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Pure Appl. Chem., 1996, Vol. 68, No. 3, pp. 675-678

Photocyclization-fragmentation route to di- and triquinanes: Stereocontrolled asymmetric synthesis of (-)-isocomene

V. H. Rawal, Andrew Eschbach, Claire Dufour and Seiji Iwasa

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  • Hong Young J., Irmisch Sandra, Wang Selina C., Garms Stefan, Gershenzon Jonathan, Zu Liansuo, Köllner Tobias G., Tantillo Dean J.: Theoretical and Experimental Analysis of the Reaction Mechanism of MrTPS2, a Triquinane-Forming Sesquiterpene Synthase from Chamomile. Chem. Eur. J. 2013, 19, 13590. <>
  • Bach Thorsten, Hehn Jörg P.: Photochemische Reaktionen als Schlüsselschritte in der Naturstoffsynthese. Angew Chem 2011, 123, 1032. <>
  • Bach Thorsten, Hehn Jörg P.: Photochemical Reactions as Key Steps in Natural Product Synthesis. Angew Chem Int Ed 2011, 50, 1000. <>
  • Schmidt Arndt W., Olpp Thomas, Baum Elke, Stiffel Tina, Knölker Hans-Joachim: Organosilicon-mediated total synthesis of the triquinane sesquiterpenes (±)-β-isocomene and (±)-isocomene. Org Biomol Chem 2010, 8, 4562. <>
  • Reddy T. Jagadeeswar, Rawal Viresh H.: Expeditious Syntheses of (±)-5-Oxosilphiperfol-6-ene and (±)-Silphiperfol-6-ene. Org Lett 2000, 2, 2711. <>
  • Dufour Claire, Iwasa Seiji, Fabré Agnes, Rawal Viresh H.: Unexpected fragmentations leading to quinanes and hydrindanes mediated by a silyl radical. Tetrahetron Lett 1996, 37, 7867. <>