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Pure Appl. Chem., 1997, Vol. 69, No. 5, pp. 1007-1014


Reference value standards and primary standards for pH measurements in D2O and aqueousorganic solvent mixtures: New accessions and assessments (Technical Report)

P. R. Mussini, T. Mussini and S. Rondinini

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  • Kılıç H.: Ultraviolet–visible study on acid–base equilibria for some 7,8-ethylenedioxy coumarins. Journal of Molecular Liquids 2013, 187, 314. <>
  • Kılıç H.: Electronic absorption study on hydration, solvation behavior for some keto and thioketo pyrimidine derivatives. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2013, 104, 328. <>
  • Carvalheda Catarina A., Campos Sara R. R., Machuqueiro Miguel, Baptista António M.: Structural Effects of pH and Deacylation on Surfactant Protein C in an Organic Solvent Mixture: A Constant-pH MD Study. J. Chem. Inf. Model. 2013, 53, 2979. <>
  • Wang Peiming, Kosinski Jerzy J., Anderko Andrzej, Springer Ronald D., Lencka Malgorzata M., Liu Jiangping: Ethylene Glycol and Its Mixtures with Water and Electrolytes: Thermodynamic and Transport Properties. Ind. Eng. Chem. Res. 2013, 52, 15968. <>
  • Vogl Michael, Brecker Lothar: Substrate binding to Candida tenuis xylose reductase during catalysis. RSC Adv. 2013, 3, 25997. <>
  • Secilmis-Canbay Hale, Cubuk-Demiralay Ebru, Alsancak Guleren, Ozkan Sibel A.: The Combined Effect of the Organic Modifier Content and pH of the Mobile Phase on the Chromatographic Behavior of Some Arylpropionic and Arylacetic Acids to Optimize Their Liquid Chromatographic Determinations. Chromatographia 2012, 75, 711. <>
  • Eixelsberger Thomas, Brecker Lothar, Nidetzky Bernd: Catalytic mechanism of human UDP-glucose 6-dehydrogenase: in situ proton NMR studies reveal that the C-5 hydrogen of UDP-glucose is not exchanged with bulk water during the enzymatic reaction. Carbohydrate Research 2012, 356, 209. <>
  • Sanli Nurullah, Sanli Senem, Sızır Umit, Gumustas Mehmet, Ozkan Sibel A.: Determination of pK a Values of Cefdinir and Cefixime by LC and Spectrophotometric Methods and Their Analysis in Pharmaceutical Dosage Forms. Chroma 2011, 73, 1171. <>
  • Sanli Senem, Sanli Nurullah, Gumustas Mehmet, Ozkan Sibel A., Karadas Nurgul, Aboul-Enein Hassan Y.: Simultaneous Estimation of Ceftazidime and Ceftizoxime in Pharmaceutical Formulations by HPLC Method. Chromatogr Suppl 2011, 74, 549. <>
  • Bonin Julien, Costentin Cyrille, Louault Cyril, Robert Marc, Savéant Jean-Michel: Water (in Water) as an Intrinsically Efficient Proton Acceptor in Concerted Proton Electron Transfers. J Am Chem Soc 2011, 133, 6668. <>
  • Vogl Michael, Kratzer Regina, Nidetzky Bernd, Brecker Lothar: Candida tenuis xylose reductase catalysed reduction of acetophenones: the effect of ring-substituents on catalytic efficiency. Biomol Chem 2011, 9, 5863. <>
  • Dean S. W., Moutinho da Silva Ricardo, Borges Paulo Paschoal, Fraga Isabel Cristina Serta, Stradiotto Nelson Ramos: New Methodology for pH Measurements in Fuel Ethanol Using Glass Electrode. J ASTM Int 2011, 8, 103192. <>
  • Demiralay Ebru Cubuk, Cubuk Burcu, Ozkan Sibel A., Alsancak Guleren: Combined effect of polarity and pH on the chromatographic behavior of some angiotensin II receptor antagonists and optimization of their determination in pharmaceutical dosage forms. J  Pharm Biomed Anal 2010, 53, 475. <>
  • KANZAKI Ryo, SONG Xuedan, ISHIGURO Shin-ichi, UMEBAYASHI Yasuhiro: Electrochemistry 2010, 78, 687. <>
