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Pure Appl. Chem., 1997, Vol. 69, No. 6, pp. 1325-1334

http://dx.doi.org/10.1351/pac199769061325

ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON ELECTROANALYTICAL CHEMISTRY

Consistency of pH standard values with the corresponding thermodynamic acid dissociation constants (Technical Report)

M. Filomena Camões, M. J. Guiomar Lito, M. I. A. Ferra and A. K. Covington

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  • Horváth Péter, Gergely András, Mazák Károly, Kökösi József, Szász György: Novel Data on the Effect of Tetrahydrofuran as an Organic Co-Modifier in RP-HPLC. Chromatographia 2013, 76, 441. <http://dx.doi.org/10.1007/s10337-013-2421-y>
  • Roy Lakshmi N., Roy Rabindra N., Allen Kathleen A., Mehrhoff Casey J., Henson Isaac B., Stegner Jessica M.: Buffer standards for the physiological pH of the zwitterionic compound of 3-(N-morpholino)propanesulfonic acid (MOPS) from T=(278.15 to 328.15)K. K J CHEM THERMODYN 2012, 47, 21. <http://dx.doi.org/10.1016/j.jct.2011.09.010>
  • Roy Rabindra N., Roy Lakshmi N., Henson Isaac B., Stegner Jessica M., Dinga John J., Summers Clark E., Suhrheinrich Gregory L., Veliz Jaime A., Dieterman Lauren A.: Buffer standards for the physiological pH of N-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]glycine (TRICINE) from T=(278.15 to 328.15)K. The Journal of Chemical Thermodynamics 2012, 52, 11. <http://dx.doi.org/10.1016/j.jct.2012.02.019>
  • Ferra M. I. A., Graça J. R., Marques A. M. M.: Application of the Pitzer Model to Assignment of pH to Phthalate Standard Buffer Solutions. J Solution Chem 2009, 38, 1433. <http://dx.doi.org/10.1007/s10953-009-9421-4>
  • Partanen Jaakko I., Juusola Pekka M., Covington Arthur K.: Re-evaluation of the First and Second Stoichiometric Dissociation Constants of Oxalic Acid at Temperatures from 0 to 60 °C in Aqueous Oxalate Buffer Solutions with or without Sodium or Potassium Chloride. J Solution Chem 2009, 38, 1385. <http://dx.doi.org/10.1007/s10953-009-9443-y>
  • Bastos Ivan N., Platt Gustavo M., Andrade Mônica C., Soares Glória D.: Theoretical study of Tris and Bistris effects on simulated body fluids. J Mol Liq 2008, 139, 121. <http://dx.doi.org/10.1016/j.molliq.2007.12.003>
  • Raghuraman B., Gustavson G., Mullins O. C., Rabbito P.: Spectroscopic pH measurement for high temperatures, pressures and ionic strength. AIChE 2006, 52, 3257. <http://dx.doi.org/10.1002/aic.10933>
  • Partanen Jaakko I., Covington Arthur K.: Re-evaluation of the First and Second Stoichiometric Dissociation Constants of Phthalic Acid at Temperatures from (0 to 60) °C in Aqueous Phthalate Buffer Solutions with or without Potassium Chloride. 1. Estimation of the Parameters for the Hückel Model Activity Coefficient Equations for Calculation of the Second Dissociation Constant. J Chemical & Engineering Data 2006, 51, 777. <http://dx.doi.org/10.1021/je0504921>
  • Lito M.J. Guiomar H.M., Camões M. Filomena G.F.C.: Reassessment of pH reference values with improved methodology for the evaluation of ionic strength. Analytica Chimica Acta 2005, 531, 141. <http://dx.doi.org/10.1016/j.aca.2004.09.048>
  • Kumar Anil: Pressure dependence of the dissociation of acetic, benzoic, mandelic and succinic acids at 298.15K. Thermochimica 2005, 439, 154. <http://dx.doi.org/10.1016/j.tca.2005.06.045>
  • Partanen Jaakko I., Covington Arthur K.: Re-evaluation of Stoichiometric Dissociation Constants from Electrochemical Cell Data for Formic Acid at Temperatures from (0 to 60) °C and for Some Other Aliphatic Carboxylic Acids at (18 or 25) °C in Aqueous Potassium Chloride Solutions. J Chemical & Engineering Data 2005, 50, 497. <http://dx.doi.org/10.1021/je040013i>
