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Pure Appl. Chem., 1999, Vol. 71, No. 2, pp. 303-320

http://dx.doi.org/10.1351/pac199971020303

ORGANIC CHEMISTRY DIVISION
COMMISSION ON PHOTOCHEMISTRY

Terminology, relative photonic efficiencies and quantum yields in heterogeneous photocatalysis. Part I: Suggested protocol

Nick Serpone and Angela Salinaro

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  • Nomikos Georgios N., Panagiotopoulou Paraskevi, Kondarides Dimitris I., Verykios Xenophon E.: Kinetic and mechanistic study of the photocatalytic reforming of methanol over Pt/TiO2 catalyst. Applied Catalysis B: Environmental 2014, 146, 249. <http://dx.doi.org/10.1016/j.apcatb.2013.03.018>
  • Menéndez-Flores Víctor M., Ohno Teruhisa: High visible-light active Ir-doped-TiO2 brookite photocatalyst synthesized by hydrothermal microwave-assisted process. Catalysis Today 2014, 230, 214. <http://dx.doi.org/10.1016/j.cattod.2014.01.032>
  • Othman Siti Hajar, Abd Salam Nurul Raudhah, Zainal Norhazlizam, Kadir Basha Roseliza, Talib Rosnita A.: Antimicrobial Activity of TiO2 Nanoparticle-Coated Film for Potential Food Packaging Applications. International Journal of Photoenergy 2014, 2014, 1. <http://dx.doi.org/10.1155/2014/945930>
  • Martínez C., Vilariño S., Fernández M.I., Faria J., L. M. Canle, Santaballa J.A.: Mechanism of degradation of ketoprofen by heterogeneous photocatalysis in aqueous solution. Applied Catalysis B: Environmental 2013, 142-143, 633. <http://dx.doi.org/10.1016/j.apcatb.2013.05.018>
  • Zhang Qian, Li Chaolin, Li Ting: Rapid photocatalytic decolorization of methylene blue using high photon flux UV/TiO2/H2O2 process. Chemical Engineering Journal 2013, 217, 407. <http://dx.doi.org/10.1016/j.cej.2012.11.106>
  • Zhang Guangshan, Zhang Wen, Wang Peng, Minakata Daisuke, Chen Yongsheng, Crittenden John: Stability of an H2-producing photocatalyst (Ru/(CuAg)0.15In0.3Zn1.4S2) in aqueous solution under visible light irradiation. International Journal of Hydrogen Energy 2013, 38, 1286. <http://dx.doi.org/10.1016/j.ijhydene.2012.11.033>
  • Kandiel Tarek A., Robben Lars, Alkaim Ayad, Bahnemann Detlef: Brookite versus anatase TiO2 photocatalysts: phase transformations and photocatalytic activities. Photochem. Photobiol. Sci. 2013, 12, 602. <http://dx.doi.org/10.1039/c2pp25217a>
  • Alkaim A. F., Kandiel Tarek A., Hussein F. H., Dillert R., Bahnemann D. W.: Enhancing the photocatalytic activity of TiO2 by pH control: a case study for the degradation of EDTA. Catal. Sci. Technol. 2013, 3, 3216. <http://dx.doi.org/10.1039/c3cy00494e>
  • Pugachevskii M. A.: Photocatalytic properties of titania nanoparticles obtained by laser ablation. Nanotechnol Russia 2013, 8, 432. <http://dx.doi.org/10.1134/S1995078013040125>
  • Mountacer H., Nemmaoui S. M., Rafqah S., Voyard G., Sarakha M.: Photocatalysis of the Organophosphorus Fenamiphos: Insight into the Degradation Mechanism. ISRN Environmental Chemistry 2013, 2013, 1. <http://dx.doi.org/10.1155/2013/319178>
  • Machalický O., Lichý L., Tomica M., Hrdina R., Šolcová O.: Photocatalysis of sulfo and carboxy derivatives of indigo in a TiO2 slurry with the use of polychromatic irradiation. Reac Kinet Mech Cat 2012, 107, 63. <http://dx.doi.org/10.1007/s11144-012-0442-4>
  • Doronkin Dmitry E., Khan Tuhin Suvra, Bligaard Thomas, Fogel Sebastian, Gabrielsson P��r, Dahl S��ren, Obreg��n S., Caballero A., Col��n G., Ismail Adel A.: Sulfur poisoning and regeneration of the Ag/��-Al2O3 catalyst for H2-assisted SCR of NOx by ammonia. Applied Catalysis B: Environmental 2012, 117-118, 49. <http://dx.doi.org/10.1016/j.apcatb.2012.01.006>
