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Pure Appl. Chem., 2002, Vol. 74, No. 1, pp. 135-142

http://dx.doi.org/10.1351/pac200274010135

Curiosity and simplicity in the invention and discovery of new metal-mediated reactions for organic synthesis

William B. Motherwell

Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H OAJ, UK

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  • Best Daniel, Lam Hon Wai: C═N-Containing Azaarenes as Activating Groups in Enantioselective Catalysis. J. Org. Chem. 2014, 79, 831. <http://dx.doi.org/10.1021/jo402414k>
  • Yeh Chien-Hung, Korivi Rajendra Prasad, Cheng Chien-Hong: Ene-Carbonyl Reductive Coupling Mediated by Zinc and Ammonia for the Synthesis of γ-Hydroxybutyric Acid Derivatives. Adv. Synth. Catal. 2013, 355, 1338. <http://dx.doi.org/10.1002/adsc.201300073>
  • Ishikawa Shingo, Sheppard Tom D., D'Oyley Jarryl M., Kamimura Akio, Motherwell William B.: A Rapid Route to Aminocyclopropanes via Carbamatoorganozinc Carbenoids. Angew. Chem. 2013, 125, 10244. <http://dx.doi.org/10.1002/ange.201304720>
  • Ishikawa Shingo, Sheppard Tom D., D'Oyley Jarryl M., Kamimura Akio, Motherwell William B.: A Rapid Route to Aminocyclopropanes via Carbamatoorganozinc Carbenoids. Angew. Chem. Int. Ed. 2013, 52, 10060. <http://dx.doi.org/10.1002/anie.201304720>
  • Vicente Rubén, González Jesús, Riesgo Lorena, González Javier, López Luis A.: Catalytic Generation of Zinc Carbenes from Alkynes: Zinc-Catalyzed Cyclopropanation and SiH Bond Insertion Reactions. Angew. Chem. 2012, 124, 8187. <http://dx.doi.org/10.1002/ange.201203914>
  • Burns Alan R., Solana González Jorge, Lam Hon Wai: Enantioselective Copper(I)-Catalyzed Borylative Aldol Cyclizations of Enone Diones. Angew. Chem. 2012, 124, 10985. <http://dx.doi.org/10.1002/ange.201205899>
  • Vicente Rubén, González Jesús, Riesgo Lorena, González Javier, López Luis A.: Catalytic Generation of Zinc Carbenes from Alkynes: Zinc-Catalyzed Cyclopropanation and SiH Bond Insertion Reactions. Angew. Chem. Int. Ed. 2012, 51, 8063. <http://dx.doi.org/10.1002/anie.201203914>
  • Burns Alan R., Solana González Jorge, Lam Hon Wai: Enantioselective Copper(I)-Catalyzed Borylative Aldol Cyclizations of Enone Diones. Angew. Chem. Int. Ed. 2012, 51, 10827. <http://dx.doi.org/10.1002/anie.201205899>
  • Saxena Aakarsh, Choi Bonnie, Lam Hon Wai: Enantioselective Copper-Catalyzed Reductive Coupling of Alkenylazaarenes with Ketones. J. Am. Chem. Soc. 2012, 134, 8428. <http://dx.doi.org/10.1021/ja3036916>
  • Motherwell William B.: ChemInform Abstract: Curiosity and Simplicity in the Invention and Discovery of New Metal-mediated Reactions for Organic Synthesis. ChemInform 2010, 33, no. <http://dx.doi.org/10.1002/chin.200243286>
  • Lumby Ralph J.R., Joensuu Pekka M., Lam Hon Wai: Racemic and asymmetric cobalt-catalysed reductive aldol couplings of α,β-unsaturated amides with ketones. Tetrahedron 2008, 64, 7729. <http://dx.doi.org/10.1016/j.tet.2008.06.022>
  • Villanueva Margalef Isabel, Rupnicki Leszek, Lam Hon Wai: Formal synthesis of salinosporamide A using a nickel-catalyzed reductive aldol cyclization–lactonization as a key step. Tetrahedron 2008, 64, 7896. <http://dx.doi.org/10.1016/j.tet.2008.06.038>
  • Hashimoto Toru, Ito Jun-ichi, Nishiyama Hisao: Felkin–Anh selectivity in Rh(bisoxazolinylphenyl)-catalyzed reductive aldol coupling reaction: asymmetric synthesis of stereotriads. Tetrahedron 2008, 64, 9408. <http://dx.doi.org/10.1016/j.tet.2008.07.092>
  • Motherwell William B., Bégis Guillaume, Cladingboel David E., Jerome Laure, Sheppard Tom D.: Observations on the direct amidocyclopropanation of alkenes using organozinc carbenoids. Tetrahedron 2007, 63, 6462. <http://dx.doi.org/10.1016/j.tet.2007.03.027>
  • Jung Cheol-Kyu, Garner Susan A., Krische Michael J.: Hydrogen-Mediated Aldol Reductive Coupling of Vinyl Ketones Catalyzed by Rhodium:  High Syn-Selectivity through the Effect of Tri-2-furylphosphine. Org Lett 2006, 8, 519. <http://dx.doi.org/10.1021/ol052859x>
  • Fogg Deryn E., dos Santos Eduardo N.: Tandem catalysis: a taxonomy and illustrative review. Coord Chem Rev - 2004, 248, 2365. <http://dx.doi.org/10.1016/j.ccr.2004.05.012>