  • Partanen Jaakko I., Covington Arthur K.: Re-evaluation of the Second Stoichiometric Dissociation Constants of Phosphoric Acid at Temperatures from (0 to 60) °C in Aqueous Buffer Solutions with or without NaCl or KCl. 1. Estimation of the Parameters for the Hückel Model Activity Coefficient Equations. J Chemical & Engineering Data 2005, 50, 1502. <http://dx.doi.org/10.1021/je050161o>
  • Partanen Jaakko I., Covington Arthur K.: Re-Evaluation of Stoichiometric Dissociation Constants from Electrochemical Cell Data for Propionic and n-Butyric Acids at (0 to 60) °C and for Some Other Aliphatic Carboxylic Acids at (18 or 25) °C in Aqueous Sodium Chloride Solutions. J Chemical & Engineering Data 2004, 49, 394. <http://dx.doi.org/10.1021/je030242p>
  • Lito M.J.Guiomar H.M, Camões M.Filomena G.F.C, Covington A.K: Effect of citrate impurities on the reference pH value of potassium dihydrogen buffer solution. Analytica Chimica Acta 2003, 482, 137. <http://dx.doi.org/10.1016/S0003-2670(03)00194-6>
  • Partanen Jaakko I., Covington Arthur K.: Determination of Stoichiometric Dissociation Constants of Acetic Acid in Aqueous Solutions Containing Acetic Acid, Sodium Acetate, and Sodium Chloride at (0 to 60) °C. J Chemical & Engineering Data 2003, 48, 797. <http://dx.doi.org/10.1021/je030100v>
  • Boström M., Williams D., Stewart P., Ninham B.: Hofmeister effects in membrane biology: The role of ionic dispersion potentials. Phys Rev E 2003, 68, 041902. <http://dx.doi.org/10.1103/PhysRevE.68.041902>
  • Barbosa J, Barrón D, Jiménez-Lozano E, Sanz-Nebot V: Comparison between capillary electrophoresis, liquid chromatography, potentiometric and spectrophotometric techniques for evaluation of pKa values of zwitterionic drugs in acetonitrile–water mixtures. Analytica Chimica Acta 2001, 437, 309. <http://dx.doi.org/10.1016/S0003-2670(01)00997-7>
  • Barbosa J., Barrón D., Cano J., Jiménez-Lozano E., Sanz-Nebot V., Toro I.: Evaluation of electrophoretic method versus chromatographic, potentiometric and absorptiometric methodologies for determing pKa values of quinolones in hydroorganic mixtures. J  Pharm Biomed Anal 2001, 24, 1087. <http://dx.doi.org/10.1016/S0731-7085(00)00561-6>
  • de Mendonça António J.G., Vaz Margarida I.P.M., de Mendonça Dina I.M.D.: Activity coefficients in the evaluation of food preservatives. Innovative Food Science and Emerging Technology 2001, 2, 175. <http://dx.doi.org/10.1016/S1466-8564(01)00037-6>
  • Barriada José L., Brandariz Isabel, Kataky Ritu, Covington Arthur K., Sastre de Vicente Manuel E.: pH Standardization of 0.05 mol·kg-1 Tetraoxalate Buffer:  Application of the Pitzer Formalism. J Chemical & Engineering Data 2001, 46, 1292. <http://dx.doi.org/10.1021/je010052j>
  • Barbosa J, Barrón D, Butı́ S: Chromatographic behaviour of ionizable compounds in liquid chromatography. Part 1. pH scale, pKa and pHS values for standard buffers in tetrahydrofuran–water. Analytica Chimica Acta 1999, 389, 31. <http://dx.doi.org/10.1016/S0003-2670(99)00133-6>
  • Barbosa J, Marqués I, Barrón D, Sanz-Nebot V: The application of factor analysis to solvatochromic parameters and pHs values for the standardization of potentiometric sensors in mobile phases used in liquid chromatography. Trends in Analytical Chemistry 1999, 18, 543. <http://dx.doi.org/10.1016/S0165-9936(99)00131-4>
  • Barrón D., Butı́ S., Ruiz M., Barbosa J.: Evaluation of acidity constants and preferential solvation in tetrahydrofuran–water mixtures. J Polyhedron 1999, 18, 3281. <http://dx.doi.org/10.1016/S0277-5387(99)00265-X>
  • Barbosa J., Barrón D., Butı́ S., Marqués I.: Assignment of pHS values of reference buffer solutions for standardization of potentiometric sensors in THF–water. J Polyhedron 1999, 18, 3361. <http://dx.doi.org/10.1016/S0277-5387(99)00274-0>