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Pure Appl. Chem., 2004, Vol. 76, No. 3, pp. 615-623

Mechanistic insights into perfluoroaryl borane-catalyzed allylstannations: Toward asymmetric induction with chiral boranes

D. J. Morrison, J. M. Blackwell and W. E. Piers

Department of Chemistry, University of Calgary, 2500 University Drive N.W., Calgary, Alberta T2N 1N4, Canada

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  • Melen Rebecca L.: Applications of pentafluorophenyl boron reagents in the synthesis of heterocyclic and aromatic compounds. Chem. Commun. 2014, 50, 1161. <>
  • Zhao Xiaoxi, Liang Liyuan, Stephan Douglas W.: Facile synthesis of electrophilic vinyl boranes: reactions of alkynyl-borates and diazonium salts. Chem. Commun. 2012, 48, 10189. <>
  • Ashley Andrew E., Herrington Thomas J., Wildgoose Gregory G., Zaher Hasna, Thompson Amber L., Rees Nicholas H., Krämer Tobias, O’Hare Dermot: Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C6F5)3–n(C6Cl5)n (n = 1–3). J Ann Chem Soc 2011, 133, 14727. <>
  • Stephan Douglas W., Erker Gerhard: Frustrierte Lewis-Paare: metallfreie Wasserstoffaktivierung und mehr. angew chemie 2010, 122, 50. <>
  • Stephan Douglas W., Erker Gerhard: Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More. Angew Chem Int E 2010, 49, 46. <>
  • Xunjun Chen, Yingde Cui, Guoqiang Yin, Liewen Liao: Synthesis of vinyl substitute poly(silphenylene-siloxane) via silyl hydride-dialkoxysilane process. J Appl Polym Sci 2007, 106, 1007. <>
  • Welch Gregory C., Cabrera Lourdes, Chase Preston A., Hollink Emily, Masuda Jason D., Wei Pingrong, Stephan Douglas W.: Tuning Lewis acidity using the reactivity of “frustrated Lewis pairs”: facile formation of phosphine-boranes and cationic phosphonium-boranes. Dalton Trans 2007, 3407. <>
  • Erker Gerhard: Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions. Dalton Trans 2005, 1883. <>