoph: Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat Transformation Application. Chem. Mater. 2013, 25, 790. <>
  • Mazaj Matjaž, Mali Gregor, Rangus Mojca, Žunkovič Emanuela, Kaučič Venčeslav, Zabukovec Logar Nataša: Spectroscopic Studies of Structural Dynamics Induced by Heating and Hydration: A Case of Calcium-Terephthalate Metal–Organic Framework. J. Phys. Chem. C 2013, 117, 7552. <>
  • Boldog Ishtvan, Domasevitch Konstantin V., Baburin Igor A., Ott Holger, Gil-Hernández Beatriz, Sanchiz Joaquín, Janiak Christoph: A rare alb-4,8-Cmce metal–coordination network based on tetrazolate and phosphonate functionalized 1,3,5,7-tetraphenyladamantane. CrystEngComm 2013, 15, 1235. <>
  • Mathias Jenny-Lee, Arora Himanshu, Lavi Ronit, Vezin Hervé, Yufit Dmitry, Orio Maylis, Aliaga-Alcade Núria, Benisvy Laurent: Redox-switchable tetra-copper assembly of N,N-, N,O-phenolate-phenanthroimidazolate bridging ligands. Dalton Trans. 2013, 42, 2358. <>
  • Mehlana Gift, Ramon Gaëlle, Bourne Susan A: Methanol mediated crystal transformations in a solvatochromic metal organic framework constructed from Co(ii) and 4-(4-pyridyl) benzoate. CrystEngComm 2013, 15, 9521. <>
  • Noro Shin-ichiro, Fukuhara Katsuo, Sugimoto Kunihisa, Hijikata Yuh, Kubo Kazuya, Nakamura Takayoshi: Anion-dependent host–guest properties of porous assemblies of coordination complexes (PACs), [Cu(A)2(py)4] (A = PF6, BF4, CF3SO3, and CH3SO3; py = pyridine), based on Werner-type copper(ii) complexes in the solid state. Dalton Trans. 2013, 42, 11100. <>
  • Samanta Dipak, Mukherjee Partha Sarathi: PtII6 nanoscopic cages with an organometallic backbone as sensors for picric acid. Dalton Trans. 2013, 42, 16784. <>
  • Chang Xin-Hong, Sun Xiao-Yuan: A New 5-Connected Co(II) Complex With 5-Methylisophthalic Acid: Synthesis, Crystal Structure, and Properties. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 2013, 43, 250. <>
  • Jeazet Harold, Koschine Tönjes, Staudt Claudia, Raetzke Klaus, Janiak Christoph: Correlation of Gas Permeability in a Metal-Organic Framework MIL-101(Cr)–Polysulfone Mixed-Matrix Membrane with Free Volume Measurements by Positron Annihilation Lifetime Spectroscopy (PALS). Membranes 2013, 3, 331. <>
  • Kanoo Prakash, Ghosh Ashta Chandra, Cyriac Soumya T., Maji Tapas Kumar: A Metal-Organic Framework with Highly Polar Pore Surfaces: Selective CO2 Adsorption and Guest-Dependent On/Off Emission Properties. Chemistry A European Journal 2012, 18, 237. <>
  • Arai Takayoshi, Sakagami Ken: Asymmetric Benzoylation of meso-Hydrobenzoin Using a Reusable Tripodal Imidazoline-Pyridine-Cu Catalyst. Eur J Org 2012, 2012, 1097. <>
  • Deshmukh Milind M., Sakaki Shigeyoshi: Two-step evaluation of binding energy and potential energy surface of van der Waals complexes. J. Comput. Chem. 2012, 33, 617. <>
  • Morisaki Yasuhiro, Gon Masayuki, Tsuji Yuichi, Kajiwara Yuichi, Chujo Yoshiki: Synthesis and Characterization of [2.2]Paracyclophane-Containing Conjugated Microporous Polymers. Macromolecular Chem Phys 2012, 213, 572. <>