  • Mena E., Rey A., Acedo B., Beltrán F.J., Malato S.: On ozone-photocatalysis synergism in black-light induced reactions: Oxidizing species production in photocatalytic ozonation versus heterogeneous photocatalysis. Chemical Engineering Journal 2012, 204-206, 131. <http://dx.doi.org/10.1016/j.cej.2012.07.076>
  • Choi Kyunghoon, Lee Woojin, Emeline A.V., Zhang X., Murakami T., Fujishima A., Robertson Peter K.J., Robertson Jeanette M.C., Bahnemann Detlef W.: Enhanced degradation of trichloroethylene in nano-scale zero-valent iron Fenton system with Cu(II). Journal of Hazardous Materials 2012, 211-212, 146. <http://dx.doi.org/10.1016/j.jhazmat.2011.11.078>
  • Gupta Vinod K., Jain Rajeev, Mittal Alok, Saleh Tawfik A., Nayak Arunima, Agarwal Shilpi, Sikarwar Shalini: Photo-catalytic degradation of toxic dye amaranth on TiO2/UV in aqueous suspensions. Material Science and Engineering C 2012, 32, 12. <http://dx.doi.org/10.1016/j.msec.2011.08.018>
  • Beltrán Fernando J., Aguinaco Almudena, Rey Ana, García-Araya Juan F.: Kinetic Studies on Black Light Photocatalytic Ozonation of Diclofenac and Sulfamethoxazole in Water. Industrial Eng Chem Res 2012, 51, 4533. <http://dx.doi.org/10.1021/ie202525f>
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  • Menéndez-Flores Víctor M., Bahnemann Detlef W., Ohno Teruhisa: Visible light photocatalytic activities of S-doped TiO2-Fe3+ in aqueous and gas phase. APPLIED CATALYSIS B 2011, 103, 99. <http://dx.doi.org/10.1016/j.apcatb.2011.01.015>
  • Kandiel Tarek A., Dillert Ralf, Robben Lars, Bahnemann Detlef W.: Photonic efficiency and mechanism of photocatalytic molecular hydrogen production over platinized titanium dioxide from aqueous methanol solutions. Catal Today 2011, 161, 196. <http://dx.doi.org/10.1016/j.cattod.2010.08.012>
  • Han Zhenbang, Dong Yongchun, Dong Siming: Copper–iron bimetal modified PAN fiber complexes as novel heterogeneous Fenton catalysts for degradation of organic dye under visible light irradiation. Journal of Hazardous Materials 2011, 189, 241. <http://dx.doi.org/10.1016/j.jhazmat.2011.02.026>
  • Horikoshi Satoshi, Abe Masahiko, Sato Susumu, Serpone Nick: Effect of microwave radiation on the (Raman) lattice phonons in selected titanium dioxide solid specimens. J Photochem Photobiol A Chem 2011, 220, 94. <http://dx.doi.org/10.1016/j.jphotochem.2011.03.025>
  • Ismail Adel A., Bahnemann Detlef W.: One-step synthesis of mesoporous platinum/titania nanocomposites as photocatalyst with enhanced photocatalytic activity for methanol oxidation. Green Chem 2011, 13, 428. <http://dx.doi.org/10.1039/c0gc00744g>
  • Braslavsky Silvia E., Braun André M., Cassano Alberto E., Emeline Alexei V., Litter Marta I., Palmisano Leonardo, Parmon Valentin N., Serpone Nick: Glossary of terms used in photocatalysis and radiation catalysis (IUPAC Recommendations 2011). Pure and App Chemis 2011, 1. <http://dx.doi.org/10.1351/PAC-REC-09-09-36>
  • Ivask A., Bondarenko O., Jepihhina N., Kahru A.: Profiling of the reactive oxygen species-related ecotoxicity of CuO, ZnO, TiO2, silver and fullerene nanoparticles using a set of recombinant luminescent Escherichia coli strains: differentiating the impact of particles and solubilised metals. Anal Bioanal Chem 2010, 398, 701. <http://dx.doi.org/10.1007/s00216-010-3962-7>
  • Ismail Adel A., Kandiel Tarek A., Bahnemann Detlef W.: Novel (and better?) titania-based photocatalysts: Brookite nanorods and mesoporous structures. J Photochem Photobiol A Chem 2010, 216, 183. <http://dx.doi.org/10.1016/j.jphotochem.2010.05.016>
