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Pure Appl. Chem., 1999, Vol. 71, No. 2, pp. 281-288

http://dx.doi.org/10.1351/pac199971020281

Ruthenium-oxo and -tosylimido porphyrin complexes for epoxidation and aziridination of alkenes

C.-M. Che and W.-Y. Yu

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  • Chen Tse-Hong, Yuan Zhibo, Carver Aaron, Zhang Rui: Visible light-promoted selective oxidation of sulfides to sulfoxides catalyzed by ruthenium porphyrins with iodobenzene diacetate. Applied Catalysis A: General 2014. <http://dx.doi.org/10.1016/j.apcata.2014.04.014>
  • Enow Charles A., Marais Charlene, Bezuidenhoudt Barend C.B.: Catalytic epoxidation of stilbenes with non-peripherally alkyl substituted carbonyl ruthenium phthalocyanine complexes. J. Porphyrins Phthalocyanines 2012, 16, 403. <http://dx.doi.org/10.1142/S1088424612500459>
  • Zhang Rui, Huang Yan, Abebrese Chris, Thompson Helen, Vanover Eric, Webb Cathleen: Generation of trans-dioxoruthenium(VI) porphyrins: A photochemical approach. Inorg Chim Ada 2011, 376, 152. <http://dx.doi.org/10.1016/j.ica.2011.06.002>
  • Abebrese Chris, Huang Yan, Pan Alice, Yuan Zhibo, Zhang Rui: Kinetic studies of oxygen atom transfer reactions from trans-dioxoruthenium(VI) porphyrins to sulfides. J  Inorg Biochem 2011, 105, 1555. <http://dx.doi.org/10.1016/j.jinorgbio.2011.08.003>
  • Che Chi-Ming, Yu Wing-Yiu: ChemInform Abstract: Ruthenium-oxo and -Tosylimido Porphyrin Complexes for Epoxidation and Aziridination of Alkenes. ChemInform 2010, 31, no. <http://dx.doi.org/10.1002/chin.200001286>
  • Huang Yan, Vanover Eric, Zhang Rui: A facile photosynthesis of trans-dioxoruthenium(vi) porphyrins. Chem Commun 2010, 46, 3776. <http://dx.doi.org/10.1039/c003094e>
  • Yang Li, Wu Zhiqing, Liang Lei, Zhou Xiangge: Synthesis, crystal structures and catalytic abilities of new macrocyclic bis-pyridineamido MnIII and FeIII complexes. J Organomet Chem 2009, 694, 2421. <http://dx.doi.org/10.1016/j.jorganchem.2009.03.019>
  • Fantauzzi Simone, Caselli Alessandro, Gallo Emma: Nitrene transfer reactions mediated by metallo-porphyrin complexes. Dalton Trans 2009, 5434. <http://dx.doi.org/10.1039/b902929j>
  • Ho Chi-Ming, Zhu Nianyong, Lau Tai-Chu, Che Chi-Ming, Yip Wing-Ping: Homogeneous [RuIII(Me3tacn)Cl3]-Catalyzed Alkenecis-Dihydroxylation with Aqueous Hydrogen Peroxide. Chem Asian J 2008, 3, 70. <http://dx.doi.org/10.1002/asia.200700237>
  • Yang Li, Wei Rui-Ning, Li Rui, Zhou Xiang-Ge, Zuo Jing-Lin: Epoxidation catalyzed by iron(III) and manganese(III) pyridine-2-carboxamido complexes. Journal of Molecular Catalysis A 2007, 266, 284. <http://dx.doi.org/10.1016/j.molcata.2006.11.015>
  • D'hooghe Matthias, Boelens Mark, Piqueur Johan, Kimpe Norbert De: Stereospecific aziridination of olefins via electrophile-induced cyclization of ?,?-unsaturated imines and subsequent hydrolytic rearrangement. Chem Commun 2007, 1927. <http://dx.doi.org/10.1039/b703147e>