  • Boldog Ishtvan, Xing Lei, Schulz Axel, Janiak Christoph: Influence of sterically non-hindering methyl groups on adsorption properties of two classical zinc and copper MOF types. Comptes Rendus Chimie 2012, 15, 866. <>
  • Wibowo Arief C., Smith Mark D., Yeon Jeongho, Halasyamani P. Shiv, zur Loye Hans-Conrad: Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties. Journal of Solid State Chemistry 2012, 195, 94. <>
  • Coropceanu Eduard B., Croitor Lilia, Fonari Marina S.: Mononuclear Cd(II) and Zn(II) complexes with the 1,2-cyclohexanedionedioxime ligand: Preparation and structural characterization. Polyhedron 2012, 38, 68. <>
  • Saravanabharathi D., Obulichetty M., Rameshkumar S., Kumaravel M.: Rapid crystallization and proton conductivity of copper (II)-l-tartrate. Synthetic Metals 2012, 162, 1519. <>
  • Jayaramulu Kolleboyina, Reddy Sandeep Kumar, Hazra Arpan, Balasubramanian Sundaram, Maji Tapas Kumar: Three-Dimensional Metal–Organic Framework with Highly Polar Pore Surface: H2 and CO2 Storage Characteristics. Inorg. Chem. 2012, 51, 7103. <>
  • Haldar Ritesh, Maji Tapas Kumar: Selective carbon dioxide uptake and crystal-to-crystal transformation: porous 3D framework to 1D chain triggered by conformational change of the spacer. CrystEngCommun 2012, 14, 684. <>
  • Jeremias Felix, Henninger Stefan K., Janiak Christoph: High performance metal–organic-framework coatings obtained via thermal gradient synthesis. Chem. Commun. 2012, 48, 9708. <>
  • Croitor Lilia, Coropceanu Eduard B., Siminel Anatolii V., Kulikova Olga, Zelentsov Vyacheslav I., Datsko Tatiana, Fonari Marina S.: 1,2-Cyclohexanedionedioxime as a useful co-ligand for fabrication of one-dimensional Zn(ii) and Cd(ii) coordination polymers with wheel-and-axle topology and luminescent properties. CrysEngComm 2012, 14, 3750. <>
  • Yeşilel Okan Zafer, Günay Güneş, Darcan Cihan, Soylu Mustafa Serkan, Keskin Seda, Ng Seik Weng: An unusual 3D metal–organic framework, {[Ag4(μ4-pzdc)2(μ-en)2]·H2O}n: C–H⋯Ag, N–H⋯Ag and (O–H)⋯Ag interactions and an unprecedented coordination mode for pyrazine-2,3-dicarboxylate. CrysEngComm 2012, 14, 2817. <>
  • Tanh Jeazet Harold B., Staudt Claudia, Janiak Christoph: Metal–organic frameworks in mixed-matrix membranes for gas separation. Dalton Trans. 2012, 41, 14003. <>
  • Jeremias Felix, Khutia Anupam, Henninger Stefan K., Janiak Christoph: MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application. J Materials Chemistry 2012, 22, 10148. <>
  • Wei Qiang, Yang Dali, Larson Toti Eric, Kinnibrugh Tiffany L., Zou Ruqiang, Henson Neil J., Timofeeva Tatiana, Xu Hongwu, Zhao Yusheng, Mattes Benjamin R.: Kinetic hysteresis in gas adsorption behavior for a rigid MOF arising from zig-zag channel structures. J Materials Chemistry 2012, 22, 10166. <>
  • Han Sol, Lough Alan J., Kim Ju-Chang: Synthesis, Crystal Structures and Properties of Macrocyclic Copper(II) Complexes Containing Imidazole Pendants. Bulletin of the Korean Chemical Society 2012, 33, 2381. <>
