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Pure Appl. Chem., 1999, Vol. 71, No. 8, pp. 1511-1519

http://dx.doi.org/10.1351/pac199971081511

Bicyclization of dienes, enynes, and diynes with Ti(ii) reagent. New developments towards asymmetric synthesis

F. Sato, H. Urabe and S. Okamoto

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  • Shaibakova Mariya G., Khafizova Leila O., Chobanov Nuri M., Gubaidullin Rinat R., Popod’ko Natal’ya R., Dzhemilev Usein M.: The efficient one-pot synthesis of tetraalkyl substituted furans from symmetrical acetylenes, EtAlCl2, and carboxylic esters catalyzed by Cp2TiCl2. Tetrahedron Letters 2014, 55, 1326. <http://dx.doi.org/10.1016/j.tetlet.2014.01.015>
  • Li Ling, Kristian Kathleen E., Han Arthur, Norton Jack R., Sattler Wesley: Synthesis, Structural Characterization, and Reactivity of Cp2- and (CpMe)2-Ligated Titanaaziridines and Titanaoxiranes with Fast Enantiomer Interconversion Rates. Organometallics 2012, 31, 8218. <http://dx.doi.org/10.1021/om300825n>
  • Schäfer Christian, Miesch Michel, Miesch Laurence: Intramolecular reductive ketone–alkynoate coupling reaction promoted by (η2-propene)titanium. Biomol Chem 2012, 10, 3253. <http://dx.doi.org/10.1039/c2ob07049a>
  • Matano Yoshihiro, Imahori Hiroshi: Synthesis of Chain Type and Fused ^|^pi;-Conjugated Phosphole Derivatives. J. Synth. Org. Chem. Jpn. 2012, 70, 629. <http://dx.doi.org/10.5059/yukigoseikyokaishi.70.629>
  • Tsurugi Hayato, Nagae Haruki, Mashima Kazushi: First isolation of fully delocalized mixed-valent imido-bridged [Ti2]7+ complexes by one-electron reduction of [(C5R5)TiCl]2(μ-NAr)2. Chem Commun 2011, 47, 5620. <http://dx.doi.org/10.1039/c1cc10757g>
  • Kawaji Tsuyoshi, Shohji Noriaki, Miyashita Kenji, Okamoto Sentaro: Non-Cp titanium alkoxide-based homolytic ring-opening of epoxides by an intramolecular hydrogen abstraction in β-titanoxy radical intermediates. Chem Commun 2011, 47, 7857. <http://dx.doi.org/10.1039/c1cc12969d>
  • Sato Fumie, Urabe Hirokazu, Okamoto Sentaro: ChemInform Abstract: Bicyclization of Dienes, Enynes, and Diynes with Ti(II) Reagent. New Developments Towards Asymmetric Synthesis. ChemInform 2010, 31, no. <http://dx.doi.org/10.1002/chin.200031286>
  • Wolan Andrzej, Six Yvan: Synthetic transformations mediated by the combination of titanium(IV) alkoxides and grignard reagents: selectivity issues and recent applications. Part 1: reactions of carbonyl derivatives and nitriles. Tetrahedron 2010, 66, 15. <http://dx.doi.org/10.1016/j.tet.2009.10.050>
  • Wolan Andrzej, Six Yvan: Synthetic transformations mediated by the combination of titanium(IV) alkoxides and Grignard reagents: selectivity issues and recent applications. Part 2: Reactions of alkenes, allenes and alkynes. Tetrahedron 2010, 66, 3097. <http://dx.doi.org/10.1016/j.tet.2010.01.079>
  • Morelli Carlo F., Fornili Arianna, Sironi Maurizio, Durì Lavinia, Speranza Giovanna, Manitto Paolo: Evidence for a nucleophilic anti-attack on the cleaved C(2)–oxygen bond in Cl2AlH-catalyzed ring-opening of 2-substituted 1,3-dioxolanes. Tetrahetron Lett 2005, 46, 1837. <http://dx.doi.org/10.1016/j.tetlet.2005.01.108>
  • Nakajima Ryota, Urabe Hirokazu, Sato Fumie: Intramolecular Coupling of Vinyl Ether and Olefins or Acetylenes with Ti(II) Reagent. Regio- and Stereo-selective Vinyltitanation of Carbon-Carbon Multiple Bonds. Chem Lett 2002, 4. <http://dx.doi.org/10.1246/cl.2002.4>
  • Kim Kwangho, Okamoto Sentaro, Sato Fumie: Regiocontrol of Radical Cyclization by Lewis Acids. Efficient Synthesis of Optically Active Functionalized Cyclopentanes and Cyclohexanes. Org Lett 2001, 3, 67. <http://dx.doi.org/10.1021/ol0067890>
  • Song Yongcheng, Okamoto Sentaro, Sato Fumie: Highly Stereoselective Asymmetric Construction of an Acyclic Carbon Skeleton Having Two Adjacent Alkyl Substituents by Michael Addition of Optically Active Allenyltitaniums to Alkylidenemalonates. Org Lett 2001, 3, 3543. <http://dx.doi.org/10.1021/ol016652p>
  • Suzuki Daisuke, Urabe Hirokazu, Sato Fumie: Asymmetric Synthesis of Baylis–Hillman-Type Allyl Alcohols via a Chiral Acetylenic Ester Titanium Alkoxide Complex. Angew Chem 2000, 112, 3428. <http://dx.doi.org/10.1002/1521-3757(20000915)112:18<3428::AID-ANGE3428>3.0.CO;2-E>
  • Suzuki Daisuke, Urabe Hirokazu, Sato Fumie: Asymmetric Synthesis of Baylis–Hillman-Type Allyl Alcohols via a Chiral Acetylenic Ester Titanium Alkoxide Complex. Angew Chem 2000, 39, 3290. <http://dx.doi.org/10.1002/1521-3773(20000915)39:18<3290::AID-ANIE3290>3.0.CO;2-T>
  • Hanazawa Takeshi, Okamoto Sentaro, Sato Fumie: Preparation of Titanated Alkoxyallenes from 3-Alkoxy-2-propyn-1-yl Carbonates and (η2-Propene)Ti(O-i-Pr)2 as an Efficient Ester Homoaldol Equivalent. Org Lett 2000, 2, 2369. <http://dx.doi.org/10.1021/ol006142f>
  • Urabe Hirokazu, Nakajima Ryota, Sato Fumie: A Facile Preparation of exo-Cyclic Conjugated Dienes Fused to Lactams or Lactones via Intramolecular Coupling of Acetylenes and Their Behavior in Diels−Alder Reactions. Org Lett 2000, 2, 3481. <http://dx.doi.org/10.1021/ol0065221>