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Pure Appl. Chem., 2001, Vol. 73, No. 7, pp. 1059-1073

http://dx.doi.org/10.1351/pac200173071059

Unsaturated binuclear homoleptic metal carbonyls M2(CO)x (M = Fe, Co, Ni; x = 5, 6, 7, 8). Are multiple bonds between transition metals possible for these molecules?

Henry F. Schaefer, III and R. Bruce King

Department of Chemistry and Center for Computational Quantum Chemistry, University of Georgia, Athens, Georgia 30602

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  • Adams Richard D., Kan Yuwei, Zhang Qiang, Hall Michael B., Trufan Eszter: Bonding and Reactivity in the Electronically Unsaturated Hydrogen-Bridged Dimer [Ru3(CO)8(μ3-CMe)(μ-H)2(μ3-H)]2. Organomettalics 2012, 31, 50. <http://dx.doi.org/10.1021/om2012375>
  • Zhang Xiuhui, Li Qian-shu, Xie Yaoming, King R. Bruce, Schaefer Henry F.: A Carbonyl Group Bridging Four Metal Atoms in a Homoleptic Carbonylmetal Cluster: The Remarkable Case of ­Co4(CO)11. Eur J Inorg Chem 2008, 2008, 2158. <http://dx.doi.org/10.1002/ejic.200800107>
  • Ponec Robert, Lendvay György, Chaves Joaquin: Structure and bonding in binuclear metal carbonyls from the analysis of domain averaged Fermi holes. I. Fe2(CO)9 and Co2(CO)8. J Comput Chem 2008, 29, 1387. <http://dx.doi.org/10.1002/jcc.20894>
  • King R. Bruce, Schaefer H.F., Liu Zhaohui, Li Qian-Shu, Xie Yaoming: The oxophilicity of vanadium in unsaturated homoleptic binuclear vanadium carbonyl structures. J Organomet Chem 2008, 693, 1502. <http://dx.doi.org/10.1016/j.jorganchem.2007.10.058>
  • Omae Iwao: Three characteristic reactions of organocobalt compounds in organic synthesis. Appl Organometal Chem 2007, 21, 318. <http://dx.doi.org/10.1002/aoc.1213>
  • Gatti Carlo, Lasi Davide: Source function description of metal?metal bonding in d-block organometallic compounds. Faraday Disc 2007, 135, 55. <http://dx.doi.org/10.1039/b605404h>
  • van der Vlugt Jarl Ivar, Rauchfuss Thomas B., Wilson Scott R.: Electron-Rich Diferrous-Phosphane-Thiolates Relevant to Fe-only Hydrogenase: Is Cyanide “Nature's Trimethylphosphane”?. Chem Eur J 2006, 12, 90. <http://dx.doi.org/10.1002/chem.200500752>
  • Liu Zhaohui, Xie Yaoming, Schaefer Henry F., King R. Bruce, Li Qian-Shu: Octacarbonyldivanadium: a highly unsaturated binuclear metal carbonyl. Mole Phys 2006, 104, 763. <http://dx.doi.org/10.1080/00268970500417275>
  • King R. Bruce, Xie Yaoming, Schaefer H.F., Richardson Nancy, Li Se: Homoleptic binuclear chromium carbonyls: why haven’t they been synthesized as stable molecules?. Inorg Chim Ada 2005, 358, 1442. <http://dx.doi.org/10.1016/j.ica.2004.07.060>
  • Xie Yaoming, King R. Bruce, Schaefer Henry F.: Vibrational frequencies of the homoleptic cobalt carbonyls: Co4(CO)12 and Co6(CO)16. Spectrochim Acta A Mol Biomol Spectrosc 2005, 61, 1693. <http://dx.doi.org/10.1016/j.saa.2004.12.039>