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Pure Appl. Chem., 2005, Vol. 77, No. 3, pp. 569-579

http://dx.doi.org/10.1351/pac200577030569

Lanthanide complexes of macrocyclic derivatives useful for medical applications

Rita Delgado1,2, Judite Costa3, Krassimira P. Guerra1 and Luís M. P. Lima1

1 Instituto de Tecnologia Química e Biológica, UNL, Apartado 127, 2781-901 Oeiras, Portugal
2 Instituto Superior Técnico, Dep. de Química, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
3 Fac. de Farmácia da Universidade de Lisboa, Av. das Forças Armadas, 1649-019 Lisboa, Portugal

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  • Ouchi Kazuki, Saito Shingo, Shibukawa Masami: New Molecular Motif for Recognizing Sialic Acid Using Emissive Lanthanide–Macrocyclic Polyazacarboxylate Complexes: Deprotonation of a Coordinated Water Molecule Controls Specific Binding. Inorg. Chem. 2013, 52, 6239. <http://dx.doi.org/10.1021/ic400725a>
  • Visa Aurelia, Mracec Maria, Maranescu Bianca, Maranescu Valentin, Ilia Gheorghe, Popa Adriana, Mracec Mircea: Structure simulation into a lamellar supramolecular network and calculation of the metal ions/ligands ratio. Chemistry Central Journal 2012, 6, 91. <http://dx.doi.org/10.1186/1752-153X-6-91>
  • Lima Luís M. P., Delgado Rita, Plutnar Jan, Hermann Petr, Kotek Jan: A New Tris(phosphonomethyl) Monoacetic Acid Cyclam Derivative: Synthesis, Acid-Base and Metal Complexation Studies. Eur J Inorg Chem 2011, 2011, 527. <http://dx.doi.org/10.1002/ejic.201000919>
  • Roca-Sabio Adrián, Mato-Iglesias Marta, Esteban-Gómez David, de Blas Andrés, Rodríguez-Blas Teresa, Platas-Iglesias Carlos: The effect of ring size variation on the structure and stability of lanthanide(iii) complexes with crown ethers containing picolinate pendants. Dalton Trans 2011, 40, 384. <http://dx.doi.org/10.1039/c0dt00746c>
  • Smentek Lidia: Lanthanides caged by the organic chelates; structural properties. J Phys Condens Matter 2011, 23, 143202. <http://dx.doi.org/10.1088/0953-8984/23/14/143202>
  • Huclier-Markai S., Sabatie A., Ribet S., Kubícek V., Paris M., Vidaud C., Hermann P., Cutler C. S.: Chemical and biological evaluation of scandium(III)-polyaminopolycarboxylate complexes as potential PET agents and radiopharmaceuticals. J Radiochimica Acta 2011, 99, 653. <http://dx.doi.org/10.1524/ract.2011.1869>
  • Campello M. Paula C., Lacerda Sara, Santos Isabel C., Pereira Giovannia A., Geraldes Carlos F. G. C., Kotek Jan, Hermann Petr, Vaněk Jakub, Lubal Přemysl, Kubíček  Vojtěch: Lanthanide(III) Complexes of 4,10-Bis(phosphonomethyl)-1,4,7,10-tetraazacyclododecane-1,7-diacetic acid (trans-H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series. Chem Eur J 2010, 16, 8446. <http://dx.doi.org/10.1002/chem.201000320>
  • Lima Luís M.P., Delgado Rita, Marques Fernanda, Gano Lurdes, Santos Isabel: TETA analogue containing one methylenephosphonate pendant arm: Lanthanide complexes and biological evaluation of its 153Sm and 166Ho complexes. Eur J Med Chem 2010, 45, 5621. <http://dx.doi.org/10.1016/j.ejmech.2010.09.013>
  • Kotková Zuzana, Pereira Giovannia A., Djanashvili Kristina, Kotek Jan, Rudovský Jakub, Hermann Petr, Vander Elst Luce, Muller Robert N., Geraldes Carlos F. G. C., Lukeš Ivan: Lanthanide(III) Complexes of Phosphorus Acid Analogues of H4DOTA as Model Compounds for the Evaluation of the Second-Sphere Hydration. Eur J Inorg Chem 2009, 2009, 119. <http://dx.doi.org/10.1002/ejic.200800859>