  • Demiralay Ebru Cubuk, Alsancak Guleren, Ozkan Sibel A.: Determination of pK a values of nonsteroidal antiinflammatory drug-oxicams by RP-HPLC and their analysis in pharmaceutical dosage forms. J Sep Science 2009, 32, 2928. <>
  • Brecker Lothar, Mahut Marek, Schwarz Alexandra, Nidetzky Bernd: In situ proton NMR study of acetyl and formyl group migration in mono-O-acyl D-glucose. Magn Reson Chem 2009, 47, 328. <>
  • Spitzer Petra, Fisicaro Paola, Seitz Steffen, Champion Rachel: pH and electrolytic conductivity as parameters to characterize bioethanol. Accred Qual Assur 2009, 14, 671. <>
  • Hussain Amjad, Bhatt Anjani K., Krishna Kumar D., Thorat R.B., Padhiyar H.J., Shukla R.S.: Substitution of trans ligands in μ-oxo-bis(μ-acetato)diruthenium(III) complexes: Synthesis and kinetic studies. Inorg Chim Ada 2009, 362, 1101. <>
  • Falciola Luigi, Fierro Annamaria, Mussini Patrizia Romana, Mussini Torquato, Rossi Manuela, Dumitrel Doru: Medium Effects and Determination of Primary and Secondary Standards for pH Measurements in (Glycerol + Water) Solvent Media at Normal and Subzero Temperatures, With Characterization of Appropriate Salt Bridges†. J. Chem. Eng. Data 2009, 54, 286. <>
  • Máriássy Michal, Pratt Kenneth W, Spitzer Petra: Major applications of electrochemical techniques at national metrology institutes. Metrologica 2009, 46, 199. <>
  • Zevatskii Yu. E., Samoilov D. V., Mchedlov-Petrosyan N. O.: Conthemporary methods for the experimental determination of dissociation constants of organic acids in solutions. Russ J Gen Chem 2009, 79, 1859. <>
  • Kılıç H.: Ultraviolet–visible study of tautomeric behavior of some carbonyl and thiocarbonyl pyrimidine derivatives: Experimental evidence of enolization and thioketonization. Spectrochim Acta A Mol Biomol Spectrosc 2008, 71, 175. <>
  • Srour Rafif K., McDonald Louis M.: Determination of the Acidity Constants of Methyl Red and Phenol Red Indicators in Binary Methanol− and Ethanol−Water Mixtures. J. Chem. Eng. Data 2008, 53, 116. <>
  • Ignjatović Ljubiša M., Barek Jiří, Zima Jiří, Stević Milica C.: Adsorptive Stripping Voltammetric Determination of 1,1-Dimethyl-3-phenyltriazene. Collect Czech Chem Commun 2008, 73, 97. <>
  • Falciola Luigi, Mussini Patrizia R., Mussini Torquato, Rossi Manuela: A Determination of Standard Potentials and Related Primary pH Standards in the 50 Mass Percent (N-Methyl-2-Pyrrolidinone + Water) Mixture at Various Temperatures. J Solution Chem 2007, 36, 1037. <>
  • Nourmohammadian Farahnaz, Davoodzadeh Mahnaz, Alizadeh Abdol-Ali: New cyclopentadiene derivatives as novel pH indicators. J Dye Pig 2007, 74, 741. <>
  • Holzle L.R.B., Azambuja D.S., Piatnicki C.M.S., Englert G.E.: Corrosion behaviour of aluminium in ethyleneglycol–water electrolytes containing phosphonic acid. Material Chemistry and Physics 2007, 103, 59. <>
  • Holzle L.R.B., Azambuja D.S., Piatnicki C.M.S., Englert G.E.: Corrosion behavior of aluminium in ethyleneglycol–water electrolytes containing EDTA. Material Chemistry and Physics 2005, 91, 375. <>
  • Beltrán J.L., Sanli N., Fonrodona G., Barrón D., Özkan G., Barbosa J.: Spectrophotometric, potentiometric and chromatographic pKa values of polyphenolic acids in water and acetonitrile–water media. Analytica Chimica Acta 2003, 484, 253. <>
  • Falciola Luigi, Mussini Patrizia R., Mussini Torquato: Problems of Electrochemical Controls of Oxidation-Reduction Systems in Aqueous-Organic and Nonaqueous Media. The rH Index with Establishment of the Relevant Scales and Standards. Collect Czech Chem Commun 2003, 68, 1605. <>