  • Brezová Vlasta, Billik Peter, Vrecková Zuzana, Plesch Gustav: Photoinduced formation of reactive oxygen species in suspensions of titania mechanochemically synthesized from TiCl4. Journal of Molecular Catalysis A 2010, 327, 101. <http://dx.doi.org/10.1016/j.molcata.2010.05.019>
  • Silva Cláudia Gomes, Corma Avelino, García Hermenegildo: Metal–organic frameworks as semiconductors. J Mater Chem 2010, 20, 3141. <http://dx.doi.org/10.1039/b924937k>
  • Carlotti M. E., Ugazio E., Sapino S., Vione D., Fubini B., Morel S.: Effect of Propylene Glycol and Ethanol on the UVB-Induced Peroxidation of Linoleic Acid and Lipids of Porcine Skin, in the Presence of Different TiO2 Specimens. J Dispersion Sci Technol 2010, 31, 994. <http://dx.doi.org/10.1080/01932690903224615>
  • Sosnov E. A., Vasil’eva K. L., Malkov A. A.: The nature of the surface of pyrogenic titanium dioxide according to the optical spectroscopy data. Russ J Phys Chem 2010, 84, 1028. <http://dx.doi.org/10.1134/S0036024410060245>
  • Karunakaran Chockalingam, Dhanalakshmi Ramamoorthy: Substituent effect on nano TiO2- and ZnO-catalyzed phenol photodegradation rates. Int J Chem Kinet 2009, 41, 275. <http://dx.doi.org/10.1002/kin.20399>
  • Maretti Luca, Carbonell Esther, Alvaro Mercedes, Scaiano J.C., Garcia Hermenegildo: Laser flash photolysis of dioxo iron phthalocyanine intercalated in hydrotalcite and its use as a photocatalyst. J Photochem Photobiol A Chem 2009, 205, 19. <http://dx.doi.org/10.1016/j.jphotochem.2009.04.006>
  • Karunakaran Chockalingam, Dhanalakshmi Ramamoorthy: Selectivity in photocatalysis by particulate semiconductors. cent eur j chem 2009, 7, 134. <http://dx.doi.org/10.2478/s11532-008-0083-7>
  • Barker Philip J., Branch Amos: The interaction of modern sunscreen formulations with surface coatings. Progress in Organic Coating 2008, 62, 313. <http://dx.doi.org/10.1016/j.porgcoat.2008.01.008>
  • Menéndez-Flores Víctor M., Friedmann Donia, Bahnemann Detlef W.: Durability of Ag-TiO2 Photocatalysts Assessed for the Degradation of Dichloroacetic Acid. International Journal of Photoenergy 2008, 2008, 1. <http://dx.doi.org/10.1155/2008/280513>
  • Alvaro Mercedes, Carbonell Esther, Ferrer Belén, Llabrés i Xamena Francesc X., Garcia Hermenegildo: Semiconductor Behavior of a Metal-Organic Framework (MOF). Chem Eur J 2007, 13, 5106. <http://dx.doi.org/10.1002/chem.200601003>
  • Emeline A.V., Ryabchuk V.K., Serpone N.: Photoreactions occurring on metal-oxide surfaces are not all photocatalytic. Catal Today 2007, 122, 91. <http://dx.doi.org/10.1016/j.cattod.2007.02.007>
  • van Grieken Rafael, Marugán Javier, López-Muñoz María-José, Aguado José: On the comparison of photocatalysts activity: A novel procedure for the measurement of titania surface in TiO2/SiO2 materials. Catal Today 2007, 124, 103. <http://dx.doi.org/10.1016/j.cattod.2007.03.053>
  • Josset Sébastien, Taranto Jérôme, Keller Nicolas, Keller Valérie, Lett Marie-Claire, Ledoux Marc J., Bonnet Valery, Rougeau Sylvain: UV-A photocatalytic treatment of high flow rate air contaminated with Legionella pneumophila. Catal Today 2007, 129, 215. <http://dx.doi.org/10.1016/j.cattod.2007.08.010>
  • Serpone Nick, Dondi Daniele, Albini Angelo: Inorganic and organic UV filters: Their role and efficacy in sunscreens and suncare products. Inorg Chim Ada 2007, 360, 794. <http://dx.doi.org/10.1016/j.ica.2005.12.057>
  • Horikoshi Satoshi, Kajitani Masatsugu, Serpone Nick: The microwave-/photo-assisted degradation of bisphenol-A in aqueous TiO2 dispersions revisited. J Photochem Photobiol A Chem 2007, 188, 1. <http://dx.doi.org/10.1016/j.jphotochem.2006.11.010>