  • Svobodová Ivona, Havlíčková Jana, Plutnar Jan, Lubal Přemysl, Kotek Jan, Hermann Petr: Metal Complexes of 4,11-Dimethyl-1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) - Thermodynamic and Formation/Decomplexation Kinetic Studies. Eur J Inorg Chem 2009, 2009, 3577. <http://dx.doi.org/10.1002/ejic.200900358>
  • Yang Ting-Hai, Zhou Kai, Bao Song-Song, Zhu Cheng-Jian, Zheng Li-Min: Syntheses, structures and catalytic properties of one-dimensional lanthanide-dotp compounds [dotpH8=1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis-(methylenephosphonic acid)]. J Inorg Chem Commun 2008, 11, 1075. <http://dx.doi.org/10.1016/j.inoche.2008.05.036>
  • Samanamu Christian R., Zamora Elena Nicole, Montchamp Jean-Luc, Richards Anne F.: Synthesis of homo and hetero metal-phosphonate frameworks from bi-functional aminomethylphosphonic acid. J Solid State Chem 2008, 181, 1462. <http://dx.doi.org/10.1016/j.jssc.2008.03.023>
  • Havlíčková Jana, Medová Hana, Vitha Tomáš, Kotek Jan, Císařová Ivana, Hermann Petr: Coordination properties of cyclam (1,4,8,11-tetraazacyclotetradecane) endowed with two methylphosphonic acid pendant arms in the 1,4-positions. Dalton Trans 2008, 5378. <http://dx.doi.org/10.1039/b803235a>
  • Lima Luís M. P., Delgado Rita, Drew Michael G. B., Brandão Paula, Félix Vítor: Cyclam derivatives containing three acetate pendant arms: synthesis, acid–base, metal complexation and structural studies. Dalton Trans 2008, 6593. <http://dx.doi.org/10.1039/b809100e>
  • Glover Peter B., Bassett Andrew P., Nockemann Peter, Kariuki Benson M., Van Deun Rik, Pikramenou Zoe: Fully Fluorinated Imidodiphosphinate Shells for Visible- and NIR-Emitting Lanthanides: Hitherto Unexpected Effects of Sensitizer Fluorination on Lanthanide Emission Properties. Chem Eur J 2007, 13, 6308. <http://dx.doi.org/10.1002/chem.200700087>
  • Chen Gui, Xing Yan, Zhang Hui, Gao Jing-Xing: Synthesis of novel chiral macrocyclic ONNO-type ligands and use in asymmetric transfer hydrogenation. Journal of Molecular Catalysis A 2007, 273, 284. <http://dx.doi.org/10.1016/j.molcata.2007.04.017>
  • Delgado Rita, F?lix V?tor, Lima Lu?s M. P., Price David W.: Metal complexes of cyclen and cyclam derivatives useful for medical applications: a discussion based on thermodynamic stability constants and structural data. Dalton Trans 2007, 2734. <http://dx.doi.org/10.1039/b704360k>
  • Marques Fernanda, Gano Lurdes, Campello M. Paula, Lacerda Sara, Santos Isabel: Biological evaluation of 153Sm and 166Ho complexes with tetraazamacrocycles containing methylcarboxylate and/or methylphosphonate pendant arms. ract 2007, 95, 335. <http://dx.doi.org/10.1524/ract.2007.95.6.335>
  • Svobodov? Ivona, Lubal P?emysl, Plutnar Jan, Havl??kov? Jana, Kotek Jan, Hermann Petr, Luke? Ivan: Thermodynamic, kinetic and solid-state study of divalent metal complexes of 1,4,8,11-tetraazacyclotetradecane (cyclam) bearing two trans (1,8-)methylphosphonic acid pendant arms. Dalton Trans 2006, 5184. <http://dx.doi.org/10.1039/b603251f>
  • Táborský Petr, Lubal Přemysl, Havel Josef, Kotek Jan, Hermann Petr, Lukeš Ivan: Thermodynamic and Kinetic Studies of Lanthanide(III) Complexes with H5do3ap (1,4,7,10-Tetraazacyclododecane-1,4,7-triacetic-10-(methylphosphonic Acid)), a Monophosphonate Analogue of H4dota. Collect Czech Chem Commun 2005, 70, 1909. <http://dx.doi.org/10.1135/cccc20051909>