  • Han Shuangbing, Wei Yanhu, Valente Cory, Forgan Ross S., Gassensmith Jeremiah J., Smaldone Ronald A., Nakanishi Hideyuki, Coskun Ali, Stoddart J. Fraser, Grzybowski Bartosz A.: Imprinting Chemical and Responsive Micropatterns into Metal-Organic Frameworks. Angew Chem 2011, 123, 290. <>
  • Han Shuangbing, Wei Yanhu, Valente Cory, Forgan Ross S., Gassensmith Jeremiah J., Smaldone Ronald A., Nakanishi Hideyuki, Coskun Ali, Stoddart J. Fraser, Grzybowski Bartosz A.: Imprinting Chemical and Responsive Micropatterns into Metal-Organic Frameworks. Angew Chem Int Ed 2011, 50, 276. <>
  • Hügle Thomas, Hartl Monika, Lentz Dieter: The Route to a Feasible Hydrogen-Storage Material: MOFs versus Ammonia Borane. Chemistry A European Journal 2011, 17, 10184. <>
  • Das Sunirban, Maloth Swamy, Pal Samudranil: Nickel(II) Coordination Polymers - 4,4′-Bipyridine-Connected Six- and Four-Fold Metal-Succinate Helices and Their Corresponding Chiral and Achiral Networks. Eur J Inorg Chem 2011, 2011, 4270. <>
  • Mu Bin, Walton Krista S.: Adsorption equilibrium of methane and carbon dioxide on porous metal-organic framework Zn-BTB. Adsorption 2011. <>
  • Biswas Susobhan, Saha Rajat, Steele Ian M., Mostafa Golam: Planar tetrameric metal cluster formation at room temperature induced by π⋯π interactions: 3D supramolecular host containing 1D channel filled with solvent methanol. Inorganica Chimica Acta 2011, 368, 216. <>
  • Meng Xian-Rui, Zhong Di-Chang, Jiang Long, Li Huan-Yong, Lu Tong-Bu: Unprecedented Tuning of Structures and Gas Sorption Properties of Two 2D Nickel Metal−Organic Frameworks via Altering the Positions of Fluorine Atoms in Azamacrocyclic Ligands. Cryst Growth Des 2011, 11, 2020. <>
  • Dey Rajdip, Haldar Ritesh, Maji Tapas Kumar, Ghoshal Debajyoti: Three-Dimensional Robust Porous Coordination Polymer with Schiff Base Site on the Pore Wall: Synthesis, Single-Crystal-to-Single-Crystal Reversibility, and Selective CO2 Adsorption. Growth Des 2011, 11, 3905. <>
  • Hogan Greg A., Rath Nigam P., Beatty Alicia M.: A Stable Hydrogen-Bonded Coordination Network with Removable Guests. Growth Des 2011, 11, 3740. <>
  • Zhang Qi-Long, Zhu Bi-Xue, Zhang Yun-Qiuan, Tao Zhu, Clegg Jack K., Lindoy Leonard F., Wei Gang: Silver(I) Coordination Polymers Incorporating Neutral γ-Carbon Bound N,N′-Bis(acetylacetone)alkanediimine Units. Growth Des 2011, 11, 5688. <>
  • Kanoo Prakash, Ghosh Ashta Chandra, Maji Tapas Kumar: A Vanadium (VO2+) Metal–Organic Framework: Selective Vapor Adsorption, Magnetic Properties, and Use as a Precursor for a Polyoxovanadate. Inorg Chem 2011, 50, 5145. <>
  • Tanoue Ryota, Higuchi Rintaro, Enoki Nobuo, Miyasato Yuya, Uemura Shinobu, Kimizuka Nobuo, Stieg Adam Z., Gimzewski James K., Kunitake Masashi: Thermodynamically Controlled Self-Assembly of Covalent Nanoarchitectures in Aqueous Solution. ACS Na 2011, 5, 3923. <>
  • Haldar Ritesh, Cyriac Soumya T., Maji Tapas Kumar, Kanoo Prakash: Coordination driven axial chirality in a microporous solid assembled from an achiral linker via in situ C–N coupling. Chem Commn 2011, 47, 11038. <>
