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Pure Appl. Chem., 2001, Vol. 73, No. 2, pp. 373-376

http://dx.doi.org/10.1351/pac200173020373

New P-chirogenic diphosphines and their use in catalytic asymmetric reactions

Tsuneo Imamoto

Department of Chemistry, Faculty of Science, Chiba University, Inage-ku, Chiba 263-8522, Japan

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  • Krasiński Grzegorz, Cypryk Marek, Kwiatkowska Małgorzata, Mikołajczyk Marian, Kiełbasiński Piotr: Molecular modeling of the lipase-catalyzed hydrolysis of acetoxymethyl(i-propoxy)phenylphosphine oxide and its P-borane analogue. Journal of Molecular Graphics and Modelling 2012, 38, 290. <http://dx.doi.org/10.1016/j.jmgm.2012.09.001>
  • Zacharias Niki M., Chan Henry R., Sailasuta Napapon, Ross Brian D., Bhattacharya Pratip: Real-Time Molecular Imaging of Tricarboxylic Acid Cycle Metabolism in Vivo by Hyperpolarized 1-13C Diethyl Succinate. J. Am. Chem. Soc. 2012, 134, 934. <http://dx.doi.org/10.1021/ja2040865>
  • Kwiatkowska Małgorzata, Krasiński Grzegorz, Cypryk Marek, Cierpiał Tomasz, Kiełbasiński Piotr: Lipase-mediated stereoselective transformations of chiral organophosphorus P-boranes revisited: revision of the absolute configuration of alkoxy(hydroxymethyl)phenylphosphine P-boranes. Tet Asymm 2011, 22, 1581. <http://dx.doi.org/10.1016/j.tetasy.2011.08.024>
  • Imamoto Tsuneo: ChemInform Abstract: New P-Chirogenic Diphosphines and Their Use in Catalytic Asymmetric Reactions. ChemInform 2010, 32, no. <http://dx.doi.org/10.1002/chin.200142292>
  • Giri Santanab, Wang David Zhigang, Chattaraj Pratim Kumar: Catalyst electronic polarizability and enantiomeric excess in asymmetric hydrogenation. Tetrahedron 2010, 66, 4560. <http://dx.doi.org/10.1016/j.tet.2010.04.055>
  • Bhattacharya Pratip, Chekmenev Eduard Y., Perman William H., Harris Kent C., Lin Alexander P., Norton Valerie A., Tan Chou T., Ross Brian D., Weitekamp Daniel P.: Towards hyperpolarized 13C-succinate imaging of brain cancer. J  Magn Reson 2007, 186, 150. <http://dx.doi.org/10.1016/j.jmr.2007.01.017>
  • Kiełbasiński Piotr, Albrycht Małgorzata, Żurawiński Remigiusz, Mikołajczyk Marian: Lipase-mediated kinetic resolution of racemic and desymmetrization of prochiral organophosphorus P-boranes. Mol Catal B Enzym 2006, 39, 45. <http://dx.doi.org/10.1016/j.molcatb.2006.01.025>
  • Wang David Zhigang: Conservation of helicity and helical character matching in chiral interactions. Chirality 2005, 17, S177. <http://dx.doi.org/10.1002/chir.20140>
  • Katagiri Kosuke, Danjo Hiroshi, Yamaguchi Kentaro, Imamoto Tsuneo: Nucleophilic aromatic substitution reactions of fluorobenzenechromium complexes with P-chiral secondary phosphine–boranes: synthesis of optically pure P-chiral (dialkyl)arylphosphine–boranes. Tetrahedron 2005, 61, 4701. <http://dx.doi.org/10.1016/j.tet.2005.01.129>
  • Wang David Zhigang: Catalyst–substrate helical character matching determines enantiomeric excess. Tetrahedron 2005, 61, 7134. <http://dx.doi.org/10.1016/j.tet.2005.05.059>
  • Imamoto Tsuneo, Crépy Karen V.L, Katagiri Kosuke: Optically active 1,1′-di-tert-butyl-2,2′-dibenzophosphetenyl: a highly strained P-stereogenic diphosphine ligand. Tet Asymm 2004, 15, 2213. <http://dx.doi.org/10.1016/j.tetasy.2004.05.041>
  • Gridnev I. D., Yasutake M., Imamoto T., Beletskaya I. P.: Asymmetric Catalysis Special Feature Part I: Asymmetric hydrogenation of  , -unsaturated phosphonates with Rh-BisP* and Rh-MiniPHOS catalysts: Scope and mechanism of the reaction. Proceedings of the National Academy of Sciences 2004, 101, 5385. <http://dx.doi.org/10.1073/pnas.0306993101>
  • Oohara Nobuhiko, Katagiri Kosuke, Imamoto Tsuneo: A novel P-chirogenic phosphine ligand, (S,S)-1,2-bis-[(ferrocenyl)methylphosphino]ethane: synthesis and use in rhodium-catalyzed asymmetric hydrogenation and palladium-catalyzed asymmetric allylic alkylation. Tet Asymm 2003, 14, 2171. <http://dx.doi.org/10.1016/S0957-4166(03)00439-7>
  • Novel Synthesis of P-Chiral Hydroxymethylphosphine–Boranes through Lipase-Catalyzed Optical Resolution. Bull Chem Soc Jpn 2003, 76, 833. <http://dx.doi.org/10.1246/bcsj.76.833>
  • Xu Guopin, Gilbertson Scott R: Facile synthesis of proline based phosphineoxazoline ligands by formation of a PN bond. Tetrahetron Lett 2002, 43, 2811. <http://dx.doi.org/10.1016/S0040-4039(02)00346-5>
  • Maienza Francesca, Santoro Francesco, Spindler Felix, Malan Christophe, Mezzetti Antonio: P-Stereogenic diphosphines in the ruthenium-catalysed asymmetric hydrogenation of CC and CO double bonds. Tet Asymm 2002, 13, 1817. <http://dx.doi.org/10.1016/S0957-4166(02)00439-1>