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Pure Appl. Chem., 1996, Vol. 68, No. 3, pp. 691-694

Recent advances in asymmetric synthesis using chiral lithium amide bases

N. S. Simpkins

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  • Seki Atsushi, Asami Masatoshi: Catalytic enantioselective rearrangement of meso-epoxides mediated by chiral lithium amides in the presence of excess cross-linked polymer-bound lithium amides. Tetrahedron 2002, 58, 4655. <>
  • Honda Toshio, Kimura Nobuaki: Enantioselective Deprotonation of meso-Cycloheptanone Derivative:  Application to the Synthesis of a Potential Intermediate for Pseudomonic Acid B. Org Lett 2002, 4, 4567. <>
  • Pettersen Daniel, Amedjkouh Mohamed, Nilsson Lill Sten O., Ahlberg Per: On the novel function of the additive DBU. Catalytic stereoselective deprotonation by a mixed dimer of lithiated DBU and a chiral lithium amide. J Chem Soc Perkin Trans 2 2002, 1397. <>
  • Asami Masatoshi, Seki Atsushi: An Intriguing Effect of Polymer-Bound Lithium Amides in Catalytic Enantioselective Rearrangement of meso-Epoxides Mediated by Chiral Lithium Amides. Chem Lett 2002, 160. <>
  • Amedjkouh Mohamed, Pettersen Daniel, Nilsson Lill Sten O., Davidsson Öjvind, Ahlberg Per: A Novel Mixed Dimer of a Norephedrine-Derived Chiral Lithium Amide and 2-Lithium-1-methylimidazole, and Catalytic Enantioselective Deprotonation of Cyclohexene Oxide. Chem Eur J 2001, 7, 4368. <<4368::AID-CHEM4368>3.0.CO;2-K>
  • TORIYAMA Masaharu, TOKUTAKE Norio, KOGA Kenji: Stereoselective Reactions. XXXIII. Design and Synthesis of Chiral Bidentate Amines Having a Bulky Group on the Chiral Carbon. Chem Pharm Bull 2001, 49, 330. <>
  • TORIYAMA Masaharu, SUGASAWA Keizo, MOTOHASHI Shigeyasu, TOKUTAKE Norio, KOGA Kenji: Stereoselective Reactions. XXXIV. Enantioselective Deprotonation of Prochiral 4-Substituted Cyclohexanones Using Chiral Bidentate Lithium Amides Having a Bulky Group Instead of a Phenyl Group on the Chiral Carbon. Chem Pharm Bull 2001, 49, 468. <>
  • Magnus Philip, Bailey James M., Porter Michael J.: Application of the β-azidonation reaction to the enantioselective synthesis of the lycorane Amaryllidaceae alkaloids. Tetrahedron 1999, 55, 13927. <>
  • Lucet Denis, Le Gall Thierry, Mioskowski Charles: Die Chemie vicinaler Diamine. Angew Chem 1998, 110, 2724. <<2724::AID-ANGE2724>3.0.CO;2-4>
  • Magnus Philip, Sebhat Iyassu K.: Application of the β-azidonation reaction to the synthesis of the antitumor alkaloid (+)-pancratistatin. Tetrahedron 1998, 54, 15509. <>
  • Hoppe Dieter, Hense Thomas: Enantioselektive Synthese mit Lithium/(−)-Spartein-Carbanion-Paaren. Angew Chem 1997, 109, 2376. <>
  • Aoki Kazumasa, Tomioka Kiyoshi, Noguchi Hiroshi, Koga Kenji: Stereoselective reactions. 28. Effects of the alkyl group at the amide nitrogen of chiral bidentate lithium amides on enantioselective deprotonation reaction. Tetrahedron 1997, 53, 13641. <>
  • Yamashita Toyoharu, Sato Daisaku, Kiyoto Taro, Kumar Arvind, Koga Kenji: Stereoselective reactions. 29. Lithium-hydrogen interchange between achiral tridentate lithium amides and chiral bidentate amines. An approach to catalytic enantioselective deprotonation. Tetrahedron 1997, 53, 16987. <>
  • Nowakowski Marc, Hoffmann H.M.R: Asymmetric synthesis of the C(18)C(24) unit of lasonolide A. Tetrahetron Lett 1997, 38, 1001. <>