  • Ouellette Wayne, Darling Kari, Prosvirin Andrey, Whitenack Kelly, Dunbar Kim R., Zubieta Jon: Syntheses, structural characterization and properties of transition metal complexes of 5,5′-(1,4-phenylene)bis(1H-tetrazole) (H2bdt), 5′,5′′-(1,1′-biphenyl)-4,4′-diylbis(1H-tetrazole) (H2dbdt) and 5,5′,5′′-(1,3,5-phenylene)tris(1H-tetrazole) (H3btt). DALTON T 2011, 40, 12288. <>
  • Gerasimchuk Nikolay: An Excursion into the Intriguing World of Polymeric Tl(I) and Ag(I) Cyanoximates. Polymers 2011, 3, 1475. <>
  • Kanoo Prakash, Maji Tapas Kumar: Construction of a 2D Rectangular Grid and 3D Diamondoid Interpenetrated Frameworks and Their Functionalities by Changing the Second Spacers. Eur J Inorg Chem 2010, 2010, 3762. <>
  • Ghoshal Debajyoti, Maji Tapas Kumar: Fabrication of supramolecular frameworks by tuning the binding site of a tripodal ligand with d 10 metal ions: Interplay of covalent and non-covalent interactions in solid-state structure. J Chem Sci 2010, 122, 801. <>
  • Chamayou Anne-Christine, Janiak Christoph: A >22Å long metal-complex anion and a 1D cationic coordination polymer, both based on 4,4′-bipyridine-N,N′-dioxide, yielding a 3D and 2-fold interpenetrated fsc net of the hydrogen-bonded metal-organic 1D polymer. Inorg Chim Ada 2010, 363, 2193. <>
  • Jones Stephanie, Liu Hongxue, Schmidtke Katherine, O’Connor Charles C., Zubieta Jon: A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel chains. J Inorg Chem Commun 2010, 13, 298. <>
  • Cantos Paula M., Frisch Mark, Cahill Christopher L.: Synthesis, structure and fluorescence properties of a uranyl-2,5-pyridinedicarboxylic acid coordination polymer: The missing member of the UO22+-2,n-pyridinedicarboxylic series. J Inorg Chem Commun 2010, 13, 1036. <>
  • Kanoo Prakash, Gurunatha K. L., Maji Tapas Kumar: Versatile functionalities in MOFs assembled from the same building units: interplay of structural flexibility, rigidity and regularity. J Mater Chem 2010, 20, 1322. <>
  • Aakeröy Christer B., Champness Neil R., Janiak Christoph: Recent advances in crystal engineering. CrystEngCommun 2010, 12, 22. <>
  • Janiak Christoph, Vieth Jana K.: MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs). New J Chem 2010, 34, 2366. <>
  • Kondo Mitsuru, Takahashi Hideaki, Watanabe Hirotaka, Shimizu Yusuke, Yamanishi Katsunori, Miyazawa Makoto, Nishina Naoko, Ishida Yutaka, Kawaguchi Hiroyuki, Uchida Fumio: Syntheses and Characterization of New Nickel Coordination Polymers with 4,4’-Dipyridylsulfide. Dynamic Rearrangements of One-Dimensional Chains Responding to External Stimuli: Temperature Variation and Guest Releases/Re-Inclusions. IJMS 2010, 11, 2821. <>
  • Lan Anjian, Li Kunhao, Wu Haohan, Olson David H., Emge Thomas J., Ki Woosoek, Hong Maochun, Li Jing: A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives. Angew Chem 2009, 121, 2370. <>
  • Salles Fabrice, Jobic Hervé, Ghoufi Aziz, Llewellyn Philip L., Serre Christian, Bourrelly Sandrine, Férey Gérard, Maurin Guillaume: Transport Diffusivity of CO2 in the Highly Flexible Metal-Organic Framework MIL-53(Cr). Angew Chem 2009, 121, 8485. <>
