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Pure Appl. Chem., 2003, Vol. 75, No. 10, pp. 1433-1442

http://dx.doi.org/10.1351/pac200375101433

Use of 3-halo-1-azaallylic anions in heterocyclic chemistry

Nicola Giubellina, Wim Aelterman and N. De Kimpe

Department of Organic Chemistry, Faculty of Agricultural and Applied Biological Sciences, Ghent University, Coupure links 653, B-9000 Ghent, Belgium

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  • Mangelinckx Sven, Kadam Santosh T., Semina Elena, Callebaut Gert, Colpaert Filip, De Smaele Dirk, De Kimpe Norbert: Synthesis of cis-2-alkoxycyclopropylamines via intramolecular cyclization of 2-azaallylic anions derived from alkoxybrominated N-(arylidene)-2-methyl-2-propenylamines. Tetrahedron 2013, 69, 3728. <http://dx.doi.org/10.1016/j.tet.2013.02.094>
  • Mangelinckx Sven, De Sterck Bart, Colpaert Filip, Catak Saron, Jacobs Jan, Rooryck Stijn, Waroquier Michel, Van Speybroeck Veronique, De Kimpe Norbert: Diastereoselective Aldol Reaction of Zincated 3-Chloro-3-methyl-1-azaallylic Anions as Key Step in the Synthesis of 1,2,3,4-Tetrasubstituted 3-Chloroazetidines. J Org Chern 2012, 77, 3415. <http://dx.doi.org/10.1021/jo300203t>
  • Sasada Toshiaki, Aoki Youichi, Ikeda Reiko, Sakai Norio, Konakahara Takeo: Synthesis of Tri- or Tetrasubstituted Pyrimidine Derivatives through the [5+1] Annulation of Enamidines with either N,N-Dimethylformamide Dialkyl Acetals or Orthoesters and Their Application in a Ring Transformation of Pyrimidines to Pyrido[2,3-d]pyrimidi. Chemistry A European Journal 2011, 17, 9385. <http://dx.doi.org/10.1002/chem.201100040>
  • Leemans Erika, Mangelinckx Sven, De Kimpe Norbert: Asymmetric synthesis of 2-arylpyrrolidines starting from γ-chloro N-(tert-butanesulfinyl)ketimines. Chem Commun 2010, 46, 3122. <http://dx.doi.org/10.1039/b925209f>
  • Colpaert Filip, Mangelinckx Sven, Leemans Erika, Denolf Bram, De Kimpe Norbert: Asymmetric synthesis of new chiral N-sulfinyl 2,2-disubstituted aziridines by Grignard additions across α-chloro N-sulfinyl ketimines. Org Biomol Chem 2010, 8, 3251. <http://dx.doi.org/10.1039/c001471k>
  • Abbaspour Tehrani Kourosch, Stas Sara, Lucas Bart, De Kimpe Norbert: Synthesis and reactivity of alkenyl- and alkynyl-substituted β,β-dihalo-and β,β,β-trichloroamines. Tetrahedron 2009, 65, 1957. <http://dx.doi.org/10.1016/j.tet.2009.01.034>
  • Siwicka Aleksandra, Wojtasiewicz Krystyna, Leniewski Andrzej, Maurin Jan K, Zawadzka Anna, Czarnocki Zbigniew: (R)-1-Phenylethylamine as chiral auxiliary in the diastereoselective synthesis of tetrahydro-β-carboline derivatives. Can J Chem 2007, 85, 1033. <http://dx.doi.org/10.1139/v07-118>
  • Denolf Bram, Mangelinckx Sven, Törnroos Karl W., De Kimpe Norbert: Use of α-Chlorinated N-(tert-Butanesulfinyl)imines in the Synthesis of Chiral Aziridines. Org Lett 2006, 8, 3129. <http://dx.doi.org/10.1021/ol0611245>
  • Giubellina Nicola, Aelterman Wim, De Kimpe Norbert: Use of 3-Halo-1-azaallylic Anions in Heterocyclic Chemistry. ChemInform 2004, 35. <http://dx.doi.org/10.1002/chin.200404248>