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Pure Appl. Chem., 2000, Vol. 72, No. 11, pp. 2187-2197

Mechanism of Fe(OH)2+(aq) photolysis in aqueous solution(Technical Report)

Ivan P. Pozdnyakov1, Evgeny M. Glebov2, Victor F. Plyusnin2, Vyacheslav P. Grivin2, Yuri V. Ivanov2, Dmitry Yu. Vorobyev1 and Nikolai M. Bazhin2*

1 Novosibirsk State University, Novosibirsk, 630090, Russia
2 Institute of Chemical Kinetics and Combustion, Novosibirsk, 630090, Russia

Abstract: Experiments on laser flash photolysis (308 nm) of Fe(OH)2+(aq) complex in aqueous solution with addition of nitrobenzene demonstrate the formation of hydroxyl radical in the primary photochemical process.