  • Doña J. M., Garriga C., Araña J., Pérez J., Colon G., Macías M., Navio J. A.: The effect of dosage on the photocatalytic degradation of organic pollutants. Res. Chem. Intermed. 2007, 33, 351. <http://dx.doi.org/10.1163/156856707779238676>
  • Alvaro Mercedes, Carbonell Esther, Fornés Vicente, García Hermenegildo: Enhanced Photocatalytic Activity of Zeolite-Encapsulated TiO2 Clusters by Complexation with Organic Additives and N-Doping. Chem Eur J of Chem Phys 2006, 7, 200. <http://dx.doi.org/10.1002/cphc.200500264>
  • Joo Hyunku: A simple technique to determine quantum yield for UV photocatalytic decomposition studies. BULL KOREAN CHEM SOC 2006, 23, 931. <http://dx.doi.org/10.1007/s11814-006-0010-6>
  • Marugán Javier, Hufschmidt Dirk, López-Muñoz María-José, Selzer Volker, Bahnemann Detlef: Photonic efficiency for methanol photooxidation and hydroxyl radical generation on silica-supported TiO2 photocatalysts. APPLIED CATALYSIS B 2006, 62, 201. <http://dx.doi.org/10.1016/j.apcatb.2005.07.013>
  • Grieken Rafael, Aguado José, López-Muñoz María-José, Marugán Javier: Photocatalytic gold recovery from spent cyanide plating bath solutions. Gold Bull 2005, 38, 180. <http://dx.doi.org/10.1007/BF03215258>
  • Alvaro Mercedes, Carbonell Esther, Esplá Mercedes, Garcia Hermenegildo: Iron phthalocyanine supported on silica or encapsulated inside zeolite Y as solid photocatalysts for the degradation of phenols and sulfur heterocycles. APPLIED CATALYSIS B 2005, 57, 37. <http://dx.doi.org/10.1016/j.apcatb.2004.10.003>
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  • Kőrösi László, Németh József, Dékány Imre: Structural and photooxidation properties of SnO2/layer silicate nanocomposites. Appl Clay Sci 2004, 27, 29. <http://dx.doi.org/10.1016/j.clay.2003.12.004>
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  • Du Yikui, Rabani Joseph: Determination of quantum yields in two-dimensional scattering systems. J Photochem Photobiol A Chem 2004, 162, 575. <http://dx.doi.org/10.1016/S1010-6030(03)00412-X>
  • Pernyeszi Tı́mea, Dékány Imre: Photocatalytic degradation of hydrocarbons by bentonite and TiO2 in aqueous suspensions containing surfactants. Colloid Surf A Phys Eng Aspects 2003, 230, 191. <http://dx.doi.org/10.1016/j.colsurfa.2003.09.023>
  • Al-Rasheed Radwan, Cardin David J.: Photocatalytic degradation of humic acid in saline waters. Part 1. Artificial seawater: influence of TiO2, temperature, pH, and air-flow. Chemosphere 2003, 51, 925. <http://dx.doi.org/10.1016/S0045-6535(03)00097-3>
  • Colón G, Hidalgo M.C, Navı́o J.A: Photocatalytic behaviour of sulphated TiO2 for phenol degradation. APPLIED CATALYSIS B 2003, 45, 39. <http://dx.doi.org/10.1016/S0926-3373(03)00125-5>
  • da Silva Cláudia Gomes, Faria Joaquim Luı́s: Photochemical and photocatalytic degradation of an azo dye in aqueous solution by UV irradiation. J Photochem Photobiol A Chem 2003, 155, 133. <http://dx.doi.org/10.1016/S1010-6030(02)00374-X>
  • Rajeshwar Krishnan, Chenthamarakshan C.R, Ming Yong, Sun Wenjian: Cathodic photoprocesses on titania films and in aqueous suspensions. Journal of Electroanalytical Chemistry 2002, 538-539, 173. <http://dx.doi.org/10.1016/S0022-0728(02)00902-6>
  • Schoumacker Karine, Geantet Christophe, Lacroix Michel, Puzenat Eric, Guillard Chantal, Herrmann Jean-Marie: Photocatalytic synthesis of thio-organic compounds: case study of propan-1-thiol. J Photochem Photobiol A Chem 2002, 152, 147. <http://dx.doi.org/10.1016/S1010-6030(02)00208-3>
  • Serpone N., Salinaro A., Emeline A., Ryabchuk V.: Turnovers and photocatalysis. J Photochem Photobiol A Chem 2000, 130, 83. <http://dx.doi.org/10.1016/S1010-6030(99)00217-8>