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Pure Appl. Chem., 2001, Vol. 73, No. 2, pp. 279-282

http://dx.doi.org/10.1351/pac200173020279

Lewis-acidic organometallic compounds of the lanthanides and the alkaline earth metals as catalysts for the activation of carbonyl groups

Herbert Schumann*, Mario Glanz, Jochen Gottfriedsen, Sebastian Dechert and Dietmar Wolff

Technische Universität Berlin, Institut für Anorganische und Analytische Chemie, Sekr. C2, Straße des 17. Juni 135, D-10623 Berlin, Germany

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  • Wunderlich Stefan H., Knochel Paul: Atom-Economical Preparation of Aryl- and Heteroaryl-Lanthanum Reagents by Directed ortho-Metalation by Using tmp3[La]. Chem Eur J 2010, 16, 3304. <http://dx.doi.org/10.1002/chem.200903157>
  • Schumann Herbert, Glanz Mario, Gottfriedsen Jochen, Dechert Sebastian, Wolff Dietmar: ChemInform Abstract: Lewis-Acidic Organometallic Compounds of the Lanthanoids and the Alkaline Earth Metals as Catalysts for the Activation of Carbonyl Groups. ChemInform 2010, 32, no. <http://dx.doi.org/10.1002/chin.200143262>
  • Schumann Herbert, Freckmann Dominique M. M., Schutte Stefan, Dechert Sebastian, Hummert Markus: Organometallic Compounds of the Lanthanides. 181 Alkyllanthanide Carbene Complexes. Z anorg allg Chem 2007, 633, 888. <http://dx.doi.org/10.1002/zaac.200700028>
  • Díez-González Silvia, Nolan Steven P.: Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding. Coord Chem Rev - 2007, 251, 874. <http://dx.doi.org/10.1016/j.ccr.2006.10.004>
  • Krasovskiy Arkady, Kopp Felix, Knochel Paul: Lösliche Lanthanoid-Salze (LnCl3⋅2 LiCl) für die verbesserte Addition magnesiumorganischer Reagentien an Carbonylverbindungen. Angew Chem 2006, 118, 511. <http://dx.doi.org/10.1002/ange.200502485>
  • Krasovskiy Arkady, Kopp Felix, Knochel Paul: Soluble Lanthanide Salts (LnCl3⋅2 LiCl) for the Improved Addition of Organomagnesium Reagents to Carbonyl Compounds. Angew Chem Int Ed 2006, 45, 497. <http://dx.doi.org/10.1002/anie.200502485>
  • Steffens Alexandra, Schumann Herbert: Polymerization of Polar Monomers Using Cyclopentadienyl Complexes of the Alkaline Earth Metals. Macromol Symp 2006, 236, 203. <http://dx.doi.org/10.1002/masy.200690056>
  • Gottfriedsen Jochen, Edelmann Frank T.: Lanthanides and actinides: Annual survey of their organometallic chemistry covering the years 2001 and 2002. Coord Chem Rev - 2006, 250, 2347. <http://dx.doi.org/10.1016/j.ccr.2006.02.030>
  • Gamer Michael T., Rastätter Marcus, Roesky Peter W., Steffens Alexandra, Glanz Mario: Yttrium and Lanthanide Complexes with Various P,N Ligands in the Coordination Sphere: Synthesis, Structure, and Polymerization Studies. Chem Eur J 2005, 11, 3165. <http://dx.doi.org/10.1002/chem.200401062>
  • Schumann Herbert, Schutte Stefan, Kroth Heinz-Jürgen, Lentz Dieter: Butenylsubstituierte Erdalkalimetallocene: ein erster Schritt zu Olefinkomplexen der Erdalkalimetalle. Angew Chem 2004, 116, 6335. <http://dx.doi.org/10.1002/ange.200460927>
  • Schumann Herbert, Schutte Stefan, Kroth Heinz-Jürgen, Lentz Dieter: Butenyl-Substituted Alkaline-Earth Metallocenes: A First Step towards Olefin Complexes of the Alkaline-Earth Metals. Angew Chem Int Ed 2004, 43, 6208. <http://dx.doi.org/10.1002/anie.200460927>