  • Lan Anjian, Li Kunhao, Wu Haohan, Olson David H., Emge Thomas J., Ki Woosoek, Hong Maochun, Li Jing: A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives. Angew Chem Int E 2009, 48, 2334. <>
  • Salles Fabrice, Jobic Hervé, Ghoufi Aziz, Llewellyn Philip L., Serre Christian, Bourrelly Sandrine, Férey Gérard, Maurin Guillaume: Transport Diffusivity of CO2 in the Highly Flexible Metal-Organic Framework MIL-53(Cr). Angew Chem Int Ed 2009, 48, 8335. <>
  • Zucchi Gaël, Maury Olivier, Thuéry Pierre, Gumy Frédéric, Bünzli Jean-Claude G., Ephritikhine Michel: 2,2′-Bipyrimidine as Efficient Sensitizer of the Solid-State Luminescence of Lanthanide and Uranyl Ions from Visible to Near-Infrared. Chem Eur J 2009, 15, 9686. <>
  • Gurunatha Kargal L., Maji Tapas Kumar: Structural Flexibility and Selective Guest Accommodation in Two CuII Metal-Organic Coordination Frameworks. Eur J Inorg Chem 2009, 2009, 1592. <>
  • Xiao Weiming, Zhang Ning, Deng Shengjun, Mao Xuejin, Chen Chao: A Hydrogen-Bonded Framework Complex without Lattice Solvents: Synthesis Reversible Crystal-to-Amorphous Transformation and Chromic Properties. Z anorg allg Chem 2009, 635, 1511. <>
  • Gurunatha K.L., Maji Tapas Kumar: Three isomorphous threefold interpenetrated 2D supramolecular frameworks: Synthesis, structure and sorption properties. Inorg Chim Ada 2009, 362, 1541. <>
  • Gurunatha K.L., Dutta Sudipta, Mostafa Golam, Pati Swapan Kumar, Maji Tapas Kumar: A 3D chiral supramolecular framework of Cu(II): Synthesis, structure and magneto-structural correlations. Inorg Chim Ada 2009, 362, 3745. <>
  • Llewellyn P. L., Horcajada P., Maurin G., Devic T., Rosenbach N., Bourrelly S., Serre C., Vincent D., Loera-Serna S., Filinchuk Y.: Complex Adsorption of Short Linear Alkanes in the Flexible Metal-Organic-Framework MIL-53(Fe). J Am Chem Soc 2009, 131, 13002. <>
  • Low John J., Benin Annabelle I., Jakubczak Paulina, Abrahamian Jennifer F., Faheem Syed A., Willis Richard R.: Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration. J Am Chem Soc 2009, 131, 15834. <>
  • Katz Michael J., Leznoff Daniel B.: Highly Birefringent Cyanoaurate Coordination Polymers: The Effect of Polarizable C−X Bonds (X = Cl, Br). J Am Chem Soc 2009, 131, 18435. <>
  • Perry IV John J., Perman Jason A., Zaworotko Michael J.: Design and synthesis of metal–organic frameworks using metal–organic polyhedra as supermolecular building blocks. Chem Soc Rev 2009, 38, 1400. <>
  • Galli Simona, Masciocchi Norberto, Tagliabue Giulia, Sironi Angelo, Navarro Jorge A. R., Salas Juan M., Mendez-Liñan Laura, Domingo Maria, Perez-Mendoza Manuel, Barea Elisa: Polymorphic Coordination Networks Responsive to CO2, Moisture, and Thermal Stimuli: Porous Cobalt(II) and Zinc(II) Fluoropyrimidinolates. Chem Eur J 2008, 14, 9890. <>
  • Kelly Niamh R., Goetz Sandrine, Batten Stuart R., Kruger Paul E.: Synthesis and structural characterisation of lanthanide coordination polymers featuring 4,4′,6,6′-tetra-carboxy-2,2′-bipyridine and rare network topology. CrystEngCommun 2008, 10, 1018. <>