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Pure Appl. Chem., 2005, Vol. 77, No. 1, pp. 131-137

http://dx.doi.org/10.1351/pac200577010131

Noniterative approach to the total asymmetric synthesis of 15-carbon polyketides and analogs with high stereodiversity

Pierre Vogel*, Sandrine Gerber-Lemaire, Ana T. Carmona, Kai Torsten Meilert and Marc-Etienne Schwenter

Laboratory of Glycochemistry and Asymmetric Synthesis, Ecole Polytechnique Fédérale de Lausanne (EPFL), BCH, CH-1015 Lausanne-Dorigny, Switzerland

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  • Yadav Arun A., Sarang Prajakta S., Sau Manishankar, Thirumalairajan Srinath, Trivedi Girish K., Salunkhe Manikrao M.: Synthesis of optically active seven-membered 1,5-anhydrocarbasugars and 1,4,5-tribenzoyloxy-2-ethoxy cycloheptanes via [5+2] cycloaddition. Tetrahedron Letters 2012, 53, 3599. <http://dx.doi.org/10.1016/j.tetlet.2012.05.014>
  • Wang Yanping, Xing Yalan, Zhang Qi, O'Doherty George A.: De novo synthesis of natural products via the asymmetric hydration of polyenes. Chemical Communication 2011, 47, 8493. <http://dx.doi.org/10.1039/c1cc11791b>
  • Favre Sylvain, Gerber-Lemaire Sandrine, Vogel Pierre: Synthetic Studies toward the CD Spiroketal of Spongistatins. Eur J Org Chem 2010, 2010, 1895. <http://dx.doi.org/10.1002/ejoc.200901285>
  • Harmata Michael: The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles. Chem Commun 2010, 46, 8904. <http://dx.doi.org/10.1039/c0cc03621h>
  • Gerber-Lemaire Sandrine, Carmona Ana T., Meilert Kai T., Vogel Pierre: Asymmetric Synthesis of the Polyol Subunit of the Polyene Macrolide Antibiotic RK-397. Eur J Org Chem 2006, 2006, 891. <http://dx.doi.org/10.1002/ejoc.200500670>
  • Coste Gérald, Gerber-Lemaire Sandrine: A New Efficient Synthesis of Long-Chain Di- and Triaminopolyols. Eur J Org Chem 2006, 2006, 3903. <http://dx.doi.org/10.1002/ejoc.200600276>
  • Coste Gérald, Gerber-Lemaire Sandrine: Selective hydrolysis of anti-1,3-diol-acetonides for the differentiation of 1,3-anti and 1,3-syn diols. Tetrahetron Lett 2006, 47, 671. <http://dx.doi.org/10.1016/j.tetlet.2005.11.110>
  • Vogel Pierre, Gerber-Lemaire Gerber, Carmona Ana T., Meilert Kai Torsten, Schwenter Marc-Etienne: Noniterative Approach to the Total Asymmetric Synthesis of 15-Carbon Polyketides and Analogues with High Stereodiversity. ChemInform 2005, 36. <http://dx.doi.org/10.1002/chin.200535281>
  • Defosseux Magali, Blanchard Nicolas, Meyer Christophe, Cossy Janine: Synthesis of polypropionate subunits from cyclopropanes. Tetrahedron 2005, 61, 7632. <http://dx.doi.org/10.1016/j.tet.2005.05.099>
  • Coste Gérald, Gerber-Lemaire Sandrine: Enzymatic desymmetrization of 1,1′-methylenedi[(1R,1′S,3R,3′S,5S,5′R)-3-hydroxy-8-oxabicyclo[3.2.1]oct-6-ene-1-yl]: novel precursors of long chain polyketides. Tet Asymm 2005, 16, 2277. <http://dx.doi.org/10.1016/j.tetasy.2005.05.038>