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Pure Appl. Chem., 2002, Vol. 74, No. 1, pp. 43-55

Organoboron compounds as mild nucleophiles in Lewis acid- and transition metal-catalyzed C­C bond-forming reactions

Robert A. Batey, Tan D. Quach, Ming Shen, Avinash N. Thadani, David V. Smil, Sze-Wan Li and D. Bruce MacKay

Department of Chemistry, 80 St. George Street, University of Toronto, Toronto, Ontario, M5S 3H6, Canada

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  • Cazorla Clément, Métay Estelle, Lemaire Marc: Oxidative nucleophilic substitution: transformation of alkylboronic derivatives. Tedrahedron 2011, 67, 8615. <>
  • Jang Hwanjong, Zhugralin Adil R., Lee Yunmi, Hoveyda Amir H.: Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity. J Am Chem Soc 2011, 133, 7859. <>
  • Shimizu Masaki, Higashi Masahiro, Takeda Youhei, Murai Masahito, Jiang Guofang, Asai Yuiga, Nakao Yoshiaki, Shirakawa Eiji, Hiyama Tamejiro: New preparation and synthetic reactions of 3,3,3-trifluoropropynyllithium, -borate and -stannane: facile synthesis of trifluoromethylated allenes, arylacetylenes and enynes. Future Medicinal Chemistry 2009, 1, 921. <>
  • Quach Tan D., Batey Robert A.: Copper(II)-Catalyzed Ether Synthesis from Aliphatic Alcohols and Potassium Organotrifluoroborate Salts. Org Lett 2003, 5, 1381. <>