  • Ballesteros O., Toro I., Sanz-Nebot V., Navalón A., Vílchez J. L., Barbosa J.: Optimization of the composition and pH of the mobile phase used for separation and determination of a series of quinolone antibacterials regulated by the European Union. Chroma 2002, 56, 413. <>
  • Antonini D, Falciola L, Mussini P.R, Mussini T: Ionization constants ofo-phthalic acid in (propylene carbonate + water) and (ethylene carbonate + water), and thermodynamics of the cellPt|H2|HCl(m)| Hg2Cl2|Hg. K J CHEM THERMODYN 2001, 33, 1473. <>
  • Barbosa J, Barrón D, Jiménez-Lozano E, Sanz-Nebot V: Comparison between capillary electrophoresis, liquid chromatography, potentiometric and spectrophotometric techniques for evaluation of pKa values of zwitterionic drugs in acetonitrile–water mixtures. Analytica Chimica Acta 2001, 437, 309. <>
  • Antonini D, Falciola L, Mussini P.R, Mussini T: Medium effects, comparability and predictability of pH-standards in aqueous+organic solvent mixtures: behavior of the (ethylene carbonate+water) and (propylene carbonate+water) systems. Journal of Electroanalytical Chemistry 2001, 503, 153. <>
  • Barbosa J., Barrón D., Cano J., Jiménez-Lozano E., Sanz-Nebot V., Toro I.: Evaluation of electrophoretic method versus chromatographic, potentiometric and absorptiometric methodologies for determing pKa values of quinolones in hydroorganic mixtures. J  Pharm Biomed Anal 2001, 24, 1087. <>
  • Barbosa J., Bergés R., Sanz-Nebot V.: Prediction of the chromatographic behaviour for a series of diuretic compounds. Chroma 2000, 51, 417. <>
  • Barbosa José, Barrón Dolores, Butí Salvador: Autoprotolysis Constants and Standardization of pH Measurements in Tetrahydrofuran-Water Mixtures. Electroanalysis (N Y ) 1999, 11, 627. <<627::AID-ELAN627>3.0.CO;2-V>
  • Barbosa J, Bergés R, Sanz-Nebot V, Toro I: Chromatographic behavior of ionizable compounds in liquid chromatography. Part 2. Standardization of potentiometric sensors and effect of pH and ionic strength on the retention of analytes using acetonitrile–water mobile phases. Analytica Chimica Acta 1999, 389, 43. <>
  • Barbosa J, Barrón D, Butı́ S: Chromatographic behaviour of ionizable compounds in liquid chromatography. Part 1. pH scale, pKa and pHS values for standard buffers in tetrahydrofuran–water. Analytica Chimica Acta 1999, 389, 31. <>
  • Barbosa J, Marqués I, Barrón D, Sanz-Nebot V: The application of factor analysis to solvatochromic parameters and pHs values for the standardization of potentiometric sensors in mobile phases used in liquid chromatography. Trends in Analytical Chemistry 1999, 18, 543. <>
  • Marqués I, Fonrodona G, Butı́ S, Barbosa J: Solvent effects on mobile phases used in liquid chromatography: factor analysis applied to protonation equilibria and solvatochromic parameters. Trends in Analytical Chemistry 1999, 18, 472. <>
  • Barrón D., Butı́ S., Ruiz M., Barbosa J.: Evaluation of acidity constants and preferential solvation in tetrahydrofuran–water mixtures. J Polyhedron 1999, 18, 3281. <>
  • Barbosa J., Barrón D., Butı́ S., Marqués I.: Assignment of pHS values of reference buffer solutions for standardization of potentiometric sensors in THF–water. J Polyhedron 1999, 18, 3361. <>
  • Hernández-Arteseros J. A., Barbosa J., Compañó R., Prat M. D.: Optimisation of mobile phase pH in liquid chromatography. Application to fluorimetric detection of series of quinolones. Chroma 1998, 48, 251. <>
  • Izutsu Kosuke, Yamamoto Hiroki: Applicability of 0.05 mol kg−1 potassium hydrogen phthalate as reference value pH standard in water–organic solvent mixtures. Talanta (London) 1998, 47, 1157. <>