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Pure Appl. Chem., 1999, Vol. 71, No. 9, pp. 1771-1807

http://dx.doi.org/10.1351/pac199971091771

ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON ELECTROANALYTICAL CHEMISTRY

A Critical Evaluation of the Redox Properties of Uranium, Neptunium and Plutonium Ions in Acidic Aqueous Solutions

Sorin Kihara, Zenko Yoshida, Hisao Aoyagi, Kohji Maeda, Osamu Shirai, Yoshihiro Kitatsuji and Yumi Yoshida

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  • Meredith Nathan A., Polinski Matthew J., Cross Justin N., Villa Eric M., Simonetti Antonio, Albrecht-Schmitt Thomas E.: Synthetic Influences on Neptunium Incorporation in Naturally Occurring Copper Uranyl Phosphates. Crystal Growth & Design 2013, 13, 386. <http://dx.doi.org/10.1021/cg3015755>
  • Deblonde Gauthier J-P., Sturzbecher-Hoehne Manuel, Abergel Rebecca J.: Solution Thermodynamic Stability of Complexes Formed with the Octadentate Hydroxypyridinonate Ligand 3,4,3-LI(1,2-HOPO): A Critical Feature for Efficient Chelation of Lanthanide(IV) and Actinide(IV) Ions. Inorg. Chem. 2013, 52, 8805. <http://dx.doi.org/10.1021/ic4010246>
  • Steele Helen M., Guillaumont Dominique, Moisy Philippe: Density Functional Theory Calculations of the Redox Potentials of Actinide(VI)/Actinide(V) Couple in Water. J. Phys. Chem. A 2013, 117, 4500. <http://dx.doi.org/10.1021/jp401875f>
  • Nakashima Nobuaki, Yamanaka Ken-ichi, Yatsuhashi Tomoyuki: Reduction of Yb(III) to Yb(II) by Two-Color Two-Photon Excitation. J. Phys. Chem. A 2013, 117, 8352. <http://dx.doi.org/10.1021/jp402194g>
  • Ogden Mark D., Sinkov Serguei I., Lumetta Gregg J., Nash Kenneth L.: Affinity of An(VI) for N4-Tetradentate Donor Ligands: Complexation of the Actinyl(VI) Ions with N4-Tetradentate Ligands. J Solution Chem 2012, 41, 616. <http://dx.doi.org/10.1007/s10953-012-9827-2>
  • Kitatsuji Yoshihiro, Kimura Takaumi, Kihara Sorin: Flow electrolysis of U, Np and Pu ions utilizing electrocatalysis at a column electrode with platinized glassy carbon fiber working electrode. Electrochimica Acta 2012, 74, 215. <http://dx.doi.org/10.1016/j.electacta.2012.04.055>
  • Kasuno Megumi, Fujimoto Kazuma, Kakitani Yuri, Matsushita Takayuki, Kihara Sorin: Precise coulometric determination of redox inert anions based on electrolysis at the aqueous|organic solution interface. Journal of Electroanalytical Chemistry 2011, 651, 111. <http://dx.doi.org/10.1016/j.jelechem.2010.11.034>
  • Horowitz S. E., Marston J. B.: Strong correlations in actinide redox reactions. J Chem Phys 2011, 134, 064510. <http://dx.doi.org/10.1063/1.3549571>
  • Okugaki Tomohiko, Kasuno Megumi, Maeda Kohji, Kihara Sorin: Redox reactions of vitamin E in 1,2-dichloroethane with oxidants in water at the water/1,2-dichloroethane interface. Journal of Electroanalytical Chemistry 2010, 639, 67. <http://dx.doi.org/10.1016/j.jelechem.2009.11.023>
  • Kitatsuji Yoshihiro, Kimura Takaumi, Kihara Sorin: Reduction behavior of neptunium(V) at a gold or platinum electrode during controlled potential electrolysis and procedures for electrochemical preparations of neptunium(IV) and (III). Journal of Electroanalytical Chemistry 2010, 641, 83. <http://dx.doi.org/10.1016/j.jelechem.2009.12.015>
  • Uehara A, Fujii T, Nagai T, Shirai O, Sato N, Yamana H: Electrochemical characteristics of uranium ions in calcium chloride hydrate melts. IOP Conf Ser Mater Sci Eng 2010, 9, 012080. <http://dx.doi.org/10.1088/1757-899X/9/1/012080>
  • Okugaki Tomohiko, Kitatsuji Yoshihiro, Kasuno Megumi, Yoshizumi Asuka, Kubota Hiroki, Shibafuji Yayoi, Maeda Kohji, Yoshida Zenko, Kihara Sorin: Development of high performance electrochemical solvent extraction method. Journal of Electroanalytical Chemistry 2009, 629, 50. <http://dx.doi.org/10.1016/j.jelechem.2009.01.022>
  • Yusov A. B., Shilov V. P., Peretrukhin V. F., Fedoseev A. M.: Uranium(III) in aqueous solutions: Preparation, properties, synthesis of solid compounds. Radiochemistry 2007, 49, 1. <http://dx.doi.org/10.1134/S1066362207010018>
  • Khan A. S. A., Ahmed Riaz, Mirza M. L.: Kinetics and electrochemical studies of uranium in acetate and formate media by cyclic voltammetry. ract 2007, 95, 693. <http://dx.doi.org/10.1524/ract.2007.95.12.693>
  • Aoyagi Hisao, Kitatsuji Yoshihiro, Yoshida Zenko, Kihara Sorin: Rapid and quantitative electrolytic preparation and speciation of neptunium ions of various oxidation states using multi-step column electrodes. Analytica Chimica Acta 2005, 538, 283. <http://dx.doi.org/10.1016/j.aca.2005.02.035>
  • Yoshizumi Asuka, Uehara Akihiro, Kasuno Megumi, Kitatsuji Yoshihiro, Yoshida Zenko, Kihara Sorin: Rapid and coulometric electrolysis for ion transfer at the aqueous|organic solution interface. Journal of Electroanalytical Chemistry 2005, 581, 275. <http://dx.doi.org/10.1016/j.jelechem.2005.02.024>
  • YOSHIDA Zenko, KIHARA Sorin, FUJINAGA Taitiro: Principle of electrolytic chromatography and coulopotentiography and its application to flow-injection analysis. BUNSEKI KAGAKU 2004, 53, 195. <http://dx.doi.org/10.2116/bunsekikagaku.53.195>
  • Yoshida Yumi, Yoshida Zenko, Aoyagi Hisao, Kitatsuji Yoshihiro, Uehara Akihiro, Kihara Sorin: Evaluation of Gibbs free energy for the transfer of a highly hydrophilic ion from an acidic aqueous solution to an organic solution based on ion pair extraction. Analytica Chimica Acta 2002, 452, 149. <http://dx.doi.org/10.1016/S0003-2670(01)01436-2>