  • Che Chi-Ming, Yip Wing-Ping, Yu Wing-Yiu: Ruthenium-Catalyzed Oxidation of Alkenes, Alkynes, and Alcohols to Organic Acids with Aqueous Hydrogen Peroxide. Chem Asian J 2006, 1, 453. <http://dx.doi.org/10.1002/asia.200600091>
  • Enthaler Stephan, Erre Giulia, Tse Man Kin, Junge Kathrin, Beller Matthias: Biomimetic transfer hydrogenation of ketones with iron porphyrin catalysts. Tetrahetron Lett 2006, 47, 8095. <http://dx.doi.org/10.1016/j.tetlet.2006.09.058>
  • Neumann Ronny, Khenkin Alexander M.: Molecular oxygen and oxidation catalysis by phosphovanadomolybdates. Chem Commun 2006, 2529. <http://dx.doi.org/10.1039/b600711m>
  • Burri Estelle, Öhm Margarita, Daguenet Corinne, Severin Kay: Site-Isolated Porphyrin Catalysts in Imprinted Polymers. Chem Eur J 2005, 11, 5055. <http://dx.doi.org/10.1002/chem.200500375>
  • Zhang Rui, Yu Wing-Yiu, Che Chi-Ming: Catalytic enantioselective oxidation of aromatic hydrocarbons with D4-symmetric chiral ruthenium porphyrin catalysts. Tet Asymm 2005, 16, 3520. <http://dx.doi.org/10.1016/j.tetasy.2005.08.059>
  • Zheng Shi-Long, Yu Wing-Yiu, Xu Ming-Xia, Che Chi-Ming: First synthesis of naturally occurring (±)-epi-conocarpan. Tetrahetron Lett 2003, 44, 1445. <http://dx.doi.org/10.1016/S0040-4039(02)02860-5>
  • Balakrishna Maravanji S., Panda Rashmishree, Mague Joel T.: Synthesis, structures, spectroscopic and electrochemical studies of Ru(II) complexes containing bis(phosphino)amine ligands. J Polyhedron 2003, 22, 587. <http://dx.doi.org/10.1016/S0277-5387(02)01422-5>
  • Teng Pang-Fei, Lai Tat-Shing, Kwong Hoi-Lun, Che Chi-Ming: Asymmetric inter- and intramolecular cyclopropanations of alkenes catalyzed by rhodium D4-porphyrin: a comparison of rhodium- and ruthenium-centred catalysts. Tet Asymm 2003, 14, 837. <http://dx.doi.org/10.1016/S0957-4166(03)00047-8>
  • Zheng Shi-Long, Yu Wing-Yiu, Che Chi-Ming: Ruthenium(II) Porphyrin Catalyzed Formation of (Z)-4-Alkyloxycarbonyl- methylidene-1,3-dioxolanes from γ-Alkoxy-α-diazo-β-ketoesters. Org Lett 2002, 4, 889. <http://dx.doi.org/10.1021/ol010283f>
  • Yau Sammi K. W., Che Chi-Ming, Lau Tai-Chu: Kinetics and mechanisms of the reduction of a cis-dioxoruthenium(vi) complex by [Ni(tacn)2]2+ and [Fe(H2O)6]2+. J Chem Soc Dalton Trans 2002, 2697. <http://dx.doi.org/10.1039/b202230c>
  • Huynh My-Hang V., White Peter S., Meyer Thomas J.: Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic Isotope Effect of ≥31.1. Angew Chem 2000, 112, 4267. <http://dx.doi.org/10.1002/1521-3757(20001117)112:22<4267::AID-ANGE4267>3.0.CO;2-5>
  • Huynh My-Hang V., White Peter S., Meyer Thomas J.: Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic Isotope Effect of ≥31.1. Angew Chem 2000, 39, 4101. <http://dx.doi.org/10.1002/1521-3773(20001117)39:22<4101::AID-ANIE4101>3.0.CO;2-E>